Selective determination of Sm (III) in lanthanide mixtures by thermal lens microscopy

Nader Shokoufi; Javad Yoosefian

Journal of Industrial and Engineering Chemistry, Vol.35, 153-157, March, 2016

DOI10.1016/j.jiec.2015.12.027 Export Citation

Selective determination of Sm (III) in lanthanide mixtures by thermal lens microscopy

Nader Shokoufi^†, and Javad Yoosefian

Analytical Instrumentation & Spectroscopy Laboratory, Faculty of Clean Technologies, Chemistry & Chemical Engineering Research Center of Iran (CCERCI), Tehran, Iran

E-mail:

Since lanthanides are inner transitional elements with their 4f and 5d energy levels closed, they possess narrow electronic absorption peaks, which are little affected by their chemical environment. In this research, a thermal lens microscope (TLM) that utilizing diode lasers as pump and probe beams was constructed for selective determination of Sm (III) without any pre-concentration and separation procedure. The calibration plot has a linear behavior over the 0.5.500 μg mL-1 range and a limit of detection (LOD) of 0.08 μg mL-1. The relative standard deviation (RSD) is smaller than 5%. This method can be potentially applicable to environmental studies.

Keywords:Sm;Thermal lens microscopy;Closed 4f and 5d energy levels;Lanthanide species

[References]

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Georges J, Mermet JM, Analysis, 16, 203 (1988)
Leite RCC, Moore RS, Whinnery JR, Appl. Phys. Lett., 5, 141 (1964)
Shokoufi N, Madarshahian S, Thermal Lens Spectrometry, Lap Lambert, Germany, 2012.
Harris J, in: Piepmeier EH (Ed.), Analytical Applications of Lasers, vol. 87, Wiley, New York, 1986.
Dovichi NJ, Harris J, Anal. Chem., 51, 728 (1979)
Shokoufi N, Shemirani F, Talanta, 73, 662 (2007)
Dovichi N, Harris J, Anal. Chem., 53, 106 (1981)
Nakanishi K, Imasaka T, Ishibashi N, Anal. Chem., 57, 1219 (1985)
Franko M, Tran CD, Encyclopedia of Analytical Chemistry, John Wiley & Sons Ltd., New York, 2010.
Snook RD, Lowe RD, Analyst, 120, 2051 (1995)
Kitamori T, Tokeshi M, Hibara A, Sato K, Anal. Chem., 76, 52A (2004)
Uchiyama K, Hibara A, Kimura H, Sawada T, Kitamori T, Jpn. J. Appl. Phys., 39, 5316 (2000)
Wannachod T, Leepipatpiboon N, Pancharoen U, Nootong K, J. Ind. Eng. Chem., 20(6), 4152 (2014)
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Yesiller SU, Erog˘lu AE, Shahwan T, J. Ind. Eng. Chem., 19(3), 898 (2013)
Samaddar P, Sen K, J. Ind. Eng. Chem., 20(4), 1209 (2014)
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Shemirani F, Shokoufi N, Anal. Chim. Acta, 557, 238 (2006)
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Ding Y, Zhao H, Sun Y, Zhang G, Wu H, Qian Y, Int. J. Inorg. Mater., 3, 151 (2001)
http://digitalcommons.calpoly.edu/star/85.
Berregi I, Durand JS, Casado JA, Talanta, 48, 719 (1999)
Varga Z, Katona R, Satefanka Z, Wallenius M, Talanta, 80, 1744 (2010)
Soylak M, Turkoglu O, Talanta, 53, 125 (2000)
Borai EH, Eid MA, Aly HF, Anal. Bioanal. Chem., 372, 537 (2002)
Faridbod F, Ganjali MR, Dinarvand R, Norouzi P, Riahi S, Sensors, 8, 1645 (2008)
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Bhattacharya S, Lyle SJ, Maghzian R, Talanta, 27, 59 (1980)
Lyle SJ, Za’tar NA, Anal. Chim. Acta, 135, 327 (1982)
Yungeng G, Bo D, Spectroc. Acta Pt. B-Atom. Spectr., 51, 1147 (1996)

[1] Dovichi NJ, Bialkowski SE, Crit. Rev. Anal. Chem., 17, 357 (1987)

[2] Georges J, Mermet JM, Analysis, 16, 203 (1988)

[3] Leite RCC, Moore RS, Whinnery JR, Appl. Phys. Lett., 5, 141 (1964)

[4] Shokoufi N, Madarshahian S, Thermal Lens Spectrometry, Lap Lambert, Germany, 2012.

