화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 292-298, December, 2017
DOI10.1016/j.jiec.2017.07.022  Export Citation
Corrosion activity and solubility in polar oils of three bis (trifluoromethylsulfonyl) imide/bis(trifluoromethylsulfonyl) amide ([NTF2]) anion-based ionic liquids
A. Fernandez-Gonzalez1, †, M.T. Mallada2, J.L. Viesca3, 4, R. Gonzalez2, 4, R, Badia1, and A. Hernandez-Battez3, 4
  • 1Department of Physical and Analytical Chemistry, University of Oviedo, Asturias, Spain
  • 2Department of Marine Science and Technology, University of Oviedo, Asturias, Spain
  • 3Department of Construction and Manufacturing Engineering, University of Oviedo, Asturias, Spain
  • 4Department of Design and Engineering, Bournemouth University, Poole, BH12 5BB, UK
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The corrosion behaviour and solubility of three bis(trifluoromethylsulfonyl)amide1 ([NTf2]) anion-based ionic liquids: 1-dodecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([C12MIM][NTf2]), tributylmethylammonium bis(trifluoromethylsulfonyl)amide ([N4441][NTf2]), and methyltrioctylammo- nium bis(trifluoromethylsulfonyl)amide ([N1888][NTf2]), as a component in a mixture with different base oils were analysed. Six polar oils suitable for use in lubrication were utilized as base oil. Solubility tests were performed by using turbidimetry, and corrosion was checked at 4 v/v% by examining the roughness and chemical composition of the surface after 21 days. The results showed that long carbon chains in the cation improve the solubility greatly in diesters and slightly in polyolesters. Corrosion was not detected at this concentration.
Keywords:Ionic liquids;Corrosion;Solubility;Lubrication
  1. Willson GJ, Hollenkamp AF, Pandolfo AG, Chem. Int., 29(4) (2007)
  2. Brennecke JF, Maginn EJ, AIChE J., 47(11), 2384 (2001)
  3. Ye C, Liu W, Chen Y, Yu L, Chem. Commun., 21, 2244 (2001)
  4. Petkovic M, Seddon KR, Rebelo LPN, Pereira CS, Chem. Soc. Rev., 40, 1383 (2011)
  5. Van Rensselar J, Tribol. Lubr. Technol., 66(4), 24 (2010)
  6. Muhammad N, Elsheikh YA, Mutalib MIA, Bazmi AA, Khan RA, Khan H, Rafiq S, Man Z, khan I, J. Ind. Eng. Chem., 21, 1 (2015)
  7. Bermudez MD, Jimenez AE, Sanes J, Carrion FJ, Molecules, 14, 2888 (2009)
  8. Minami I, Molecules, 14, 2286 (2009)
  9. Palacio M, Bhushan B, Tribol. Lett., 40, 247 (2010)
  10. Somers A, Howlett P, MacFarlane D, Forsyth M, Lubricants, 1, 3 (2013)
  11. Zhou Y, Qu J, ACS Appl. Mater. Interfaces, 9(4), 3209 (2017)
  12. Iglesias P, Bermudez MD, Carrion FJ, Martinez-Nicolas G, Wear, 256(3-4), 386 (2004)
  13. Jimenez AE, Bermudez MD, Iglesias P, Carrion FJ, Martinez-Nicolas G, Wear, 260(7-8), 766 (2006)
  14. Liu W, Ye C, Gong Q, Wang H, Wang P, Tribol. Lett., 13, 81 (2002)
  15. Phillips BS, Zabinski JS, Tribol. Lett., 17, 533 (2004)
  16. Battez AH, Gonzalez R, Viesca JL, Blanco D, Asedegbega E, Osorio A, Wear, 266, 1224 (2009)
  17. Freire MG, Neves CMSS, Marrucho IM, Coutinho JAP, Fernandes AM, J. Phys. Chem. A, 114, 3744 (2009)
  18. Somers AE, Biddulph SM, Howlett PC, Sun J, MacFarlane DR, Forsyth M, Phys. Chem. Chem. Phys., 14, 8224 (2012)
  19. Otero I, Lopez ER, Reichelt M, Fernandez J, Tribol. Int., 70, 104 (2014)
  20. Minami I, Kita M, Kubo T, Nanao H, Mori S, Tribol. Lett., 30, 215 (2008)
  21. Gonzalez R, Battez AH, Blanco D, Viesca JL, Fernandez-Gonzalez A, Tribol. Lett., 40, 269 (2010)
  22. Blanco D, Gonzalez R, Battez AH, Viesca JL, Fernandez-Gonzalez A, Tribol. Int., 44, 645 (2011)
