화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.44, 155-163, December, 2016
DOI10.1016/j.jiec.2016.08.022  Export Citation
The effect of metal complex on pervaporation performance of composite membrane for separation of n-butanol/water mixture
Ki Yong Jee, Nowon Kim1, and Yong Taek Lee†
  • Department of Chemical Engineering, College of Engineering, Kyung Hee University, Gyeonggi-do,Republic of Korea
  • 1Department of Environmental Engineering, College of Engineering, Dong-Eui University, Busan, Republic of Korea
E-mail:
We prepared a PDMS/PVDF, a PDMS/PVDF-Fe(II) and a PDMS/PVDF-Co(II) membranes. Support layer was prepared by using polyvinylidene fluoride (PVDF)/N-methyl-2-pyrrolidone (NMP) casting solution with or without Fe(II) complex or Co(II) complex. Pervaporation performance was tested to determine the contribution of metal complex additives in the support layer. The flux and the separation factor of the PDMS/PVDF-Fe(II) complex membrane were 331.84 g/m2h and 42, respectively. The flux of PDMS/PVDF membrane was 233.33 g/m2h and separation factor was 44. The separation factor of PDMS/PVDF-Fe(II) complex membrane is similar to PDMS/PVDF membrane, the flux of the former is much higher than the latter.
Keywords:Pervaporation;Butanol;Polydimethylsiloxane;Composite membrane;Metal complex
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