화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.60, 407-417, April, 2018
DOI10.1016/j.jiec.2017.11.028  Export Citation
Cyclic-carbonate functionalized polymer brushes on polymeric microspheres: Immobilized laccase for degradation of endocrine disturbing compounds
Gulay Bayramoglu1, 2, †, Bunyamin Karagoz3, and M. Yakup Arica2
  • 1Biochemical Processing and Biomaterial Research Laboratory, Gazi University, 06500 Teknikokullar, Ankara, Turkey
  • 2Department of Chemistry, Gazi University, 06500 Teknikokullar, Ankara, Turkey
  • 3Department of Chemistry, Istanbul Technical University, Maslak 34469, Istanbul, Turkey
E-mail:
A novel support material containing cyclic carbonate group for facile enzyme immobilization was synthesized from [poly(styrene-co-divinylbenzene)-graft-poly(glycidyl methacrylate)] “[PS-co-DVB-g-P (GMA)]” microsphere under carbon dioxide atmosphere. It was named as (poly(styrene-co- divinylbenzene)-graft-poly(cyclic-carbonate methacrylate)] “[PS-co-DVB-g-P(CCMA)]” microsphere. Laccase was covalently immobilized using the microspheres carrying cyclic epoxy and cyclic carbonate groups. The amount of enzyme loading on the cyclic carbonate groups of the microspheres was 47.8 mg/g. The immobilized enzyme was used for degradation of Bisphenol A, and Congo Red dye in packed bed reactor. The immobilized laccase preserved its initial activity about 67.5% and 93.0% for degradation of Bisphenol A and Conge Red, respectively.
Keywords:Immobilized laccase;Endocrine disturbance;Packed bed reactor;Environmental biotechnology;Nano-structured materials
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