화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.47, 154-168, March, 2017
DOI10.1016/j.jiec.2016.11.027  Export Citation
Corrosion and cathodic disbondment resistance of epoxy coating on zinc phosphate conversion coating containing Ni2+ and Co2+
M. Golabadi, M. Aliofkhazraei†, M. Toorani, and A. Sabour Rouhaghdam
  • Department of Materials Engineering, Faculty of Engineering, Tarbiat Modares University, Tehran, Iran
E-mail:
In this study, surface morphology, composition and anti-corrosion properties of zinc phosphate conversion coating with nickel and cobalt additives were investigated. In the second step, the phosphated coating was used as the pretreatment for the epoxy coating. The results showed that the corrosion resistance of phosphated coating containing additives has been increased significantly. The phosphated coating containing mixture of additives formed on the surface, has lower porosity and higher compaction than other samples. Also by adding a mixture of additives to the composition of the phosphated coating, adhesion strength and resistance to the cathodic disbondment of organic coatings were increased.
Keywords:Phosphate coating;Ni2+ and Co2+ additive;Epoxy coating;EIS;Cathodic disbondment;Adhesion
  1. Cho K, Rao VS, Kwon H, Electrochim. Acta, 52(13), 4449 (2007)
  2. Kalaee M, Akhlaghi S, Nouri A, Mazinani S, Mortezaei M, Afshari M, Mostafanezhad D, Allahbakhsh A, Dehaghi HA, Amirsadri A, Gohar DP, Prog. Org. Coat., 71, 173 (2011)
  3. Harun M, Marsh J, Lyon S, Prog. Org. Coat., 54, 317 (2005)
  4. Bajat J, Miskovic-Stankovic V, Bibic N, Drazic D, Prog. Org. Coat., 58, 323 (2007)
  5. Bajat J, Misovic-Stankovic V, Popic J, Drazic D, Prog. Org. Coat., 63, 201 (2008)
  6. Vaca-Cortes E, Lorenzo MA, Jirsa JO, Wheat HG, Carrasquillo RL, Research Report, Center for Transportation Research, 1998, pp. 1.
  7. Zhang X, Sloof W, Hovestad A, Van Westing E, Terryn H, De Wit J, Surf. Coat. Technol., 197, 168 (2005)
  8. Deflorian F, Rossi S, Fedrizzi L, Bonora P, Prog. Org. Coat., 52, 271 (2005)
  9. Bamoulid L, Maurette MT, De Caro D, Guenbour A, Bachir AB, Aries L, El Hajjaji S, Benoit-Marquie F, Ansart F, Surf. Coat. Technol., 202, 5020 (2008)
  10. Palraj S, Selvaraj M, Jayakrishnan P, Prog. Org. Coat., 54, 5 (2005)
  11. Freeman DB, Phosphating and Metal Pretreatment, 229, Woodhead-Faulkner, Cambridge, 1986, pp. 30.
  12. Lin BI, Lu JT, Kong G, Surf. Coat. Technol., 202, 1831 (2008)
  13. Akhtar A, Susac D, Glaze P, Wong K, Wong P, Mitchell K, Surf. Coat. Technol., 187, 208 (2004)
  14. Song Y, Mansfeld F, Corrosion Sci., 48, 154 (2006)
  15. Zimmermann D, Munoz AG, Schultze JW, Electrochim. Acta, 48(20-22), 3267 (2003)
  16. Zarei A, Afshar A, Mater. Process. Prop., 28, 615 (2009)
  17. Tsai CY, Liu JS, Chen PL, Lin CS, Corrosion Sci., 52, 3385 (2010)
  18. Li G, Niu L, Lian J, Jiang Z, Surf. Coat. Technol., 176, 215 (2004)
  19. Sandu AV, Ciomaga A, Nemtoi G, Bejinariu C, Sandu I, Microsc. Res. Tech., 75, 1711 (2012)
  20. Sandu A, Ciomaga A, Nemtoi G, Bejinariu C, Sandu I, J. Optoelectron. Adv. Mater., 14, 704 (2012)
  21. Sandu AV, Bejinariu C, Nemtoi G, Sandu IG, Vizureanu P, Ionita I, Baciu C, Rev. Chim., 64, 825 (2013)
  22. Rosalbino F, Scavino G, Mortarino G, Angelini E, Lunazzi G, J. Solid State Electrochem., 15, 703 (2011)
  23. Akhtar A, Susac D, Wong K, Wong P, Mitchell K, Surface Science Studies of the Effect of Mn2+ on Zinc Phosphating of 2024-T3 Al Alloy, Trans Tech Publications, 2006, pp. 753.
