화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.59, 410-415, March, 2018
In situ growth of hollow Cu2O spheres using anionic vesicles as soft templates
E-mail:,
Geometrically optimizing anionic vesicles were fabricated using two types of anionic surfactants with antipodal molecular configuration. The influence of counterions on the anionic vesicles was systematically investigated to maintain electrostatic interaction between the anionic vesicles and the precursors, as well as to ensure the structural integrity of the vesicle templates. The transcription from vesicles to hollow Cu2O spheres was achieved through an in situ reduction approach. The obtained hollow Cu2O spheres were assembled by abundant nanoparticles around the vesicle interface and showed preferable adsorption capacity for methyl orange in the dark compared with the solid Cu2O spheres synthesized without any surfactants.
  1. Coughlan C, Ibanez M, Dobrozhan O, Singh A, Cabot A, Ryan KM, Chem. Rev., 117(9), 5865 (2017)
  2. Zangeneh H, Zinatizadeh AAL, Habibi M, Akia M, Isa MH, J. Ind. Eng. Chem., 26, 1 (2015)
  3. Kuo CH, Huang MH, Nano Today, 5(2), 106 (2010)
  4. Huang MH, Lin PH, Adv. Funct. Mater., 22(1), 14 (2012)
  5. Huang MH, Rej S, Hsu SC, Chem. Commun., 50, 1634 (2014)
  6. Prieto G, Tuysuz H, Duyckaerts N, Knossalla J, Wang GH, Schuth F, Chem. Rev., 116(22), 14056 (2016)
  7. Qi J, Lai X, Wang J, Tang H, Ren H, Yang Y, Jin Q, Zhang L, Yu R, Ma G, Su Z, Zhao H, Wang D, Chem. Soc. Rev., 44, 6749 (2015)
  8. Purbia R, Paria S, Nanoscale, 7, 19789 (2015)
  9. Sui Y, Fu W, Zeng Y, Yang H, Zhang Y, Chen H, Li Y, Li M, Zou G, Angew. Chem.-Int. Edit., 49, 4282 (2010)
  10. Kuo CH, Huang MH, J. Am. Chem. Soc., 130(38), 12815 (2008)
  11. Gao J, Li Q, Zhao H, Li L, Liu C, Gong Q, Qi L, Chem. Mater., 20, 6263 (2008)
  12. Zhang L, Wang H, ACS Nano, 5, 3257 (2011)
  13. Hung LI, Tsung CK, Huang WY, Yang PD, Adv. Mater., 22(17), 1910 (2010)
  14. Lu CH, Qi LM, Yang JH, Wang XY, Zhang DY, Xie JL, Ma JM, Adv. Mater., 17(21), 2562 (2005)
  15. Tian Q, Yu XJ, Zhang LF, Yu DM, J. Colloid Interface Sci., 491, 294 (2017)
  16. Luo XL, Li CY, Yang DS, Liu FL, Chen YH, Mater. Chem. Phys., 151, 252 (2015)
  17. Ma YR, Qi LM, J. Colloid Interface Sci., 335(1), 1 (2009)
  18. Luo XL, Wang MJ, Yang DS, Yang J, Chen YS, J. Ind. Eng. Chem., 32, 313 (2015)
  19. Dong RH, Liu WM, Hao JC, Acc. Chem. Res., 45, 504 (2012)
  20. Yin YD, Alivisatos AP, Nature, 437, 664 (2005)
  21. Jiang W, Zhou Y, Yan D, Chem. Soc. Rev., 44, 3874 (2015)
  22. Liu J, Qiao SZ, Hartono SB, Lu GQ, Angew. Chem.-Int. Edit., 49, 4981 (2010)
  23. Mai Y, Eisenberg A, J. Am. Chem. Soc., 132(29), 10078 (2010)
  24. Wu XJ, Xu DS, J. Am. Chem. Soc., 131(8), 2774 (2009)
  25. Du J, Sun H, ACS Appl. Mater. Interfaces, 6, 13535 (2014)
  26. Wang GH, Hilgert J, Richter FH, Wang F, Bongard HJ, Spliethoff B, Weidenthaler C, Schuth F, Nat. Mater., 13, 293 (2014)
  27. Gao X, Lu F, Dong B, Zhou T, Tian W, Zheng L, Chem. Commun., 50, 8783 (2014)
  28. Wang W, Han Y, Tian M, Fan Y, Tang Y, Gao M, Wang Y, Appl. Mater. Interfaces, 5, 5709 (2013)
  29. Li L, Wang ML, Chen Y, Jiang SC, J. Colloid Interface Sci., 387, 146 (2012)
  30. Zhang A, Ma Q, Lu M, Yu G, Zhou Y, Qiu Z, Cryst. Growth Des., 8, 2402 (2008)
  31. Wang JZ, Song AX, Jia XF, Hao JC, Liu WM, Hoffmann H, J. Phys. Chem. B, 109(22), 11126 (2005)
  32. Teng MM, Song AX, Liu LP, Hao JC, J. Phys. Chem. B, 112(6), 1671 (2008)
  33. Jin Y, Bi L, Shao Y, Dong S, Chem. Eur. J., 10, 3225 (2004)
  34. Zhang X, Li D, Angew. Chem.-Int. Edit., 45, 5971 (2006)
  35. Xu H, Wang W, Angew. Chem.-Int. Edit., 46, 1489 (2007)