화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.27, 68-78, July, 2015
DOI10.1016/j.jiec.2014.11.046  Export Citation
The effect of temperature and concentration on the inhibition of acid corrosion of carbon steel by newly synthesized Schiff base
A. Ali Gurten†, Hulya Keles, Emel Bayol1, and Fatma Kandemirli2
  • Department of Chemistry, Arts and Sciences Faculty, Osmaniye Korkut Ata University, 80000 Osmaniye, Turkey, Korea
  • 1Department of Chemistry, Arts and Sciences Faculty, Nigde University, 51240 Nigde, Turkey
  • 2Biomedical Engineering Department, Faculty of Engineering and Architecture, Kastamonu University, 37200 Kastamonu, Turkey
E-mail:
Inhibition effect of Schiff base namely 1-(2-hydroxybenzylidene)-3-(2,5-dioxoimidazolidin-4-yl) urea (ALS) was studied on carbon steel corrosion in 1.0 M HCl by using the electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and linear polarization (LPR) and quantum chemical study. The values of activation energy (Ea), equilibrium constant (Kads), adsorption free energy ΔG°ads, adsorption enthalpy ΔH°ads and adsorption entropy ΔS°ads were discussed. The adsorption of inhibitor on metal followed Langmuir's adsorption isotherm. The thermodynamic parameters of adsorption reveal that there is a strong interaction between inhibitor and carbon steel. The highest inhibition efficiency was observed 5.0 × 10?4 M ALS concentration at 318 K. SEM and EDX observations confirmed the existence of protective inhibitor film on metal surface. Quantum chemical study supports the comparative inhibition effect of ALS.
Keywords:Corrosion;Carbon steel;Schiff base;AFM;Modeling study;Temperature
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