  24. Sun X, Susac D, Li R, Wong K, Foster T, Mitchell K, Surf. Coat. Technol., 155, 46 (2002)
  25. Banczek E, Rodrigues P, Costa I, Surf. Coat. Technol., 202 (2008)
  26. Shin AS, Shon MY, J. Ind. Eng. Chem., 16(6), 884 (2010)
  27. Ghanbari A, Attar MM, Appl. Surf. Sci., 316, 429 (2014)
  28. Ramezanzadeh B, Attar M, Farzam M, Surf. Coat. Technol., 205, 874 (2010)
  29. Tamilselvi M, Kamaraj P, Arthanareeswari M, Devikala S, Selvi JA, Appl. Surf. Sci., 332, 12 (2015)
  30. Kumar A, Bhola S, Majumdar JD, Surf. Coat. Technol., 206, 3693 (2012)
  31. D’Agostino AT, Anal. Chim. Acta, 262, 269 (1992)
  32. Pourbaix M, Atlas of Electrochemical Equilibria in Aqueous Solution, NACE, Houston, Texas, 1974, pp. 140.
  33. Su HY, Lin CS, Corrosion Sci., 83, 137 (2014)
  34. Haynes WM, CRC Handbook of Chemistry and Physics, CRC Press, 2014.
  35. Shannon RT, Acta Crystallogr. Sect. A, 32, 751 (1976)
  36. Li D, Neumann A, J. Colloid Interface Sci., 137, 304 (1990)
  37. Mirabedini S, Moradian S, Iran. Semin. Polym. Sci. Technol., 6, 12 (2003)
  38. Weng D, Jokiel P, Uebleis A, Boehni H, Surf. Coat. Technol., 88, 147 (1997)
  39. Notter I, Gabe D, Corros. Rev., 10, 217 (1992)
  40. Umoren S, Gasem Z, J. Dispersion Sci. Technol., 35, 1181 (2014)
  41. Lins VD, Reis GFD, de Araujo CR, Matencio T, Appl. Surf. Sci., 253(5), 2875 (2006)
  42. Zhang K, Xu B, Yang W, Yin X, Liu Y, Chen Y, Corrosion Sci., 90, 284 (2015)
  43. Popova A, Raicheva S, Sokolova E, Christov M, Langmuir, 12(8), 2083 (1996)
  44. Ramezanzadeh B, Attar MM, Mater. Chem. Phys., 130(3), 1208 (2011)
  45. Romagnoli R, Vetere V, Corrosion, 51, 116 (1995)
  46. Song GL, Shi Z, Corrosion Sci., 85, 126 (2014)
  47. Negm NA, Kandile NG, Badr EA, Mohammed MA, Corrosion Sci., 65, 94 (2012)
  48. Markhali B, Naderi R, Mahdavian M, Sayebani M, Arman S, Corrosion Sci., 75, 269 (2013)
  49. Hosseini M, Jafari M, Najjar R, Surf. Coat. Technol., 206, 280 (2011)
  50. Lu XP, Blawert C, Huang YD, Ovri H, Zheludkevich ML, Kainer KU, Electrochim. Acta, 187, 20 (2016)
  51. Zand BN, Mahdavian M, Electrochim. Acta, 52(23), 6438 (2007)
  52. Zubielewicz M, Gnot W, Prog. Org. Coat., 49, 358 (2004)
  53. Mahdavian M, Attar MM, Electrochim. Acta, 50(24), 4645 (2005)
  54. Naderi R, Attar M, Corrosion Sci., 51, 1671 (2009)
  55. Naderi R, Mahdavian M, Attar MM, Electrochim. Acta, 54(27), 6892 (2009)
  56. Alibakhshi E, Ghasemi E, Mahdavian M, Prog. Color Color. Coat., 5, 91 (2012)
  57. Grundmeier G, Stratmann M, Annu. Rev. Mater. Res., 35, 571 (2005)
  58. Ogle K, Morel S, Meddahi N, Corrosion Sci., 47, 2034 (2005)
  59. Sørensen PA, Dam-Johansen K, Weinell C, Kiil S, Prog. Org. Coat., 68, 70 (2010)
  60. Dong CF, Fu AQ, Li XG, Cheng YF, Electrochim. Acta, 54(2), 628 (2008)
  61. Legghe E, Aragon E, Belec L, Margaillan A, Melot D, Prog. Org. Coat., 66, 276 (2009)
  62. Ghaffari M, Naderi R, Sayehbani M, Prog. Org. Coat., 86, 117 (2015)