화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.61, 161-168, May, 2018
DOI10.1016/j.jiec.2017.12.013  Export Citation
Entrapment of ball-milled biochar in Ca-alginate beads for the removal of aqueous Cd(II)
Bing Wang1, 2, Bin Gao2, †, and Yongshan Wan3
  • 1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
  • 2Department of Agricultural and Biological Engineering, University of Florida, Gainesville, FL 32611, USA
  • 3National Health and Environmental Effects Research Laboratory, US EPA, Gulf Breeze, FL 32561, USA
E-mail:
A novel adsorbent was synthesized through the entrapment of ball-milled biochar in Ca-alginate beads for the removal of aqueous Cd(II). Batch adsorption experiments were conducted to compare Cd(II) adsorption characteristics of ball-milled biochar (BMB), Ca-alginate (CA), and Ca-alginate entrapped ballmilled biochar (CA-BMB). All the tested adsorbents showed excellent sorption ability. The maximum Cd (II) adsorption capacity estimated with Langmuir isotherm modeling was 251.8 mg g-1 for CA, 227.1 mg g-1 for CA-BMB, and 40.0 mg g-1 for BMB. The results demonstrate that entrapment of ballmilled biochar in Ca-alginate provides a low-cost and high-effective way for the removal of aqueous Cd (II).
Keywords:Composite adsorbent;Ball milling;Cadmium;Wastewater;Adsorption
  1. Ghosh D, Saha R, Ghosh A, Nandi R, Saha B, Desalin. Water Treat., 53, 413 (2015)
  2. Zhao Q, Wang Y, Cao Y, Chen A, Ren M, Ge Y, Yu Z, Wan S, Hu A, Bo Q, Ruan L, Chen H, Qin S, Chen W, Hu C, Tao F, Xu D, Xu J, Wen L, Li L, Sci. Total Environ., 407-471, 340 (2014)
  3. Li Z, Ma Z, van der Kuijp TJ, Yuan Z, Huang L, Sci. Total Environ., 468-469, 843 (2014)
  4. Bailey SE, Olin TJ, Bricka RM, Adrian DD, Water Res., 33, 2649 (1999)
  5. Xu M, Hadi P, Chen GH, Mckay G, J. Hazard. Mater., 273, 118 (2014)
  6. Luo XG, Zhang LN, J. Hazard. Mater., 171(1-3), 340 (2009)
  7. Ahmad M, Rajapaksha AU, Lim JE, Zhang M, Bolan N, Mohan D, Vithanage M, Lee SS, Ok YS, Chemosphere, 99, 19 (2014)
  8. Mohan D, Sarswat A, Ok YS, Pittman CU, Bioresour. Technol., 160, 191 (2014)
  9. Inyang MI, Gao B, Yao Y, Xue Y, Zimmerman A, Mosa A, Pullammanappallil P, Ok YS, Cao X, Crit. Rev. Environ. Sci. Technol., 46, 406 (2016)
  10. Xu X, Cao X, Zhao L, Wang H, Yu H, Gao B, Environ. Sci. Pollut. Res., 20, 358 (2013)
  11. Wang FY, Wang H, Ma JW, J. Hazard. Mater., 177(1-3), 300 (2010)
  12. Wu H, Lai C, Zeng G, Liang J, Chen J, Xu J, Dai J, Li X, Liu J, Chen M, Lu L, Hu L, Wan J, Crit. Rev. Biotechnol., 37, 754 (2017)
  13. Zeng G, Wu H, Liang J, Guo S, Huang L, Xu P, Liu Y, Yuan Y, He X, He Y, RSC Adv., 5, 34541 (2015)
  14. Sun YN, Gao B, Yao Y, Fang JN, Zhang M, Zhou YM, Chen H, Yang LY, Chem. Eng. J., 240, 574 (2014)
  15. Xue YW, Gao B, Yao Y, Inyang M, Zhang M, Zimmerman AR, Ro KS, Chem. Eng. J., 200, 673 (2012)
  16. Rajapaksha AU, Chen SS, Tsang DC, Zhang M, Vithanage M, Mandal S, Gao B, Bolan NS, Ok YS, Chemosphere, 148, 276 (2016)
  17. Zhou YM, Gao B, Zimmerman AR, Fang J, Sun YN, Cao XD, Chem. Eng. J., 231, 512 (2013)
  18. Zhou YM, Gao B, Zimmerman AR, Chen H, Zhang M, Cao XD, Bioresour. Technol., 152, 538 (2014)
  19. Wang SS, Gao B, Zimmerman AR, Li YC, Ma L, Harris WG, Migliaccio KW, Bioresour. Technol., 175, 391 (2015)
  20. Zhang M, Gao B, Varnoosfaderani S, Hebard A, Yao Y, Inyang M, Bioresour. Technol., 130, 457 (2013)
  21. Zhou YY, Liu XC, Xiang YJ, Wang P, Zhang JC, Zhang FF, Wei JH, Luo L, Lei M, Tang L, Bioresour. Technol., 245, 266 (2017)
  22. Zhou YY, Liu XC, Tang L, Zhang FF, Zeng GM, Peng XQ, Luo L, Deng YC, Pang Y, Zhang JC, J. Hazard. Mater., 333, 80 (2017)
