Journal of Industrial and Engineering Chemistry, Vol.64, 256-265, August, 2018
Controllable synthesis of plate BiOBr loaded plate Bi2O2CO3 with exposed {001} facets for ciprofloxacin photo-degradation
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Combination of semiconductors is one of the most efficient ways to improve photocatalytic activities. Plate BiOBr loaded plate Bi2O2CO3 facet is fabricated via one-step hydrothermal process, where urea acts not only as carbon source but as capping agent. As-prepared Bi2O2CO3/BiOBr is of an irregular multi-plate shape, a desirable structure for improved photocatalytic properties. Bi2O2CO3/BiOBr nanoplates with exposed active {001} facet exhibit a ciprofloxacin degradation rate of 90% under visible-light for 4 h. The photodegradation mechanism is speculated. The high activity is attributed to the exposed {001} facet of Bi2O2CO3, formation of heterojunction, extended photoresponse range, and efficient charges carrier transfer.
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