CO2 부가반응에 적용된 Silica 담지 이온성 액체 촉매

김동우; 김현국; 조득희; Dong-Woo Kim; Hyeon-Gook Kim; Deug-Hee Cho

Applied Chemistry for Engineering, Vol.27, No.3, 239-244, June, 2016

DOI10.14478/ace.2016.1031 Export Citation

CO2 부가반응에 적용된 Silica 담지 이온성 액체 촉매

Application of Silica-supported Ionic Liquid Catalysts to Cycloaddition of CO2

김동우, 김현국, 조득희^†

화학산업고도화센터 한국화학연구원

Dong-Woo Kim, Hyeon-Gook Kim, and Deug-Hee Cho^†

Chemical Industry Development Center, Korea Research Institute of Chemical Technology, 45 Jongga-ro, Jung-gu, Ulsan 44412, Republic of Korea

E-mail:

초록

본 총설에서는 CO2와 에폭시 화합물의 부가반응에서 무정형, SBA, MCM 또는 상업적으로 쉽게 이용 가능한 다양한 silica 지지체에 담지된 이온성 액체의 촉매적 적용가능성에 대하여 검토하였다. CO2 부가반응에 의한 5원환 카보네이트의 합성에 대하여 담지된 이온성 액체의 구조적인 영향과 silica 지지체의 종류에 따른 촉매 활성을 검토한 바, 관능기 또는 금속을 보유한 이온성 액체인 경우에 촉매 성능이 개선됨을 알 수 있었다. 또한 silica에 담지된 이온성 액체(SSIL) 촉매의 재사용성과 반응메커니즘을 조사하여 제시하였다.

The catalytic applicability of various ionic liquids immobilized on different silica-supports such as amorphous, SBA, MCM and commercial silica for the cycloaddition of CO2 and epoxides is reviewed in this work. The effects of different structures of supported ionic liquids and silica supports in the synthesis cyclic carbonate by the cycloaddition of CO2 have been remarked. The studies revealed that ionic liquids possessing functional groups or metals exhibited increased catalytic performance towards cyclic carbonate synthesis. Moreover, the reusability of SSIL catalyst and mechanism for the cycloaddition of CO2 were studied.

Keywords:carbon dioxide;cycloaddition;ionic liquid;immobilization;silica

[References]

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Romano U, Chim. Ind., 75, 303 (1993)
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Kim DW, Roshan R, Tharun J, Cherian A, Park DW, Korean J. Chem. Eng., 30(11), 1973 (2013)
Han L, Park SW, Park DW, Energy Environ. Sci., 2, 1286 (2009)
Han L, Choi HJ, Choi SJ, Liub B, Park DW, Green Chem., 13, 1023 (2011)
Han L, Park MS, Choi SJ, Kim YJ, Lee SM, Park DW, Catal. Lett., 142(2), 259 (2012)
Wang JQ, Kong DL, Chen JY, Cai F, He LN, J. Mol. Catal. A-Chem., 249(1-2), 143 (2006)
Wang JQ, Yue XD, Cai F, He LN, Catal. Commun., 8, 167 (2007)
Kishimoto Y, Ogawa I, Ind. Eng. Chem. Res., 43(26), 8155 (2004)
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Kawanami H, Sasaki A, Matsui K, Ikushima Y, Chem. Commun., 7, 896 (2003)
Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)
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Udayakumar S, Raman V, Shim HL, Park DW, Appl. Catal. A: Gen., 368(1-2), 97 (2009)
Dharman MM, Choi HJ, Kim DW, Park DW, Catal. Today, 164(1), 544 (2011)

[1] Gavin DG, Bower CJ, Options for reducing greenhouse gases in the global environment, Proc. of the JAPAN-EC, Japan (1991).

[2] Inoue S, Tsuruta T, Koinuma H, J. Polym. Sci. Polym. Lett., 7(4), 287 (1969)

[3] Inoue S, Yamazaki N, Organic and Bioorganic Chemistry of Carbon Dioxide, Kodansha Ltd., Tokyo (1981).

[4] Cho SH, Bai BC, Yu HR, Lee YS, Appl. Chem. Eng., 22(5), 343 (2011)

[5] Romano U, Chim. Ind., 75, 303 (1993)

[6] Shaikh AA, Sivaram S, Chem. Rev., 96(3), 951 (1996)

[7] Weissermel K, Arpe HJ, Industral Organic Chemestry, 3rd ed., Wiley-VCH, New York (1997).

[8] Song CE, Shim WH, Roh EJ, Choi JH, Chem. Commun., 17, 1695 (2000)

[9] Kim DW, Roshan R, Tharun J, Cherian A, Park DW, Korean J. Chem. Eng., 30(11), 1973 (2013)

[10] Han L, Park SW, Park DW, Energy Environ. Sci., 2, 1286 (2009)

[11] Han L, Choi HJ, Choi SJ, Liub B, Park DW, Green Chem., 13, 1023 (2011)

[12] Han L, Park MS, Choi SJ, Kim YJ, Lee SM, Park DW, Catal. Lett., 142(2), 259 (2012)

[13] Wang JQ, Kong DL, Chen JY, Cai F, He LN, J. Mol. Catal. A-Chem., 249(1-2), 143 (2006)

[14] Wang JQ, Yue XD, Cai F, He LN, Catal. Commun., 8, 167 (2007)

[15] Kishimoto Y, Ogawa I, Ind. Eng. Chem. Res., 43(26), 8155 (2004)

[16] Huang JW, Shi M, J. Org. Chem., 68, 6705 (2003)

[17] Kawanami H, Sasaki A, Matsui K, Ikushima Y, Chem. Commun., 7, 896 (2003)

[18] Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)

[19] Udayakumar S, Lee MK, Shim HL, Park SW, Park DW, Catal. Commun., 10, 659 (2009)

[20] Udayakumar S, Raman V, Shim HL, Park DW, Appl. Catal. A: Gen., 368(1-2), 97 (2009)

[21] Dharman MM, Choi HJ, Kim DW, Park DW, Catal. Today, 164(1), 544 (2011)