화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.33, No.9, 2628-2637, September, 2016
DOI10.1007/s11814-016-0108-4  Export Citation
An experimental and kinetic study of toluene oxidation over LaMn1-xBxO3 and La0.8A0.2Mn0.3B0.7O3 (A=Sr, Ce and B=Cu, Fe) nano-perovskite catalysts
Ali Tarjomannejad, Ali Farzi†, Aligholi Niaei, and Dariush Salari1
  • Department of Chemical & Petroleum Engineering, University of Tabriz, Tabriz, Iran
  • 1Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
E-mail:
Catalytic oxidation of toluene over perovskite-type oxides of the general formula LaMn1-xBxO3 (B=Cu, Fe and x=0, 0.3, 0.7) and La0.8A0.2Mn0.3B0.7O3 (A=Sr, Ce and B=Cu, Fe) was investigated, where the catalysts were synthesized by sol-gel auto combustion method. The catalysts were characterized by XRD, BET, H2-TPR, XPS, and SEM. Obtained XRD patterns confirmed the perovskites to be single-phase perovskite-type oxides. Specific surface areas of perovskites were obtained between 25-40m2/g. The perovskite catalysts showed high activity for the toluene oxidation. Based on the results, Fe-containing perovskite catalysts exhibited higher activity than Cu-containing perovskite catalysts. The substitution of Sr and Ce in A-site of the perovskite catalysts enhanced their activity for toluene oxidation. Among different synthesized catalysts in this research, La0.8Ce0.2Mn0.3Fe0.7O3 has the highest activity. Nearly complete elimination of toluene was achieved at 200 ℃ with this catalyst. Based on Langmuir-Hinshelwood mechanisms, kinetic studies were conducted on toluene oxidation, indicating LH-OS-ND (adsorption of reagents on same types of sites and non-dissociative adsorption of oxygen) as the most probable mechanism which could predict the experimental data with correlation coefficient of R2=0.9952.
Keywords:Toluene Oxidation;La0.8A0.2B0.7Mn0.3O3;Perovskite;Sol-gel;Kinetic
  1. Ma W, Huang Q, Xu Y, Chen Y, Zhu S, Shen S, Ceram. Int., 39, 277 (2013)
  2. Liotta LF, Appl. Catal. B: Environ., 100(3-4), 403 (2010)
  3. Jodaei A, Niaei A, Salari D, Korean J. Chem. Eng., 28(8), 1665 (2011)
  4. Kim MS, Kim JS, Kim BW, Korean J. Chem. Eng., 29(5), 549 (2012)
  5. Hosseini S, Alvarez-Galvan M, Fierro J, Niaei A, Salari D, Ceram. Int., 39, 9253 (2013)
  6. Lahousse C, Bernier A, Grange P, Delmon B, Papaefthimiou P, Ioannides T, Verykios X, J. Catal., 178(1), 214 (1998)
  7. Giraudon JM, Elhachimi A, Leclercq G, Appl. Catal. B: Environ., 84(1-2), 251 (2008)
  8. Giraudon JM, Elhachimi A, Wyrwalski F, Siffert S, Aboukais A, Lamonier JF, Leclercq G, Appl. Catal. B: Environ., 75(3-4), 157 (2007)
  9. Pereniguez R, Hueso JL, Gaillard F, Holgado JP, Caballero A, Catal. Lett., 142(4), 408 (2012)
  10. Tanaka H, Misono M, Curr. opin. Solid State Mat. Sci., 5, 381 (2001)
  11. Esther J, Sukla LB, Pradhan N, Panda S, Korean J. Chem. Eng., 32(1), 1 (2015)
  12. Rezlescu N, Rezlescu E, Doroftei C, Popa P, Ignat M, Dig. J. Nanomater. Biostruct, 8, 581 (2013)
  13. Royer S, Duprez D, ChemCatChem, 3, 24 (2011)
  14. Levasseur B, Kaliaguine S, Appl. Catal. B: Environ., 88(3-4), 305 (2009)
  15. Niu JR, Deng JG, Liu W, Zhang L, Wang GZ, Dai HX, He H, Zi XH, Catal. Today, 126(3-4), 420 (2007)
