화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.44, 146-154, December, 2016
DOI10.1016/j.jiec.2016.08.024  Export Citation
MOF-derived nitrogen-doped porous carbon as metal-free catalysts for acetylene hydrochlorination
Xiaoyan Li, Jinli Zhang, and Wei Li†
  • School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, PR China
E-mail:
A series of ZIF-derived nitrogen-doped carbon materials were prepared using melamine as the additional nitrogen sources for acetylene hydrochlorination. The results indicated that the optimal complex of Z4M1 exhibits the highest acetylene conversion of 60% under the reaction conditions of 180 °C, C2H2 gas hourly space velocity (GHSV) = 50 h-1, VHCl/VC2H2 = 1.15, suggesting a promising metal-free catalyst for acetylene hydrochlorination. It is illustrated that the additions of melamine not only make the complex of Z4M1 displays special morphological structure and proper pore structure, but also adjust the relative content ratio of three nitrogen species in ZIF-derived nitrogen-doped carbon materials.
Keywords:Metal-organic frameworks;Metal-free catalyst;Acetylene hydrochlorination
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