Iron hexacyanoferrate/graphene/carbon fibers composite (PB/GN/CFs) was prepared by electrochemical method. Characterization of PB/GN/CFs in a separated adsorption and electrically switched ion exchange desorption processes (Ads-ESIX) of cesium ions (Cs+) was confirmed by FE-SEM, XRD, IR, XPS and electrochemistry techniques. PB/GN/CFs displayed two quasi reversible transformations from Fe-4(III)(Fe-II(CN)(6))(3) to Fe-4(III)(Fe-III(CN)(6)Cl)(3), or to (NH4)(4)Fe-4(II)[Fe-II(CN)(6)](3) at a potential range of -0.1-1.2 V in pH 2, 0.1 M NH4Cl. The recovery of Cs+ was investigated by PB/GN/CFs using Ads-ESIX method. Cs+ could be selectively adsorbed by PB/GN/CFs from aqueous solution in pH 7.0, and desorbed in pH 2, 0.1 M NH4Cl. The desorption rate of Cs+ depended on the introduction of potential at PB/GN/CFs in pH 2, 0.1 M NH4Cl. Both H3O+ and NH4+ could play dual role of electrolyte and competitor for the desorption of Cs+. PB/GN/CFs could be used to the recovery of Cs+ from the residual salt lake brine in which potasium had been removed from Qarham playa of Qaidam Basin in China. (C) 2017 Elsevier Ltd. All rights reserved.