One-pot synthesis of high fructose corn syrup directly from starch with SO42./USY solid catalyst

Yong Sun; Caixia Xiong; Huihui Chen; Xianhai Zeng; Xing Tang; Tingzhou Lei; Lu Lin

Korean Journal of Chemical Engineering, Vol.34, No.7, 1924-1929, July, 2017

DOI10.1007/s11814-017-0098-x Export Citation

One-pot synthesis of high fructose corn syrup directly from starch with SO42./USY solid catalyst

Yong Sun^†, Caixia Xiong, Huihui Chen, Xianhai Zeng, Xing Tang, Tingzhou Lei¹, and Lu Lin^†

*Xiamen Key Laboratory of High-valued Conversion Technology of Agricultural Biomass, College of Energy, Xiamen University, Xiamen 361102, China
¹Henan Key Laboratory of Biomass Energy, Huayuan Road 29, Zhengzhou, Henan 450008, China

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An efficient process was developed for the conversion of starch directly into high fructose corn syrup (HFCS) by using SO4 2-/USY solid catalyst in water. The SO4 2-/USY catalyst was found to act as a bifunctional catalyst with high activity for both hydrolysis of starch and isomerization of glucose, achieving a one-step preparation path of HFCS from starch. An optimal HFCS yield, containing 58.34% glucose and 27.84% fructose (mass fraction), was obtained at 150 °C for only 1 h.

Keywords:Starch;HFCS;SO4 2./USY Catalyst;Hydrolysis;Isomerization

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[1] Tordoff MG, Alleva AM, Am. J. Clin. Nutr., 51, 963 (1990)

[2] Duffey KJ, Popkin BM, Am. J. Clin. Nutr., 88, 1722 (2008)

[3] Zhang Y, Hidajat K, Ray AK, Biochem. Eng. J., 21, 111 (2004)

[4] Oh YH, Eom IY, Joo JC, Yu JH, Song BK, Lee SH, Hong SH, Park SJ, Korean J. Chem. Eng., 32(10), 1945 (2015)

[5] Jeong J, Antonyraj CA, Shin S, Kim S, Kim B, Lee KY, Cho JK, J. Ind. Eng. Chem., 19(4), 1106 (2013)

[6] Buchholz K, Seibel J, Carbohydr. Res., 343, 1966 (2008)

[7] Corma A, Iborra S, Velty A, Chem. Rev., 107(6), 2411 (2007)

[8] Thananatthanachon T, Rauchfuss TB, Angew. Chem.-Int. Edit., 49, 6616 (2010)

[9] Son PA, Nishimura S, Ebitani K, React. Kinet. Mech. Cata., 106, 185 (2012)

[10] Song YS, Kim JE, Park C, Kim SW, Korean J. Chem. Eng., 28(4), 1096 (2011)

[11] Roman-Leshkov Y, Moliner M, Labinger JA. Davis ME, Angew. Chem.-Int. Edit., 49, 8954 (2010)

[12] Kooyman C, Vellenga K, De Wilt H, Carbohydr. Res., 54, 33 (1977)

[13] Moliner M, Roman-Leshkov Y, Davis ME, Proc. Natl. Acad. Sci. U.S.A., 107, 6164 (2010)

[14] Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)

[15] Knill CJ, Kennedy JF, Carbohydr. Polym., 51, 281 (2003)

[16] Yang BY, Montgomery R, Carbohydr. Res., 280, 27 (1996)

[17] Vuorinen T, Sjostrom E, Carbohydr. Res., 108, 23 (1982)

[18] Mao DS, Lu GZ, Chen QL, Lu WK, Petrochem. Technol., 30, 152 (2001)

[19] Liu HP, Zhou P, Lv LH, Petrochem. Technol., 32, 108 (2003)

[20] Vekariya RH, Prajapati NP, Patel HD, Synth. Commun., 46, 1713 (2016)

[21] Qin X, Zhao W, Han B, Liu B, Lian B, Wu S, Korean J. Chem. Eng., 32(6), 1064 (2015)

[22] Testova N, Paukshtis E, Ione K, React. Kinet. Catal. Lett., 44, 243 (1991)

[23] Zhou P, Wang XP, Cai TX, Chin. Chem. Lett., 13, 1013 (2002)

[24] Won KY, Um BH, Kim SW, Oh KK, Korean J. Chem. Eng., 29(5), 614 (2012)

[25] Esmaeili N, Zohuriaan-Mehr MJ, Bouhendi H, Bagheri-Marandi G, Korean J. Chem. Eng., 33(6), 1964 (2016)

[26] Dee SJ, Bell AT, ChemSusChem, 4, 1166 (2011)

[27] Fan YZ, Cao FH, J. Chem. Eng. Chin. Univ., 25, 341 (2011)