화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 305-313, August, 2017
DOI10.1016/j.jiec.2017.04.001  Export Citation
Micrometer-sized nano-structured silicon/carbon composites for lithium-ion battery anodes synthesized based on a three-step Hansen solubility parameter (HSP) concept
Yee Hwa Sehlleier1, †, Sascha Dobrowolny2, Lisong Xiao1, Angelika Heinzel2, Christof Schulz1, 3, and Hartmut Wiggers1, 3
  • 1IVG, Institute for Combustion and Gas Dynamics, Reactive Fluids, University of Duisburg, Essen, Duisburg, Germany
  • 2Institute of Energy and Environmental Process Engineering, Department of Energy Technology, University of Duisburg-Essen, Duisburg, Germany
  • 3CENIDE, Center for Nanointegration Duisburg, Essen, Duisburg, Germany
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The processing towards Si/C composites, components and synthesis parameters were selected based on the concept of Hansen solubility parameters (HSP). Si/polymer composites were generated through modified bulk polymerization and subsequent pyrolysis transformed the polymer into the desired porous carbon matrix. Coulombic efficiencies (CE) in excess of 76% after the first cycle and 99.95% after solid electrolyte interphase (SEI) formation have been achieved. A notably high specific delithiation capacity of around 1600 mAh/g with an extremely stable cycling performance even after 400 cycles is obtained. This scalable and economical synthesis approach is readily applicable to the commercial production of anode materials.
Keywords:Nano silicon;Hansen solubility parameters;Pore formation mechanism;Gas phase synthesized nanoparticles;Lithium ion battery
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