Experimental method for simultaneous and continuous measurement of absorption rate, viscosity and heat of reaction of carbon dioxide capture solvents

Junghwan Kim; Huiyong Kim; Jayeop Kim; Sung June Hwang; Kwang Soon Lee

Journal of Industrial and Engineering Chemistry, Vol.61, 152-160, May, 2018

DOI10.1016/j.jiec.2017.12.012 Export Citation

Experimental method for simultaneous and continuous measurement of absorption rate, viscosity and heat of reaction of carbon dioxide capture solvents

Junghwan Kim, Huiyong Kim, Jayeop Kim, Sung June Hwang, and Kwang Soon Lee^†

Chemical and Biomolecular Engineering Department, Sogang University, 35 Baekbeom-ro, Mapogu, Seoul 121-742, Republic of Korea

E-mail:

When screening solvents for carbon capture, a large amount of property data for each solvent in the CO2- loaded state is required. In this paper, a novel experimental method is proposed that involves modifying a wetted wall column in order to simultaneously measure the absorption rate, viscosity, pH, and heat of reaction of carbon capture solvents while the CO2 loading is increased continuously. The proposed method was applied to 30 wt% aqueous monoethanolamine and 30 wt% aqueous piperazine as solvents and found to produce measurement results that matched well with literature data.

Keywords:Carbon dioxide capture;Solvent screening;Wetted wall column;Simultaneous measurements;Continuous measurements

[References]

Kim H, Hwang SJ, Lee KS, Environ. Sci. Technol., 49, 1478 (2015)
Puxty G, Rowland R, Allport A, Yang Q, Bown M, Burns R, Maeder M, Attalla M, Environ. Sci. Technol., 43, 6427 (2009)
Rochelle GT, Science, 325, 1652 (2009)
Dugas RE, Carbon Dioxide Absorption, Desorption, and Diffusion in Aqueous Piperazine and Monoethanolamine, The University of Texas at Austin, 2009.
Ghosh UK, Kentish SE, Stevens GW, Energy Procedia, 1, 1075 (2009)
Puxty G, Rowland R, Attalla M, Chem. Eng. Sci., 65(2), 915 (2010)
Behr P, Maun A, Deutgen K, Tunnat A, Oeljeklaus G, Gorner K, Energy Procedia, 4, 85 (2011)
Tunnat A, Behr P, Gorner K, Energy Procedia, 51, 197 (2014)
Aboudheir A, Tontiwachwuthikul P, Chakma A, Idem R, Chem. Eng. Sci., 58(23-24), 5195 (2003)
Liu HL, Liang ZW, Sema T, Rongwong W, Li C, Na YQ, Idem R, Tontiwachwuthikul P, Idem R, Tontiwachwuthikul P, AIChE J., 60(10), 3502 (2014)
Liu HL, Sema T, Liang ZW, Fu KY, Idem R, Na YQ, Tontiwachwuthikul P, Sep. Purif. Technol., 136, 81 (2014)
Kierzkowska-Pawlak H, Int. J. Greenh. Gas Control, 37, 76 (2015)
Lu BH, Wang XQ, Xia YF, Liu N, Li SJ, Li W, Energy Fuels, 27(10), 6002 (2013)
Kim I, Svendsen HF, Ind. Eng. Chem. Res., 46(17), 5803 (2007)
Mathias PM, O'Connell JP, Ind. Eng. Chem. Res., 51(13), 5090 (2012)
Seader JD, Henley EJ, Roper DK, Separation Process Principles, Wiley, 2017.
Hilliard MD, Predictive A, The University of Texas at Austin, 2008.
Chen X, The University of Texas at Austin, 2011.
Weiland RH, Dingman JC, Cronin DB, Browning GJ, J. Chem. Eng. Data, 43(3), 378 (1998)
Amundsen TG, Oi LE, Eimer DA, J. Chem. Eng. Data, 54(11), 3096 (2009)
Matin NS, Remias JE, Liu KL, Ind. Eng. Chem. Res., 52(47), 16979 (2013)
Hartono A, Mba EO, Svendsen HF, J. Chem. Eng. Data, 59(6), 1808 (2014)
Pacheco MA, Kaganoi S, Rochelle GT, Chem. Eng. Sci., 55(21), 5125 (2000)

[Referenced By]

[1] Kim H, Hwang SJ, Lee KS, Environ. Sci. Technol., 49, 1478 (2015)

[2] Puxty G, Rowland R, Allport A, Yang Q, Bown M, Burns R, Maeder M, Attalla M, Environ. Sci. Technol., 43, 6427 (2009)

[3] Rochelle GT, Science, 325, 1652 (2009)

[4] Dugas RE, Carbon Dioxide Absorption, Desorption, and Diffusion in Aqueous Piperazine and Monoethanolamine, The University of Texas at Austin, 2009.

[5] Ghosh UK, Kentish SE, Stevens GW, Energy Procedia, 1, 1075 (2009)

[6] Puxty G, Rowland R, Attalla M, Chem. Eng. Sci., 65(2), 915 (2010)

[7] Behr P, Maun A, Deutgen K, Tunnat A, Oeljeklaus G, Gorner K, Energy Procedia, 4, 85 (2011)

[8] Tunnat A, Behr P, Gorner K, Energy Procedia, 51, 197 (2014)

[9] Aboudheir A, Tontiwachwuthikul P, Chakma A, Idem R, Chem. Eng. Sci., 58(23-24), 5195 (2003)

[10] Liu HL, Liang ZW, Sema T, Rongwong W, Li C, Na YQ, Idem R, Tontiwachwuthikul P, Idem R, Tontiwachwuthikul P, AIChE J., 60(10), 3502 (2014)

[11] Liu HL, Sema T, Liang ZW, Fu KY, Idem R, Na YQ, Tontiwachwuthikul P, Sep. Purif. Technol., 136, 81 (2014)

[12] Kierzkowska-Pawlak H, Int. J. Greenh. Gas Control, 37, 76 (2015)

[13] Lu BH, Wang XQ, Xia YF, Liu N, Li SJ, Li W, Energy Fuels, 27(10), 6002 (2013)

[14] Kim I, Svendsen HF, Ind. Eng. Chem. Res., 46(17), 5803 (2007)

[15] Mathias PM, O'Connell JP, Ind. Eng. Chem. Res., 51(13), 5090 (2012)

[16] Seader JD, Henley EJ, Roper DK, Separation Process Principles, Wiley, 2017.

[17] Hilliard MD, Predictive A, The University of Texas at Austin, 2008.

[18] Chen X, The University of Texas at Austin, 2011.

[19] Weiland RH, Dingman JC, Cronin DB, Browning GJ, J. Chem. Eng. Data, 43(3), 378 (1998)

[20] Amundsen TG, Oi LE, Eimer DA, J. Chem. Eng. Data, 54(11), 3096 (2009)

[21] Matin NS, Remias JE, Liu KL, Ind. Eng. Chem. Res., 52(47), 16979 (2013)

[22] Hartono A, Mba EO, Svendsen HF, J. Chem. Eng. Data, 59(6), 1808 (2014)

[23] Pacheco MA, Kaganoi S, Rochelle GT, Chem. Eng. Sci., 55(21), 5125 (2000)