화학공학소재연구정보센터
Journal of Materials Science, Vol.32, No.5, 1195-1199, 1997
The Influence of the Structure on the Electrical and Magnetic-Properties of Bi2Sr2Cacu2O8+delta Single-Crystals
The correlation between the structure, chemical composition, electrical and magnetic properties of Bi2Sr2CaCu2O8+delta single crystals is presented. As revealed by SEM measurements, the small samples (approximately 1 mm x 1 mm x 0.2 mm) are stacks of thin plates (1-2 mu m). Microcompositional measurements (energy dispersive spectroscopy) show the Bi2Sr2CaCu2O8+delta (2212)-phase and a small quantity of residual phases enriched in bismuth and strontium and calcium-deficient. Magnetically modulated microwave absorption measurements (MAMMA) lead to a value for the anisotropy of the upper critical field of about 7, which is more than twice the reported value for YBa2Cu3O7-delta single crystals (also determined from MAMMA responses). The plot of the resistance versus temperature suggests that only the first 10-20 plates from the surface of the sample have a contribution to the sample conductivity. The imaginary part, chi", of the magnetic susceptibility of our samples shows three peaks.