화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 295-304, August, 2017
DOI10.1016/j.jiec.2017.03.059  Export Citation
Novel organic-inorganic hybrid polyvinylidene fluoride ultrafiltration membranes with antifouling and antibacterial properties by embedding N-halamine functionalized silica nanospheres
Han Wang, Zuo-Ming Wang1, Xi Yan, Jun Chen1, Wan-Zhong Lang†, and Ya-Jun Guo
  • The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry and Chemical Engineering, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, China
  • 1College of Life and Environment Sciences, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, China
E-mail:
Novel polyvinylidene fluoride (PVDF) hybrid ultrafiltration membranes with antifouling and antibacterial properties are prepared by embedding N-halamine functionalized silica nanospheres (HFSNs). With the addition of HFSNs, the antifouling properties of PVDF membranes are significantly improved. The results reveal that the highest pure water permeation flux of 559.8 L m-2 bar-1 h-1 is attained when the 0.6 wt% HFSNs is added in the casting solution. The membrane of M-3 with 0.9 wt% HFSNs addition shows the highest sterilization ratios of 97.1% and 97.0% against (escherichia coli) E. coli and (staphylococcus aureus) S. aureus respectively. After 6 times of inhibition-activation cycles, the membrane still remains 72.3% against E.coli.
Keywords:Polyvinylidenefluoride (PVDF);Ultrafiltration;N-halamine functionalized silica;nanospheres (HFSNs);Silica nanospheres;Antibacterial
  1. Yuliwati E, Ismail AF, Desalination, 273(1), 226 (2011)
  2. Rahimpour A, Madaeni SS, Amirinejad M, Mansourplanah Y, Zereshki S, J. Membr. Sci., 330(1-2), 189 (2009)
  3. Tang CY, Zhang Q, Wang K, Fu Q, Zhang CL, J. Membr. Sci., 337(1-2), 240 (2009)
  4. Choi JH, Jegal J, Kim WN, J. Membr. Sci., 284(1-2), 406 (2006)
  5. Zhang X, Lang WZ, Xu HP, Yan X, Guo YJ, Chu LF, J. Membr. Sci., 469, 458 (2014)
  6. Zhang F, Zhang WB, Yu Y, Deng B, Li JY, Jin J, J. Membr. Sci., 432, 25 (2013)
  7. Yan L, Li YS, Xiang CB, Xianda S, J. Membr. Sci., 276(1-2), 162 (2006)
  8. Wu H, Mansouri J, Chen V, J. Membr. Sci., 433, 135 (2013)
  9. Shen JN, Ruan HM, Wu LG, Gao CJ, Chem. Eng. J., 168(3), 1272 (2011)
  10. Zhang X, Lang WZ, Yan X, Lou ZY, Chen XF, J. Membr. Sci., 499, 179 (2016)
  11. Sawada I, Fachrul R, Ito T, Ohmukai Y, Maruyama T, Matsuyama H, J. Membr. Sci., 387-388, 1 (2012)
  12. Zhang JY, Zhang YT, Chen YF, Du L, Zhang B, Zhang HQ, Liu JD, Wang KJ, Ind. Eng. Chem. Res., 51(7), 3081 (2012)
  13. Liao CJ, Yu P, Zhao JQ, Wang LM, Luo YB, Desalination, 272(1-3), 59 (2011)
  14. Chen T, Liu X, Liu L, Zhang Y, Wang Z, Zhang Q, Synth. Met., 174, 1 (2013)
  15. Zhang B, Lin Y, Tang X, He S, Xie G, J. Rare Earths, 28, 451 (2010)
  16. Qiu JH, Zhang YW, Zhang YT, Zhang HQ, Liu JD, J. Colloid Interface Sci., 354(1), 152 (2011)
  17. Ciston S, Lueptow RM, Gray KA, J. Membr. Sci., 320(1-2), 101 (2008)
  18. Duan L, Huang W, Zhang Y, RSC Adv., 5, 6666 (2015)
  19. Li R, Hu P, Ren X, Worley SD, Huang TS, Carbohydr. Polym., 92, 534 (2013)
  20. Pan Y, Yu Z, Shi H, Chen Q, Zeng G, Di H, Ren X, He Y, J. Chem. Technol. Biotechnol., 92, 562 (2017)
  21. Liu S, Sun G, Ind. Eng. Chem. Res., 45(19), 6477 (2006)
  22. Worley SD, Sun G, Trends Polym. Sci., 4, 364 (1996)
  23. Sun YY, Sun G, Ind. Eng. Chem. Res., 43(17), 5015 (2004)
  24. Braun M, Sun YY, J. Polym. Sci. A: Polym. Chem., 42(15), 3818 (2004)
  25. Sun YY, Sun G, J. Appl. Polym. Sci., 88(4), 1032 (2003)
  26. Qian L, Sun G, J. Appl. Polym. Sci., 89(9), 2418 (2003)
  27. Worley S, Li F, Wu R Kim J, Wei CI, Williams J, Owens J, Wander J, Bargmeyer A, Shirtliff M, Surf. Coat. Int. B: Coat. Transact., 86, 273 (2003)
  28. Zhou CE, Kan CW, Appl. Surf. Sci., 328, 410 (2015)
  29. Cheng X, Li R, Du J, Sheng J, Ma K, Ren X, Huang TS, Polym. Adv. Technol., 26, 99 (2015)
  30. Zhao L, Yan X, Jie Z, Yang H, Yang S, Liang J, J. Nanopart. Res., 16, 1 (2014)
  31. Jie ZQ, Zhang B, Zhao LH, Yan XF, Liang J, J. Mater. Sci., 49(9), 3391 (2014)
  32. Stober W, Fink A, Bohn E, J. Colloid Interface Sci., 26, 62 (1968)
  33. Li ZK, Lang WZ, Miao W, Yan X, Guo YJ, J. Membr. Sci., 511, 151 (2016)
  34. Xu HP, Lang WZ, Yan X, Zhang X, Guo YJ, J. Membr. Sci., 467, 412 (2014)
  35. Kang B, Li YD, Liang J, Yan X, Chen J, Lang WZ, RSC Adv., 6, 1710 (2016)
  36. Lee S, Cha YC, Hwang HJ, Moon JW, Han IS, Mater. Lett., 61, 3130 (2007)
  37. Moore GE, Badger RM, J. Am. Chem. Soc., 74, 6076 (1952)
  38. Zhang FX, Srinivasan MP, Langmuir, 20(6), 2309 (2004)
  39. Wei XY, Wang Z, Zhang Z, Wang JX, Wang SC, J. Membr. Sci., 351(1-2), 222 (2010)
  40. Chen ZB, Sun YY, Ind. Eng. Chem. Res., 45(8), 2634 (2006)
  41. Bottino A, Camera-Roda G, Capannelli G, Munari S, J. Membr. Sci., 57, 1 (1991)
  42. Ng LY, Mohammad AW, Leo CP, Hilal N, Desalination, 308, 15 (2013)
  43. Yang X, Zhang B, Liu Z, Deng B, Yu M, Li L, Jiang H, Li J, J. Mater. Chem., 21, 11908 (2011)
  44. Cai Q, Bao S, Zhao Y, Zhao TY, Xiao LH, Gao G, Chokto H, Dong A, J. Colloid Interface Sci., 444, 1 (2015)
  45. Badrossamay MR, Sun G, React. Funct. Polym., 68(12), 1636 (2008)
  46. Natan M, Gutman O, Lavi R, Margel S, Banin E, ACS Nano, 9, 1175 (2015)
  47. Bastarrachea LJ, Goddard JM, J. Agric. Food Chem., 63 (2015)