화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.25, No.6, 504-512, June, 2017
DOI10.1007/s13233-017-5118-5  Export Citation
Iron and Copper Based Catalysts Containing Anionic Phenolate Ligands for Atom Transfer Radical Polymerization
Chiaki Nishiura, Valerie Williams, and Krzysztof Matyjaszewski†
  • Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, USA
E-mail:
Iron and copper complexes with anionic phenolate-bis(pyridyl)amine ligands were synthesized and examined as catalysts for atom transfer radical polymerization (ATRP) of methyl (meth)acrylate and styrene. With copper complexes, polymers with narrow molecular weight distributions, Mw/Mn ~1.2, were prepared. The catalytic performance of copper catalysts was affected by nature of halogen specie and by the steric and electronic effects. In iron-mediated ATRP procedures, the number-average molecular weights of the polymers increased with monomer conversion, however, the molecular weight distributions of the resulting polymers were relatively broad Mw/Mn~1.7, due to slow deactivation processes.
Keywords:atom transfer radical polymerization (ATRP);catalyst design;iron-mediated ATRP;green chemistry
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