  23. Battez AH, Gonzalez T, Viesca JL, Fernandez-Gonzalez A, Hadfield M, Tribol. Int., 58, 71 (2013)
  24. Gonzalez R, Battez AH, Viesca JL, Higuera-Garrido A, Fernandez-Gonzalez A, Tribol. Trans., 56, 887 (2013)
  25. Viesca JL, Garcia A, Battez AH, Gonzalez R, Monge R, Fernandez-Gonzalez A, Hadfield M, Tribol Lett., 52, 431 (2013)
  26. Garcia A, Gonzalez R, Battez AH, Viesca JL, Monge R, Fernandez-Gonzalez A, Hadfield M, Tribol. Int., 72, 42 (2014)
  27. Monge R, Gonzalez R, Battez AH, Fernandez-Gonzalez A, Viesca JL, Garcia A, Hadfield M, Wear, 328-329, 50 (2015)
  28. Jimenez AE, Bermudez MD, Iglesias P, Carrion FJ, Martinez-Nicolas G, Wear, 260, 766 (2006)
  29. Qu J, Truhan JJ, Dai S, Luo H, Blau PJ, Tribol. Lett., 22, 207 (2006)
  30. Qu J, Blau PJ, Dai S, Luo H, Meyer HM, Tribol. Lett., 35, 181 (2009)
  31. Gonzalez R, Bartolome M, Blanco D, Viesca JL, Fernandez-Gonzalez A, Hernandez Battez A, Tribol. Int., 98, 82 (2016)
  32. Yu B, Bansal DG, Qu J, Sun X, Luo H, Dai S, Smolenski DJ, Wear, 289, 58 (2012)
  33. Fraser KJ, MacFarlane DR, Aust. J. Chem., 65, 309 (2009)
  34. Zhou F, Liang Y, Liu W, Chem. Soc. Rev., 38(9), 2590 (2009)
  35. Barnhill WC, Qu J, Luo H, Meyer III HM, Ma C, Chi M, Papke BL, ACS Appl. Mater. Interfaces, 6, 22585 (2014)
  36. Cann PM, Spikes HA, Tribol. Trans., 37, 580 (1994)
  37. Smeeth M, Gunsel S, Spikes HA, Tribol. Trans., 39(3), 726 (1996)
  38. Guangteng G, Smeeth M, Cann PM, Spikes HA, Proc. Inst. Mech. Eng. J., 210, 1 (1996)
  39. Rico JEF, Battez AH, Cuervo DG, Wear, 253, 827 (2002)
  40. Cambiella A, Benito JM, Pazos C, Coca J, Hernandez A, Fernandez JE, J. Mater. Process. Technol., 184, 139 (2007)
  41. Jimenez AE, Bermudez MD, Wear, 265, 787 (2008)
  42. Somers AE, Khemchandani B, Howlett PC, Sun J, Macfarlane DR, Forsyth M, ACS Appl. Mater. Interfaces, 5, 11544 (2013)
  43. Jimenez AE, Bermudez MD, Tribol.-Mater. Surf. Interfaces, 6, 109 (2012)
  44. Yao M, Liang Y, Xia Y, Zhou F, ACS Appl. Mater. Interfaces, 1, 467 (2009)
  45. Cai M, Liang Y, Zhou F, Liu W, Faraday Discuss., 156, 147 (2012)
  46. Zhang H, Xia Y, Yao M, Jia Z, Liu Z, Tribol. Lett., 36, 105 (2009)
  47. Kronberger M, Pejakovic V, Gabler C, Kalin M, Proc. Inst. Mech. Eng. Part J: J. Eng. Tribol. 226, 933 (2012).
  48. Pejakovic V, Kronberger M, Kalin M, Lubr. Sci., 26, 107 (2014)
  49. Pejakovic V, Kronberger M, Mahrova M, Vilas M, Tojo E, Kalin M, Proc. Inst. Mech. Eng. Part J: J. Eng. Tribol. 226, 293 (2012).
  50. Singh AK, Mohapatra S, Pani B, J. Ind. Eng. Chem., 33, 288 (2016)
  51. Gurten AA, Keles H, Bayol E, Kandemirli F, J. Ind. Eng. Chem., 27, 68 (2015)
  52. Xia G, Jiang X, Zhou L, Liao Y, Duan M, Wang H, Pu Q, Zhou J, J. Ind. Eng. Chem., 27, 133 (2015)
  53. Strassburg S, Bermudez H, Hoagland D, Biomacromolecules, 17(6), 2233 (2016)
  54. Stout KJ, Sullivan PJ, Dong WP, Mainsah E, Luo N, Mathia T, Zahouan H, (1993) Published on behalf of the Commission of the European Communities.
  55. Blanco D, Viesca JL, Mallada MT, Ramajo B, Gonzalez R, Battez AH, Surf. Coat. Technol., 302, 13 (2016)
  56. Miller NJ, Miller JC, Statistics and Chemometrics for Analytical Chemistry, 4th ed., Prentice Hall, 2000 ISBN: 0130228885.
  57. Bulmer MG, Principles of Statistics, 2nd ed., Courier Corporation, Dover, 1979 ISBN: 9780486637600.
  58. Marcus P, Grimal JM, Corrosion Sci., 33, 508 (1992)
  59. Tan BJ, Klabunde KJ, Sherwood PMA, Chem. Mater., 2, 186 (1990)