화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 221-230, October, 2018
DOI10.1016/j.jiec.2018.05.033  Export Citation
Study of the impact of sequence of corrosion inhibitor doping in zeolite on the self-healing properties of silane sol-gel film
Leili Rassouli, Reza Naderi†, and Mohammad Mahdavain1, †
  • School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran, Iran
  • 1Department of Surface Coatings and Corrosion, Institute of Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
E-mail:,
Different doping approaches were examined to prepare NaX zeolite nanoparticles as host for Zn2+ and mercaptobenzimidazole. The zeolites were incorporated in a silane sol.gel coating. In solution phase, the corrosion inhibition was found to depend on the sequence of doping. The released inhibitors reduced the steel corrosion through formation of a protective layer on the surface. In best condition, the layer reduced corrosion current density from 13.9 μA cm-2 to 1.5 μA cm-2 after 24 h exposure. According to trend and magnitude of charge transfer resistance, superiority of the coating with zeolites was attributed to function of inhibitors at interface.
Keywords:Zeolite nanoparticle;Corrosion inhibitor;Self-healing properties;Silane film;Steel
  1. Montemor ME, Feffeira MGS, Electrochim. Acta, 52(24), 6976 (2007)
  2. Montemor MF, Pinto R, Ferreira MGS, Electrochim. Acta, 54(22), 5179 (2009)
  3. Alinejad S, Naderi R, Mahdavian M, Prog. Org. Coat., 101, 142 (2016)
  4. Dias SAS, Lamaka SV, Nogueira CA, Diamantino TC, Ferreira MGS, Corrosion Sci., 62, 153 (2012)
  5. Montemor MF, Trabelsi W, Zheludevich M, Ferreira MGS, Prog. Org. Coat., 57, 67 (2006)
  6. Trabelsi W, Triki E, Dhouibi L, Ferreira MGS, Zheludkevich ML, Montemor MF, Surf. Coat. Technol., 200, 4240 (2006)
  7. Tavandashti NP, Sanjabi S, Shahrabi T, Mater. Corros., 62, 411 (2011)
  8. Roussi E, Tsetsekou A, Skarmoutsou A, Charitidis CA, Karantonis A, Surf. Coat. Technol., 232, 131 (2013)
  9. Palanivel V, Huang Y, Van Ooij WJ, Prog. Org. Coat., 53, 153 (2005)
  10. Tian Z, Shi H, Liu F, Xu S, Han E, Prog. Org. Coat., 82, 81 (2015)
  11. Quinet M, Neveu B, Moutarlier V, Audebert P, Ricq L, Prog. Org. Coat., 58, 46 (2007)
  12. Khramov AN, Voevodin NN, Balbyshev VN, Donley MS, Thin Solid Films, 447, 549 (2004)
  13. Khramov A, Voevodin NN, Balbyshev VN, Mantz RA, Thin Solid Films, 483(1-2), 191 (2005)
  14. Aparicio M, Pellice SA, Dura A, Corrosion Sci., 50, 1283 (2008)
  15. Montemor MF, Ferreira MGS, Prog. Org. Coat., 63, 330 (2008)
  16. Gonzalez E, Pavez J, Azocar I, Zagal JH, Zhou X, Melo F, Thompson GE, Paez MA, Electrochim. Acta, 56(22), 7586 (2011)
  17. Zand RZ, Verbeken K, Flexer V, Adriaens A, Mater. Chem. Phys., 145(3), 450 (2014)
  18. Tavandashti NP, Sanjabi S, Prog. Org. Coat., 69, 384 (2010)
  19. Ferrer EL, Rollon AP, Mendoza HD, Lafont U, Garcia SJ, Microporous Mesoporous Mater., 188, 8 (2014)
  20. Dias SAS, Marques A, Lamaka SV, Simoes A, Diamantino TC, Ferreira MGS, Electrochim. Acta, 112, 549 (2013)
  21. Dias SAS, Lamaka SV, Diamantino TC, Ferreira MGS, J. Electrochem. Soc., 161, 215 (2014)
  22. Capri A, Calabrese L, Bonaccorsi L, Proverbio E, Solid State Phenom., 227, 163 (2015)
  23. Al-Jubouri SM, Holmes SM, J. Chem. Eng., 308, 476 (2017)
  24. Ferreira L, Fonseca AM, Botelho G, Almeida-Aguiar C, Neves IC, Microporous Mesoporous Mater., 160, 126 (2012)
  25. Haile T, Nakhla G, Allouche E, Corrosion Sci., 50, 713 (2008)
  26. Calabrese L, Bonaccorsi L, Caprı A, J. Coat. Technol. Res., 11, 883 (2014)
  27. Calabrese L, Bonaccorsi L, Capri A, Proverbio E, Prog. Org. Coat., 77, 1341 (2014)
  28. Rassouli L, Naderi R, Mahdavian M, J. Taiwan Inst. Chem. Eng., 85, 207 (2018)
  29. Rassouli L, Naderi R, Mandavain M, Appl. Surf. Sci., 423, 571 (2017)
  30. Sebastian J, Jinka KM, Jasra RV, J. Catal., 244(2), 208 (2006)
  31. Ahmed IAM, Young SD, Crout NMJ, Geochim. Cosmochim. Acta, 70, 4850 (2006)
  32. Blonski P, Birczynski A, Lalowicsz ZT, Datka J, Lodziana Z, J. Phys. Chem. C, 119, 19548 (2015)
  33. Amboya A, Nguyen T, Huynh HT, Brown A, Ratliff G, Yonutas H, Cizmeciyan D, Garcia MA, Org. Biomol. Chem., 7, 2322 (2009)
  34. Form GR, Paper ES, Acta Crystallogr. Sect. B-Struct. Sci., 32, 345 (1976)
  35. Velu S, Ma XL, Song CS, Ind. Eng. Chem. Res., 42(21), 5293 (2003)
  36. Lin LG, Zhang YZ, Zhang HY, Lu FW, J. Colloid Interface Sci., 360(2), 753 (2011)
  37. Wahdan MH, Mater. Chem. Phys., 49, 135 (1997)
  38. Markhali BP, Naderi R, Mahdavian M, Sayebani M, Arman SY, Corrosion Sci., 75, 269 (2013)
  39. Salehi E, Naderi R, Ramezanzadeh B, Appl. