화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.48, 224-229, April, 2017
DOI10.1016/j.jiec.2017.01.005  Export Citation
Anti-fouling ultrafiltration membrane made from surface saponification of poly(vinyl acetate-co-vinyl pivalate) with enhanced syndiotacticity
Jintae Kim, Seong-Cheol Kim†, Hongsik Byun1, Young-Suk Jung2, and PilHo Huhd1
  • School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea
  • 1Department of Polymer Science & Engineering, Pusan National University, Pusan 609-735, Republic of Korea
  • 2College of Pharmacy, Pusan National University, Pusan 609-735, Republic of Korea
E-mail:
Syndiotactic poly(vinyl acetate-co-vinyl pivalate) was synthesized for the fabrication of anti-fouling membranes. The mechanical strength of the syndiotactic PVA membrane was retained by a selective surface saponification reaction and the solubility of PVA on the surface was reduced by introducing syndiotacticity. The selective saponification reaction of the membrane was monitored by FT-IR and contact angle measurements. The fouling resistance was analyzed by measuring the flux of the protein solution as well as the adsorption of humic acid and E. coli on the membrane surface. The surface modification of the syndiotactic polymer membrane provided good mechanical strength and better biofouling resistance.
Keywords:PVA;Tacticity;Saponification;Ultrafiltration;Biofouling
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