  16. Huang H, Liu Y, Tang W, Chen Y, Catal. Commun., 9, 55 (2008)
  17. Liu G, Li J, Yang K, Tang W, Liu H, Yang J, Yue R, Chen Y, Particuology, 19, 60 (2015)
  18. Li N, Boreave A, Deloume JP, Gaillard F, Solid State Ion., 179(27-32), 1396 (2008)
  19. Alvarez-Galvan MC, O'Shea VAD, Arzamendi G, Pawelec B, Gandia LM, Fierro JLG, Appl. Catal. B: Environ., 92(3-4), 445 (2009)
  20. Zawadzki M, Trawczynski J, Catal. Today, 176(1), 449 (2011)
  21. Stege WP, Cadus LE, Barbero BP, Catal. Today, 172(1), 53 (2011)
  22. Giroir-Fendler A, Alves-Fortunato M, Richard M, Wang C, Diaz JA, Gil S, Zhang CH, Can F, Bion N, Guo YL, Appl. Catal. B: Environ., 180, 29 (2016)
  23. Deng JG, Zhang L, Dai HX, Au CT, Catal. Lett., 130(3-4), 622 (2009)
  24. Zhang C, Guo Y, Guo Y, Lu G, Boreave A, Retailleau L, Baylet A, Giroir-Fendler A, Appl. Catal. B: Environ., 148-149, 490 (2014)
  25. Hosseini SA, Salari D, Niaei A, Oskoui SA, J. Ind. Eng. Chem., 19(6), 1903 (2013)
  26. Meiqing S, Zhen Z, Jiahao C, Yugeng S, Jun W, Xinquan W, J. Rare Earths, 31, 119 (2013)
  27. Giannakas AE, Leontiou AA, Ladavos AK, Pomonis PJ, Appl. Catal. A: Gen., 309(2), 254 (2006)
  28. Chan KS, Ma J, Jaenicke S, Chuah GK, Lee JY, Appl. Catal. A: Gen., 107(2), 201 (1994)
  29. Abdolrahmani M, Parvari M, Habibpoor M, Chin. J. Catal., 31, 394 (2010)
  30. Oskoui SA, Niaei A, Tseng HH, Salari D, Izadkhah B, Hosseini SA, ACS Combinatorial Sci., 15, 609 (2013)
  31. Leontiou AA, Ladavos AK, Armatas GS, Trikalitis PN, Pomonis PJ, Appl. Catal. A: Gen., 263(2), 227 (2004)
  32. Wu MD, Xu LH, Weng D, Catal. Today, 90(3-4), 199 (2004)
  33. Cano E, Torres C, Bastidas J, Mater. Corros., 52, 667 (2001)
  34. Maluf S, Assaf E, J. Natural Gas Chem., 19, 567 (2010)
  35. Jo M, Tanaka A, Appl. Surf. Sci., 100, 11 (1996)
  36. Gao B, Deng J, Liu Y, Zhao Z, Li X, Wang Y, Dai H, Chin. J. Catal., 34, 2223 (2013)
  37. Tanaka H, Mizuno N, Misono M, Appl. Catal. A: Gen., 244(2), 371 (2003)
  38. Yoon JS, Lim YS, Choi BH, Hwang HJ, Int. J. Hydrog. Energy, 39(15), 7955 (2014)
  39. Deng JG, Zhang L, Dai HX, He H, Au CT, Ind. Eng. Chem. Res., 47(21), 8175 (2008)
  40. Zhong H, Zeng R, J. Serb. Chem. Soc., 71, 1049 (2006)
  41. Zheng SJ, Hua Q, Gu WB, Liu BZ, J. Mol. Catal. A-Chem., 391, 7 (2014)
  42. Lin YC, Hohn KL, Catalysts, 4, 305 (2014)
  43. Karthikeyan S, Gupta V, Boopathy R, Titus A, Sekaran G, J. Mol. Liq., 173, 153 (2012)
  44. Gupta V, Gupta B, Rastogi A, Agarwal S, Nayak A, Water Res., 45, 4047 (2011)
  45. Gupta VK, Jain R, Saleh TA, Nayak A, Malathi S, Agarwal S, Sep. Sci. Technol., 46(5), 839 (2011)
  46. Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 12 (2012)
  47. Vannice MA, Joyce WH, Kinetics of catalytic reactions, Springer (2005).
  48. Markova-Velichkova M, Lazarova T, Tumbalev V, Ivanov G, Kovacheva D, Stefanov P, Naydenov A, Chem. Eng. J., 231, 236 (2013)
  49. Hu CQ, Chem. Eng. J., 168(3), 1185 (2011)
  50. Behar S, Gomez-Mendoza NA, Gomez-Garcia MA, Swierczynski D, Quignard F, Tanchoux N, Appl. Catal. A: Gen., 504, 203 (2014)
  51. Bedia J, Rosas JM, Rodriguez-Mirasol J, Cordero T, Appl. Catal. B: Environ., 94(1-2), 8 (2010)