  23. Peng X, Liu X, Zhou Y, Peng B, Tang L, Luo L, Yao B, Deng Y, Tang J, Zeng G, RSC Adv., 8755 (2017).
  24. Ye S, Zeng G, Wu H, Zhang C, Dai J, Liang J, Yu J, Ren X, Yi H, Cheng M, Zhang C, Crit. Rev. Biotechnol., 37, 1062 (2017)
  25. Lyu H, Gao B, He F, Zimmerman A, Ding C, Huang H, Tang J, Crittenden J, Chem. Eng. J., 335, 110 (2018)
  26. Lyu H, Gao B, He F, Zimmerman A, Ding C, Huang H, Tang J, Environ. Pollut., 233, 54 (2018)
  27. Peterson SC, Jackson MA, Kim S, Palmquist DE, Powder Technol., 228, 115 (2012)
  28. Lyu H, Gao B, He F, Ding C, Tang J, Crittenden JC, ACS Sustain. Chem. Eng., 5, 9568 (2017)
  29. Wang D, Zhang W, Hao X, Zhou D, Environ. Sci. Technol., 47, 821 (2013)
  30. Zhang W, Niu J, Morales VL, Chen X, Hay AG, Lehmann J, Steenhuis TS, Ecohydrology, 3, 497 (2010)
  31. Kookana RS, Soil Res., 48, 627 (2010)
  32. Chen M, Wang D, Yang F, Xu X, Xu N, Cao X, Environ. Pollut., 230, 540 (2017)
  33. Lee KY, Mooney DJ, Prog. Polym. Sci, 37, 106 (2012)
  34. Do XH, Lee BK, J. Environ. Manage., 131, 375 (2013)
  35. Jung KW, Jeong TU, Kang HJ, Ahn KH, Bioresour. Technol., 211, 108 (2016)
  36. Roh H, Yu MR, Yakkala K, Koduru JR, Yang JK, Chang YY, J. Ind. Eng. Chem., 26, 226 (2015)
  37. Kolodynska D, Wnetrzak R, Leahy JJ, Hayes MHB, Kwapinski W, Hubicki Z, Chem. Eng. J., 197, 295 (2012)
  38. Taty-Costodes VC, Fauduet H, Porte C, Delacroix A, J. Hazard. Mater., 105(1-3), 121 (2003)
  39. Li YH, Di Z, Ding J, Wu D, Luan Z, Zhu Y, Water Res., 39, 605 (2005)
  40. Mohan D, Singh KP, Water Res., 36, 2304 (2002)
  41. Fourest E, Volesky B, Environ. Sci. Technol., 30, 277 (1996)
  42. Papageorgiou SK, Kouvelos EP, Katsaros FK, Desalination, 224(1-3), 293 (2008)
  43. Kadirvelu K, Namasivayam C, Adv. Environ. Res., 7, 471 (2003)
  44. Padilla-Ortega E, Leyva-Ramos R, Mendoza-Barron J, Appl. Clay Sci., 88-89, 10 (2014)
  45. Wang HY, Gao B, Wang SS, Fang J, Xue YW, Yang K, Bioresour. Technol., 197, 356 (2015)
  46. Ding Z, Hu X, Wan Y, Wang S, Gao B, J. Ind. Eng. Chem., 33, 239 (2016)
  47. Li YH, Ding J, Luan Z, Di Z, Zhu Y, Xu C, Wu D, Wei B, Carbon, 41, 2787 (2003)
  48. Soltani RDC, Jafari AJ, Khorramabadi GS, Am. J. Environ. Sci., 5, 41 (2009)
  49. Guo H, Zhang S, Kou Z, Zhai S, Ma W, Yang Y, Carbohydr. Polym., 115, 177 (2015)
  50. Kacar Y, Arpa C, Tan S, Denizli A, Genc O, Arica MY, Process Biochem., 37(6), 601 (2002)