Sensitive Detection of Morphine by Efficient Molecular Imprinted Polymers Based on Goethite Nanorods

S. Mojtaba Amininasab; Parvin Holakooei; Zahed Shami; Marjan Hassanzadeh

Macromolecular Research, Vol.26, No.8, 730-737, August, 2018

DOI10.1007/s13233-018-6099-8 Export Citation

Sensitive Detection of Morphine by Efficient Molecular Imprinted Polymers Based on Goethite Nanorods

S. Mojtaba Amininasab^†, Parvin Holakooei, Zahed Shami, and Marjan Hassanzadeh

Polymer Chemistry Research Laboratory, Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

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We prepared new morphine molecular imprinted polymer goethite nanorods (MMIPGN) which showed excellent adsorption properties due to presence of complementary cavities on the surface of polymer. MMIPGN was synthesized by using morphine as template, fumarate-functionalized goethite nanorods (FFGN) as auxiliary monomer, methcrylic acid (MAA) as functional monomer and ethylene glycol dimethacrylate (EGDMA) as a cross linker. The structural properties were characterized by Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), field emission scanning electron microscopy (FESEM) and thermal gravimetric analysis (TGA). The adsorption behaviors of MMIPGN were monitored under various adsorption conditions such as contact time, pH, the amount of adsorbent and initial concentration of morphine. The selectivity of morphine by MMIPGN was investigated in the presence of foreign species such as epinephrine (Ep), ascorbic acid (Aa), and monoacetylmorphine (Mm) and the value of selectivity coefficients was obtained 1.19, 1.13, and 2.15, respectively. The experimental data were followed by Langmuir isotherm model and Elovich kinetic models.

Keywords:polymer composites;molecular imprinting polymer;goethite nanorods;morphine;imprinting efficiency

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[Referenced By]

[1] Hassanzadeh M, Ghaemy M, Ahmadi S, Macromol. Biosci., 16, 1515 (2016)

[2] Meineke I, Freudenthaler S, Hofmann U, Schaeffeler E, Mikus G, Schwab M, Prange HW, Gleiter CH, Brockmoller J, British J. Clin. Pharmacol., 54, 592 (2002)

[3] Kolaei M, Dashtian K, Rafiee Z, Ghaedi M, Ultrason. Sonochem., 33, 240 (2016)

[4] Chericoni S, Stefanelli F, Iannella V, Giusiani M, J. Chromatogr. B, 949, 127 (2014)

[5] Mahdy T, El-Shihi TH, Emara MM, Chericoni S, Giusiani M, Giorgi M, J. Anal. Toxicol., 36, 548 (2012)

[6] Mashayekhi S, Ghandforoush-Sattari M, Hain R, J. Clin. Pharm. Ther., 33, 419 (2008)

[7] Alnajjar AA, Acta Chromatogr., 20, 227 (2008)

[8] Hsu HC, Chen LC, Ho KC, Anal. Chim. Acta, 504, 141 (2004)

[9] Valimaki HS, Pulli T, Tappura K, J. Fluoresc., 20, 1003 (2010)

[10] Navaee A, Salimi A, Teymourian H, Biosens. Bioelectron., 31, 205 (2012)

[11] Yeh WM, Ho KC, Anal. Chim. Acta, 542, 76 (2005)

[12] Cao H, Xiao JB, Xu M, Macromol. Res., 14(3), 324 (2006)

[13] Lee SC, Chang JY, Macromol. Res., 17(7), 522 (2009)

[14] Kublickas R, Werner C, Voit B, eXPRESS Polym. Lett., 11, 645 (2017)

[15] He MQ, Bao LL, Sun KY, Zhao DX, Li WB, Xia JX, Li HM, eXPRESS Polym. Lett., 8, 850 (2014)

[16] Yang WL, Huang SM, Wu QZ, He JF, J. Polym. Res., 21, 383 (2014)

[17] Byun HS, Yang DS, Cho SH, Polymer, 54(2), 589 (2013)

[18] Anirudhan TS, Alexander S, Eur. Polym. J., 97, 84 (2017)

[19] Zhong S, Zhou CY, Zhang XN, Zhou H, Li H, Zhu XH, Wang Y, J. Hazard. Mater., 276, 58 (2014)

[20] Huang W, Kong Y, Yang W, Ni X, Wang N, Lu Y, Xu W, J. Polym. Res., 23, 94 (2016)

[21] Hemmati K, Sahraei R, Ghaemy M, Polymer, 101, 257 (2016)

[22] Yang X, Dong X, Zhang K, Yang F, Guo Z, J. Mater. Chem. B, 4, 920 (2016)

[23] Yang S, Wang Y, Jiang Y, Li S, Liu W, Polymers, 8, 216 (2016)

[24] da Silva RCS, Mano V, Pereira AC, de Figueiredo EC, Borges KB, Anal. Methods, 8, 4075 (2016)

[25] Alexander S, Baraneedharan P, Balasubrahmanyan S, Ramaprabhu S, Eur. Polym. J., 86, 106 (2017)

[26] Wang Y, Wang E, Wu Z, Li H, Zhu Z, Zhu X, Dong Y, Carbohydr. Polym., 101, 517 (2014)

[27] Yongfeng K, Wuping D, Yan L, Junxia K, Jing X, Carbohydr. Polym., 88, 459 (2012)

[28] Machynakova A, Lhotska I, Hrobonova K, Satinsky D, J. Pharm. Biomed. Anal., 145, 144 (2017)

[29] Hao Y, Gao R, Shi L, Liu D, Tang Y, Guo Z, J. Chromatogr. A, 1396, 7 (2015)

[30] Wang Y, Ren S, Jiang H, Peng Y, Bai J, Li Q, Li C, Gao Z, Ning B, RSC Adv., 7, 22215 (2017)

[31] Hassanzadeh M, Ghaemy M, New J. Chem., 41, 2277 (2017)

[32] Bagan H, Zhou T, Eriksson NL, Bulow L, Ye L, RSC Adv., 7, 41705 (2017)

[33] Atta NF, Galal A, Azab SM, Analyst, 136, 4682 (2011)

[34] Li SJ, Gong SQ, Adv. Funct. Mater., 19(16), 2601 (2009)

[35] Guo X, Zhang J, Ge J, Yang C, Dang Z, Liu S, Gao L, RSC Adv., 5, 100464 (2015)

[36] Wang ZP, Ma YJ, He HL, Pei CH, He P, Appl. Surf. Sci., 332, 456 (2015)

[37] Brok E, Frandsen C, Madsen DE, Jacobsen H, Birk JO, Lefmann K, Bendix J, Pedersen KS, Boothroyd CB, Berhe AA, Simeoni GG, J. Phys. D-Appl. Phys., 47, 365003 (2014)

[38] Rose J, Cortalezzi-Fidalgo MM, Moustier S, Magnetto C, Jones CD, Barron AR, Wiesner MR, Bottero JY, Chem. Mater., 14, 621 (2002)

[39] Li H, Li W, Zhang Y, Wang T, Wang B, Xu W, Jiang L, Song W, Shu C, Wang C, J. Mater. Chem., 21, 7878 (2011)

[40] Ahmed MA, Abdelbar NM, Mohamed AA, Int. J. Biol. Macromol., 107, 1046 (2018)

[41] Saavedra LNM, Baeta BEL, Pereira MC, de Oliveira LCA, da Silva AC, Fuel, 210, 380 (2017)