[5] Harris J, in: Piepmeier EH (Ed.), Analytical Applications of Lasers, vol. 87, Wiley, New York, 1986.

[6] Dovichi NJ, Harris J, Anal. Chem., 51, 728 (1979)

[7] Shokoufi N, Shemirani F, Talanta, 73, 662 (2007)

[8] Dovichi N, Harris J, Anal. Chem., 53, 106 (1981)

[9] Nakanishi K, Imasaka T, Ishibashi N, Anal. Chem., 57, 1219 (1985)

[10] Franko M, Tran CD, Encyclopedia of Analytical Chemistry, John Wiley & Sons Ltd., New York, 2010.

[11] Snook RD, Lowe RD, Analyst, 120, 2051 (1995)

[12] Kitamori T, Tokeshi M, Hibara A, Sato K, Anal. Chem., 76, 52A (2004)

[13] Uchiyama K, Hibara A, Kimura H, Sawada T, Kitamori T, Jpn. J. Appl. Phys., 39, 5316 (2000)

[14] Wannachod T, Leepipatpiboon N, Pancharoen U, Nootong K, J. Ind. Eng. Chem., 20(6), 4152 (2014)

[15] Wannachod T, Leepipatpiboon N, Pancharoen U, Phatanasri S, J. Ind. Eng. Chem., 21, 535 (2015)

[16] Yoon SJ, Lee JG, Tajima H, Yamasaki A, Kiyono F, Nakazato T, Tao H, J. Ind. Eng. Chem., 16(3), 350 (2010)

[17] Yesiller SU, Erog˘lu AE, Shahwan T, J. Ind. Eng. Chem., 19(3), 898 (2013)

[18] Samaddar P, Sen K, J. Ind. Eng. Chem., 20(4), 1209 (2014)

[19] Dybczynski RS, Czerska E, Danko B, Kulisa K, Samczynski Z, Appl. Radiat. Isot., 68, 23 (2010)

[20] Blair PD, TrAC Trends Anal. Chem., 5, 220 (1986)

[21] Alonso JIG, Thoby-Schultzendorff D, Giovanonne B, Koch L, Wiesmann H, J. Anal. At. Spectrom., 8, 673 (1993)

[22] Weltje L, Heidenreich H, Zhu W, Wolterbeek HT, Korhammer S, Goeij JJMD, Markert B, Sci. Total Environ., 286, 191 (2002)

[23] Krachler M, Mohl C, Emons H, Shotyk W, J. Anal. At. Spectrom., 17, 844 (2002)

[24] Navarro MS, Andrade S, Ulbrich H, Gomes CB, Girardi VA, Geostand. Geoanal. Res., 32, 167 (2008)

[25] Markert B, Li ZD, Sci. Total Environ., 103, 27 (1991)

[26] Navarro MS, Ulbrich H, Andrade S, Janasi VA, J. Alloy. Compd., 344, 40 (2002)

[27] Shemirani F, Shokoufi N, Anal. Chim. Acta, 557, 238 (2006)

[28] Shokoufi N, Hamdamali A, Anal. Chim. Acta, 681, 56 (2010)

[29] Ding Y, Zhao H, Sun Y, Zhang G, Wu H, Qian Y, Int. J. Inorg. Mater., 3, 151 (2001)

[30] http://digitalcommons.calpoly.edu/star/85.

[31] Berregi I, Durand JS, Casado JA, Talanta, 48, 719 (1999)

[32] Varga Z, Katona R, Satefanka Z, Wallenius M, Talanta, 80, 1744 (2010)

[33] Soylak M, Turkoglu O, Talanta, 53, 125 (2000)

[34] Borai EH, Eid MA, Aly HF, Anal. Bioanal. Chem., 372, 537 (2002)

[35] Faridbod F, Ganjali MR, Dinarvand R, Norouzi P, Riahi S, Sensors, 8, 1645 (2008)

[36] Arrebola A, Bagur MG, Sanchez M, Gazquez D, Romero R, Camino M, J. Anal. At. Spectrom., 13, 765 (1998)

[37] Bhattacharya S, Lyle SJ, Maghzian R, Talanta, 27, 59 (1980)

[38] Lyle SJ, Za’tar NA, Anal. Chim. Acta, 135, 327 (1982)

[39] Yungeng G, Bo D, Spectroc. Acta Pt. B-Atom. Spectr., 51, 1147 (1996)