Korean Journal of Chemical Engineering, Vol.34, No.1, 160-169, January, 2017
Porous polyethersulfone hollow fiber membrane in CO2 separation process via membrane contactor - The effect of nonsolvent additives
E-mail:,
A membrane contactor (MC) is used for natural gas sweetening and wastewater treatment with a membrane that is acting as a separating barrier between two phases, usually liquid and gas. The performance of membrane is governed by parameters such as pore size, porosity, tortuosity and surface hydrophobicity, which can be controlled by a number of methods. Addition of nonsolvents to spinning solution is known to be one of such methods. In this study, the effects of low molecular weight additives as phase inversion promoters on the morphology of polyethersulfone hollow fiber membranes and their performance in gas-liquid MC processes were investigated. It was found that among the six nonsolvent additives under study, addition of water resulted in the highest CO2 flux, by decreasing the thermodynamic stability of polymer solution and maintaining high solvent-nonsolvent exchange rate.
- Pogaku R, Sarbatly RH, Advances in biofuels, Springer, New York (2013).
- Comite A, Costa C, Felice RD, Pagliai P, Vitiello D, Korean J. Chem. Eng., 32(2), 239 (2015)
- Jeong D, Yun M, Oh J, Yum I, Lee Y, Korean J. Chem. Eng., 27(3), 939 (2010)
- Bakeri G, Ismail AF, Rahimnejad M, Matsuura T, Rana D, Sep. Purif. Technol., 98, 262 (2012)
- Bakeri G, Ismail AF, Rahimnejad M, Matsuura T, Chem. Eng. Res. Des., 92(7), 1381 (2014)
- Lafreniere LY, Talbot FDF, Matsuura T, Sourirajan S, Ind. Eng. Chem. Res., 26(11), 2385 (1987)
- Wienk IM, Scholtenhuis FH, Vandenboomgaard T, Smolders CA, J. Membr. Sci., 106(3), 233 (1995)
- Su BH, Fu P, Li Q, Tao Y, Li Z, Zao HS, Zhao CS, J. Mater. Sci. -Mater. Med., 19, 745 (2008)
- Liu Y, Koops GH, Strathmann H, J. Membr. Sci., 223(1-2), 187 (2003)
- Xu ZL, Qusay FA, J. Appl. Polym. Sci., 91(5), 3398 (2004)
- Chaturvedia BK, Ghosh AK, Ramachandhran V, Trivedi MK, Hanra MS, Misra BM, Desalination, 133(1), 31 (2001)
- Ismail AF, Hassan AR, Sep. Purif. Technol., 55(1), 98 (2007)
- Razmjou A, Resosudarmo A, Holmes RL, Li HY, Mansouri J, Chen V, Desalination, 287, 271 (2012)
- Razmjou A, Mansouri J, Chen V, Lim M, Amal R, J. Membr. Sci., 380(1-2), 98 (2011)
- Sotto A, Rashed A, Zhang RX, Martinez A, Braken L, Luis P, Van der Bruggen B, Desalination, 287, 317 (2012)
- Basri H, Ismail AF, Aziz M, Nagai K, Matsuura T, Abdullah MS, Ng BC, Desalination, 261(3), 264 (2010)
- Basri H, Ismail AF, Aziz M, Desalination, 273(1), 72 (2011)
- Cao X, Tang M, Liu F, Nie Y, Zhao C, Colloids Surf. B: Biointerfaces, 81, 555 (2010)
- Shen JN, Ruan HM, Wu LG, Gao CJ, Chem. Eng. J., 168(3), 1272 (2011)
- Ananth A, Arthanareeswaran G, Wang HT, Desalination, 287, 61 (2012)
- Maximous N, Nakhla G, Wong K, Wan W, Sep. Purif. Technol., 73(2), 294 (2010)
- Han LF, Xu ZL, Cao Y, Wei YM, Xu HT, J. Membr. Sci., 372(1-2), 154 (2011)
- Mansourpanah Y, Gheshlaghi A, J. Polym. Res., 19(13), 1 (2012)
- Xu ZL, Qusay FA, J. Membr. Sci., 233(1-2), 101 (2004)
- Ghasem N, Al-Marzouqi M, Zhu LP, Sep. Purif. Technol., 92, 1 (2012)
- Gabelman A, Hwang ST, J. Membr. Sci., 159(1-2), 61 (1999)
- Zheng DQ, Guo TM, Knapp H, Fluid Phase Equilib., 129(1-2), 197 (1997)
- Kreulen H, Smolders CA, Versteeg GF, van Swaaij WPM, J. Membr. Sci., 78, 197 (1993)
- Rezaei M, Ismail AF, Bakeri G, Hashemifard SA, Matsuura T, Chem. Eng. J., 260, 875 (2015)
- Park HH, Lim CW, Jo HD, Choi WK, Lee HK, Korean J. Chem. Eng., 24(4), 693 (2007)
- Mansourizadeh A, Ismail AF, Abdullah MS, Ng BC, J. Membr. Sci., 355(1-2), 200 (2010)
- Bakeri G, Ismail AF, Rana D, Matsuura T, Chem. Eng. J., 198-199, 327 (2012)
- Srisurichan S, Jiraratananon R, Fane AG, J. Membr. Sci., 277(1-2), 186 (2006)
- Bakeri G, Matsuura T, Ismail AF, J. Membr. Sci., 383(1-2), 159 (2011)
- Loh CH, Wang R, Chin. J. Chem. Eng., 20(1), 71 (2012)
- Alsalhy QF, Salih HA, Simone S, Zablouk M, Drioli E, Figoli A, Desalination, 345, 21 (2014)
- Fontananova E, Jansen JC, Cristiano A, Curcio E, Drioli E, Desalination, 192(1-3), 190 (2006)
- Bakeri G, Ismail AF, DashtArzhandi MR, Matsuura T, J. Membr. Sci., 475, 57 (2015)
- Li JL, Chen BH, Sep. Purif. Technol., 41(2), 109 (2005)