Adsorption of AuCl 4 -  from Acidic Chloride Solution by Chemically Modified Lignin Based on Rice Straw

Baoping Zhang; Yun Liu; Zhongchen Ma; Meichen Guo; Bowen Shen

Macromolecular Research, Vol.26, No.2, 121-127, February, 2018

DOI10.1007/s13233-018-6016-1 Export Citation

Adsorption of AuCl 4 - from Acidic Chloride Solution by Chemically Modified Lignin Based on Rice Straw

Baoping Zhang^{1, 2}, Yun Liu^{1, 2, †}, Zhongchen Ma^{1, 2}, Meichen Guo^{1, 2}, and Bowen Shen^{1, 2}

¹The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei, 430081, P. R. China
²Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei, 430081, P. R. China

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The chemically modified lignin was synthesized based on rice straw and the adsorption properties of AuCl 4 - were investigated in this paper. The adsorbent was characterized by Fourier transform infrared spectrometer, scanning electronic microscope and thermogravimetric analysis and differential scanning calorimetry. The chemically modified rice straw lignin was of excellent thermal stability and had plenty of primary amines and hydroxyls. Many influence factors such as initial concentration of AuCl 4 - , adsorption time and concentration of hydrochloric acid on AuCl 4 - were optimized. The maximum adsorption capacity was 783.94 mg·g-1. The equilibrium adsorption time was 600 min. The equilibrium isotherm fitted well with the Langmuir model and the pseudo-second-order kinetic model was suitable for describing the adsorption of AuCl 4 - . Low hydrochloric acid concentration could promote the selectivity of adsorption on AuCl 4 - . Combination of ion exchange and reduction was the mechanism. AuCl 4 - was adsorbed by ion exchange first and then reduced from hydrochloric acid medium in the form of Au(0) by phenolic hydroxyl.

Keywords:lignin;AuCl4-;adsorption-reduction;selectivity

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[Referenced By]

[1] Kim JK, Ahn H, Macromol. Res., 16(2), 163 (2008)

[2] Pienpinijtham P, Thammacharoen C, Ekgasit S, Macromol. Res., 20(12), 1281 (2012)

[3] Crocket JH, Vincent EA, Wager LR, Geochim. Cosmochim. Acta, 14, 153 (1958)

[4] Syed S, Hydrometallurgy, 115-116, 30 (2012)

[5] Ranjbar R, Naderi M, Omidvar H, Amoabediny G, Hydrometallurgy, 143, 54 (2014)

[6] Kumar V, Lee J, Jeong J, Jha MK, Kim B, Singh R, J. Ind. Eng. Chem., 21, 805 (2015)

[7] Akcil A, Erust C, Gahan CS, Ozgun M, Sahin M, Tuncuk A, Waste Manage., 45, 258 (2015)

[8] Liu P, Liu GF, Chen DL, Chen SY, Tang N, Nonferr. Metal Soc., 19, 1509 (2009)

[9] Jin ZN, Ma ZY, Yang HY, Lin XJ, J. Northeast. Univ., Nat. Sci., 36, 1305 (2015)

[10] Kwak IS, Bae MA, Won SW, Mao J, Sneha K, Park J, Sathishkumar M, Yun YS, Chem. Eng. J., 165(2), 440 (2010)

[11] Chao HP, Chang CC, Nieva A, J. Ind. Eng. Chem., 20(5), 3408 (2014)

[12] Esfandiar N, Nasernejad B, Ebadi T, J. Ind. Eng. Chem., 20(5), 3726 (2014)

[13] Ju XH, Igarashi K, Miyashita S, Mitsuhashi H, Inagaki K, Fujii SI, Sawada H, Kuwabara T, Minoda A, Bioresour. Technol., 211, 759 (2016)

[14] Li MC, Ge X, Cho UR, Macromol. Res., 21(7), 793 (2013)

[15] Pumama P, Kim SH, Macromol. Res., 22(1), 74 (2014)

[16] Chen XJ, Cai JC, Zhang ZH, Liu LJ, Yang GL, Colloid Polym. Sci., 292, 2157 (2014)

[17] Ge Y, Li Z, Kong Y, Song Q, Wang K, J. Ind. Eng. Chem., 20(6), 4429 (2014)

[18] Lu S, Li HP, Zhang FG, Du N, Hou WG, Colloid Polym. Sci., 294, 1369 (2016)

[19] Nair V, Panigrahy A, Vinu R, Chem. Eng. J., 254, 491 (2014)

[20] Jorgetto AD, da Silva ACP, Wondracek MHP, Silva RIV, Valini ED, Saeki MJ, Pedrosa VA, Castro GR, Appl. Surf. Sci., 345, 81 (2015)

[21] Parajuli D, Inoue K, Kawakita H, Ohto K, Harada H, Funaoka M, Miner Eng., 21, 61 (2008)

[22] Parajuli D, Khunathai K, Adhikari CR, Inoue K, Ohto K, Kawakita H, Funaoka M, Hirota K, Miner. Eng., 22(13), 1173 (2009)

[23] Adhikari BB, Gurung M, Alam S, Tolnai B, Inoue K, Chem. Eng. J., 231, 190 (2013)

[24] Chandra, Mubarok MZ, Miner. Eng., 89, 1 (2016)

[25] Zhang BP, Ma ZC, Yang F, Liu Y, Guo MC, Colloids Surf. A: Physicochem. Eng. Asp., 514, 260 (2017)

[26] Zhang J, Zhou X, Zhou Z, Chen H, Chen L, Macromol. Res., 22(5), 515 (2014)

[27] Mohammed-Ziegler I, Grun A, Spectrochim. Acta A, 62, 506 (2005)

[28] Xiao JB, Chen XQ, Yu HZ, Xu M, Macromol. Res., 14(4), 443 (2006)

[29] Bhadra BN, Ahmed I, Jhung SH, Fuel, 174, 43 (2016)

[30] Adhikar CR, Parajuli D, Kawakita H, Ohto K, Inoue K, Harada H, New J. Chem., 32, 1634 (2008)

[31] Guo XY, Zhang SZ, Shan XQ, J. Hazard. Mater., 151(1), 134 (2008)

[32] He ZW, He LH, Yang J, Lu QF, Ind. Eng. Chem. Res., 52(11), 4103 (2013)

[33] Dwivedi AD, Dubey SP, Hokkanen S, Fallah RN, Sillanpaa M, Chem. Eng. J., 255, 97 (2014)

[34] Al-Saidi HM, J. Saudi Chem. Soc., 54, 615 (2013)

[35] Fırlak M, Yetimoglu EK, Kahraman MV, J. Water Process. Eng., 3, 105 (2014)

[36] Fan RY, Xie F, Guan XL, Zhang QL, Luo ZR, Bioresour. Technol., 163, 167 (2014)

[37] Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)