A flexible imprinted photonic resin film templated by nanocrystalline cellulose for naked-eye recognition of sulfonamides

Fusheng Zhang; Enxiu Liu; Xudong Zheng; Longbao Yu; Yongsheng Yan

Journal of Industrial and Engineering Chemistry, Vol.58, 172-178, February, 2018

DOI10.1016/j.jiec.2017.09.022 Export Citation

A flexible imprinted photonic resin film templated by nanocrystalline cellulose for naked-eye recognition of sulfonamides

Fusheng Zhang, Enxiu Liu, Xudong Zheng¹, Longbao Yu^†, and Yongsheng Yan

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China
¹School of Environment and Safety Engineering, Changzhou University, Changzhou 213164, PR China

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An optical sulfonamides sensor is fabricated based on a molecular imprinted resin templated by nanocrystalline cellulose. A chiral nematic imprinted composite film is synthesized which is subsequently treated with removal of templates to generate a red reflecting photonic film. The film shows a naked-eye color response to sulfanilamide, which is related to reassemble imprinted sites in the chiral nematic structure, resulting in a yellow reflecting film. Upon exposure to various antibiotics, it can be simultaneously in selectively response to three sulfonamides. This strategy facilitates enormously potential application of the resin as battery-free and portative optical monitoring sensors.

Keywords:Nanocrystalline cellulose;Molecular imprinted resin;Photonic film;Naked-eye recognition;Sulfonamides

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[3] Luo Y, Xu L, Rysz M, Wang Y, Zhang H, Alvarez PJJ, Environ. Sci. Technol., 45, 1827 (2011)

[4] Garcia-Galan MJ, Diaz-Cruz MS, Barcelo D, Environ. Int., 37, 462 (2011)

[5] Ding C, He JZ, Appl. Microbiol. Biotechnol., 87(3), 925 (2010)

[6] Xu LC, Pan JM, Dai JD, Li XX, Hang H, Cao ZJ, Yan YS, J. Hazard. Mater., 233, 48 (2012)

[7] Zamora-Galvez A, Ait-Lahcen A, Mercante LA, Morales-Narvaez E, Amine A, Merkoci A, Anal. Chem., 88, 3578 (2016)

[8] Ayankojo AG, Tretjakov A, Reut J, Boroznjak R, Opik A, Rappich J, Furchner A, Hinrichs K, Syritski V, Anal. Chem., 88, 1476 (2016)

[9] Moon JH, Yang S, Chem. Rev., 110(1), 547 (2010)

[10] Chen CW, Li CC, Jau HC, Yu LC, Hong CL, Guo DY, Wang CT, Lin TH, ACS Photonics, 2, 1524 (2015)

[11] Tudela AG, Hung CL, Chang DE, Cirac JI, Kimble HJ, Nat. Photonics, 9, 320 (2015)

[12] Ge J, Yin Y, Angew. Chem.-Int. Edit., 50, 1492 (2011)

[13] Fenzl C, Hirsch T, Wolfbeis OS, Angew. Chem.-Int. Edit., 53, 3318 (2014)

[14] Liu Y, Yu L, Jiang Y, Xiong W, Wang Q, Sun J, Yang H, Zhao XZ, Nano Energy, 26, 648 (2016)

[15] Hu XB, Li GT, Huang J, Zhang D, Qiu Y, Adv. Mater., 19(24), 4327 (2007)

[16] Zhao YJ, Zhao XW, Hu J, Li J, Xu WY, Gu ZZ, Angew. Chem.-Int. Edit., 48, 7350 (2009)

[17] Lu W, Asher SA, Meng ZH, Yan ZQ, Xue M, Qiu LL, Yi D, J. Hazard. Mater., 316, 87 (2016)

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[21] Kim DY, Nah C, Kang SW, Lee SH, Lee KM, White TJ, Jeong KU, ACS Nano, 10, 9570 (2016)

[22] Wang L, Li Q, Adv. Funct. Mater., 26(1), 10 (2016)

[23] Aida T, Meijer EW, Stupp SI, Science, 335(6070), 813 (2012)

[24] Stroganov V, Ryabchun A, Bobrovsky A, Shibaev V, Macromol. Rapid Commun., 33(21), 1875 (2012)

[25] Hsiao YC, Sung YC, Lee MJ, Lee W, Biomed. Opt. Express, 6, 5033 (2015)

[26] Moirangthem M, Arts R, Merkx M, Schenning APHJ, Adv. Funct. Mater., 26(8), 1154 (2016)

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[29] Shopsowitz KE, Hamad WY, MacLachlan MJ, J. Am. Chem. Soc., 134(2), 867 (2012)

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[31] Khan MK, Hamad WY, MacLachlan MJ, Adv. Mater., 26(15), 2323 (2014)

[32] Zhang F, Zheng X, Liu E, Yu L, Yan Y, J. Ind. Eng. Chem., 46, 397 (2017)

[33] Cachelin P, Green JP, Peijs T, Heeney M, Bastiaansen CWM, Adv. Opt. Mater., 4, 592 (2016)

[34] Wu T, Li J, Li J, Ye S, Wei J, Guo J, J. Mater. Chem., 4, 9687 (2016)

[35] Lu T, Pan H, Ma J, Li Y, Bokhari SW, Jiang XL, Zhu SM, Zhang D, ACS Appl. Mater. Interfaces, 9, 18231 (2017)

[36] Zheng XD, Pan JM, Zhang FS, Liu EL, Shi WD, Yan YS, Chem. Eng. J., 284, 879 (2016)

[37] Khan MK, Giese M, Yu M, Kelly JA, Hamad WY, MacLachlan MJ, Angew. Chem.-Int. Edit., 52, 8921 (2013)

[38] Khan MK, Bsoul A, Walus K, Hamad WY, MacLachlan MJ, Angew. Chem.-Int. Edit., 54, 4304 (2015)

[39] de H, Acta Crystallogr, 4, 219 (1951)