Journal of Industrial and Engineering Chemistry, Vol.36, 139-146, April, 2016
Preparation and electrochemical analysis of graphene nanosheets/nickel hydroxide composite electrodes containing carbon nanotubes
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A set of graphene nanosheets (GNS)/nickel hydroxide (Ni(OH)2) composites were successfully synthesized by adding single-walled carbon nanotubes (SWCNT) to the composites with various weight contents. The mixed composites were prepared by ultrasonication and chemical precipitation. It is postulated that the SWCNT act as additives in the composites, preventing the aggregation of the graphene sheets. The structural characterization indicated that the Ni(OH)2 nanoparticles were deposited on the surface of GNS, and the SWCNT were dispersed between or onto the graphene sheets. The electrochemical performance of the composites was investigated by changing the contents of the added SWCNT. The prepared GNS/SWCNT/Ni(OH)2 composites exhibited the superior electrochemical performance, indicated by the large specific capacitance over 1000 Fg-1 and excellent cycle performance over 2000 cycles. Among the prepared composites, the GNS/Ni(OH)2 composite containing 20 wt.% SWCNT displayed the maximum specific capacitance with a value of 1149 Fg-1 at a in 6 M KOH electrolyte. Moreover, 92% of the initial specific capacitance of the composite was maintained after 2000-cycle test. Based on these results, the composite is thought to be suitable candidate for supercapacitor electrode materials.
Keywords:Graphene nanosheets;Nickel hydroxide;Single-walled carbon nanotubes;Composite electrodes;Supercapacitor
- Simon P, Gogotsi Y, Nat. Mater., 7(11), 845 (2008)
- Miller JR, Simon P, Science, 321, 651 (2008)
- Bao LH, Zang JF, Li XD, Nano Lett., 11, 1215 (2011)
- Kim M, Kim S, J. Ind. Eng. Chem., 20(6), 4447 (2014)
- Wang GP, Zhang L, Zhang JJ, Chem. Soc. Rev., 41, 797 (2012)
- Oh M, Kim S, Electrochim. Acta, 78, 279 (2012)
- Oh MS, Park SJ, Jung Y, Kim S, Synth. Met., 162(7), 695 (2012)
- Ramesh TN, Jayashree RS, Kamath PV, Rodrigues S, Shukla AK, J. Power Sources, 104(2), 295 (2002)
- Zhao DD, Zhou WJ, Li HL, Chem. Mater., 19, 3882 (2007)
- Wang H, Liang Y, Mirfakhrai T, Chen Z, Casalongue HS, Dai H, Nano Res., 4, 729 (2011)
- Bak SM, Kim KH, Lee CW, Kim KB, J. Mater. Chem., 21, 1984 (2011)
- Wang HL, Casalongue HS, Liang YY, Dai HJ, J. Am. Chem. Soc., 132(21), 7472 (2010)
- Zhong JH, Wang AL, Li GR, Wang JW, Ou YN, Tong YX, J. Mater. Chem., 22, 5656 (2012)
- Liu CG, Lee YS, Kim YJ, Song IC, Kim JH, Synth. Met., 159, 2009 (2009)
- Jiang X, Ma Y, Li J, Huang W, J. Phys. Chem., 114, 22462 (2010)
- Jeong HM, Lee JW, Shin WH, Choi YH, Shin HJ, Kang JK, Choi JW, Nano Lett., 11, 2472 (2011)
- Park S, Ruoff RS, Nat. Nanotechnol., 4(4), 217 (2009)
- Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS, Adv. Mater., 22(35), 3906 (2010)
- Huang Y, Liang JJ, Chen YS, Small, 8, 1805 (2012)
- Park J, Park SJ, Kim S, J. Electrochem. Soc., 161(5), F641 (2014)
- Yan J, Sun W, Wei T, Zhang Q, Fan Z, Wei F, J. Mater. Chem., 22, 11494 (2012)
- Yan J, Wei T, Shao B, Ma FQ, Fan ZJ, Zhang ML, Zhang C, Shang YC, Qian WZ, Wei F, Carbon, 48, 1731 (2010)
- Kim J, Kim S, Electrochim. Acta, 119, 11 (2014)
- Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin LC, Phys. Chem. Chem. Phys., 13, 17615 (2011)
- Wu Y, Zhang T, Zhang F, Wang Y, Ma Y, Huang Y, Liu Y, Chen Y, Nano Energy, 1, 820 (2012)
- Choi JR, Lee YS, Park SJ, J. Ind. Eng. Chem., 20(5), 3421 (2014)
- Yim YJ, Park SJ, J. Ind. Eng. Chem., 21(1), 155 (2015)
- Ajayan PM, Zhou OZ, Appl. Phys., 80, 391 (2001)
- Hummers WH, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
- Liang YY, Wu DQ, Feng XL, Mullen K, Adv. Mater., 21(17), 1679 (2009)
- Yuan CZ, Gao B, Zhang XG, J. Power Sources, 173(1), 606 (2007)
- Lee JW, Ann T, Soundararajan D, Ko JM, Kim JD, Chem. Commun., 47, 6305 (2011)
- Li BJ, Cao HQ, Shao J, Zheng H, Lu YX, Yin JF, Qu MZ, Chem. Commun., 47, 3159 (2011)
- Chen X, Chen XH, Zhang FQ, Yang Z, Huang SM, J. Power Sources, 243, 555 (2013)
- Park SK, Shao Y, Wan H, Rieke PC, Viswanathan VV, Towne SA, Liu J, Wang Y, Electrochem. Commun., 13, 258 (2011)
- Battumur T, Ambade SB, Ambade RB, Pokharel P, Lee DS, Han SH, Lee W, Lee SH, Curr. Appl. Phys., 13(1), 196 (2013)
- Du F, Yu D, Dai L, Ganguli S, Varshney V, Roy AK, Chem. Mater., 23, 4810 (2011)
- Zeng FY, Kuang YF, Zhang NS, Huang ZY, Pan Y, Hou ZH, Zhou HH, Yan CL, Schmidt OG, J. Power Sources, 247, 396 (2014)
- Kim Y, Kim S, Electrochim. Acta, 163, 252 (2015)
- Kim J, Kim S, Appl. Surf. Sci., 295, 31 (2014)