화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.63, 245-254, July, 2018
DOI10.1016/j.jiec.2018.02.022  Export Citation
Behavior of SAPO-11 as acid function in the direct synthesis of dimethyl ether from syngas and CO2
M. Sánchez-Contador†, A. Ateka, A.T. Aguayo, and J. Bilbao
  • Department of Chemical Engineering, University of the Basque Country UPV/EHU, P.O. Box 644, 48080 Bilbao, Spain
E-mail:
The kinetic behavior for methanol dehydration of different SAPOs (-11 and -18) and HZSM 5 zeolites (with different acidity and various acidity modification treatments) has been studied under the suitable conditions for the direct synthesis of dimethyl ether (DME) from H2 + CO + CO2. SAPO-11 shows a good performance for methanol dehydration, with DME yield above 80% and negligible paraffin formation, and has been assessed as acid function of a bifunctional catalyst in the single-stage synthesis of DME (with CuO-ZnO-ZrO2 as metallic function, metallic/acid mass ratio = 1/2). The bifunctional catalyst (CZZr/S-11) shows a stable kinetic behavior with high selectivity to DME (over 80%).
Keywords:Dimethyl ether;Methanol dehydration;SAPO-11. HZSM-5;Bifunctional catalyst
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