Bimetallic Au/Ag nanoframes as spectator for Co2+ ion

Heyjin Lee; Hwa Kyung Sung; Chulhwan Park; Younghun Kim

Journal of Industrial and Engineering Chemistry, Vol.48, 235-241, April, 2017

DOI10.1016/j.jiec.2017.01.007 Export Citation

Bimetallic Au/Ag nanoframes as spectator for Co2+ ion

Heyjin Lee, Hwa Kyung Sung¹, Chulhwan Park, and Younghun Kim^†

Department of Chemical Engineering, Kwangwoon University, Kwangwoon-ro 20, Nowon-gu,Seoul 01897, Republic of Korea
¹National Institute of Environmental Research, Hwangyong-ro 42, Seo-gu, Incheon 22689, Republic of Korea

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A highly sensitive colorimetric sensing methodology based on glutathione (GSH)-modified silver nanoparticles (AgNP) for the selective analysis for Co2+ ions is reported. We attempted to enhance the chemical stability of AgNPs in low pH condition by additional treatments such as sulfidation and galvanic replacement reaction (GRR). Bimetallic Au/Ag nanoframes (Au/AgNF) with center-open nanostructures were prepared via GRR, and the selective detection of Co2+ ion was evaluated at various concentrations. GSH-Au/AgNF has good linearity between concentration of Co2+ ion and absorbance intensity in UV-vis spectra, and thus allows a rapidly quantitative assay of Co2+ down to 1.7 μM.

Keywords:Colorimetric detection;Bimetallic nanoparticles;Heavy metal ions;Spectator

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[Referenced By]

[1] Yao Y, Tian D, Li H, ACS Appl. Mater. Interfaces, 2, 684 (2010)

[2] Dou Y, Yang X, Liu Z, Zhu S, Colloids Surf. A: Physicochem. Eng. Asp., 423, 20 (2013)

[3] Pike SD, White ER, Shaffer MSP, Williams CK, Nat. Commun., 7, 13008 (2016)

[4] Slocik JM, Zabinski J, Phillips DM, Naik RR, Small, 4, 548 (2008)

[5] Zhang F, Zeng L, Zhang Y, Wang H, Wu A, Nanoscale, 3, 2150 (2011)

[6] Liu DB, Qu WS, Chen WW, Zhang W, Wang Z, Jiang X, Anal. Chem., 82, 9606 (2010)

[7] Kalluri JR, Arbneshi T, Khan SA, Neely A, Candice P, Varisli B, Washington M, McAfee S, Robinson B, Banerjee S, Singh AK, Senapati D, Ray PC, Angew. Chem.-Int. Edit., 48, 9668 (2009)

[8] Sung HK, Oh SY, Park C, Kim Y, Langmuir, 29(28), 8978 (2013)

[9] Chen L, Fu X, Lu W, Chen L, ACS Appl. Mater. Interfaces, 5, 284 (2013)

[10] Zhang Z, Zhang J, Lou T, Pan D, Chen L, Qu C, Chen Z, Analyst, 137, 400 (2012)

[11] Chen L, Li J, Chen L, ACS Appl. Mater. Interfaces, 6, 15897 (2014)

[12] Wang X, Hou H, Li Y, Wang Y, Hao C, Ge C, J. Ind. Eng. Chem., 41, 82 (2016)

[13] Zhang ZY, Chen ZP, Pan DW, Chen LX, Langmuir, 31(1), 643 (2015)

[14] Levard C, Hotze EM, Lowry GV, Brown GE, Environ. Sci. Technol., 46, 6900 (2012)

[15] Sung HK, Kim Y, Mater. Lett., 145, 154 (2015)

[16] Zhang C, Luo L, Luo J, Evans DG, Sun X, Chem. Commun., 48, 7241 (2012)

[17] Roh J, Yi J, Kim Y, Langmuir, 26(14), 11621 (2010)

[18] Chen Z, He YJ, Luo SL, Lin HL, Chen YF, Sheng PT, Li JX, Chen BB, Liu CB, Cai QY, Analyst, 135, 1066 (2010)

[19] Xue C, Mirkin CA, Angew. Chem.-Int. Edit., 119, 2082 (2007)

[20] Roh J, Umh HN, Sung HK, Lee B, Kim Y, Colloids Surf. A: Physicochem. Eng. Asp., 415, 449 (2012)

[21] Fang F, Kong LT, Huang JR, Wu SB, Zhang KS, Wang XL, Sun B, Jin Z, Wang J, Huang XJ, Liu JH, J. Hazard. Mater., 270, 1 (2014)

[22] Aherne D, Charles DE, Brennan-Fournet ME, Kelly JM, Gun'ko YK, Langmuir, 25(17), 10165 (2009)

[23] Metraux GS, Gao YC, Jin R, Mirkin CA, Nano Lett., 3, 519 (2003)

[24] Sun YA, Xia YN, Adv. Mater., 15(9), 695 (2003)

[25] Wu XM, Redmond PL, Liu HT, Chen YH, Steigerwald M, Brus L, J. Am. Chem. Soc., 130(29), 9500 (2008)

[26] Redmond PL, Wu X, Brus L, J. Phys. Chem. C, 111, 8942 (2007)

[27] Tsuji M, Hamasaki M, Yajima A, Hattori M, Tsuji T, Kawazumi H, Mater. Lett., 121, 113 (2014)

[28] Bala T, Prasad BLV, Sastry M, Kahaly MU, Waghmare UVJ, J. Phys. Chem. A, 111, 6183 (2007)

[29] Baruwati B, Polshettiwar V, Varma RS, Green Chem., 11, 926 (2009)

[30] El-Safty SA, Adsorption, 15, 227 (2009)

[31] Zhou Y, Zhao H, He Y, Ding N, Cao Q, Colloids Surf. A: Physicochem. Eng. Asp., 391, 179 (2011)