화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 82-97, October, 2017
DOI10.1016/j.jiec.2017.05.021  Export Citation
Selective production of propylene from methanol over nanosheets of metal-substituted MFI zeolites
Naser Hadi, Reza Alizadeh†, and Aligholi Niaei1
  • Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran
  • 1Faculty of Chemical Engineering, University of Tabriz, Tabriz, Iran
E-mail:
The nanosheets of M-substituted (M: Mn, Ce, W) MFI zeolites were successfully synthesized via hydrothermal method. The catalysts were satisfactorily characterized by different techniques and the well synthesized nanostructures were approved. The prepared catalysts were examined in methanol to propylene process and showed improved performance compared to the conventional H-ZSM-5. The Wsubstituted MFI nanosheets productively represented the best performance with complete methanol conversion, propylene selectivity of 55.70%, total selectivity to light olefins of 88.04% and catalytic lifetime of 81 h. Furthermore, TGA and BET analyses were conducted to characterize the coke deposition. The lowest coke was detected on W-substituted MFI nanosheets.
Keywords:M-substituted (M: Mn;Ce;W) MFI zeolite;nanosheets;Methanol to propylene (MTP);Hydrothermal;C22-6-6Br2;Catalytic stability
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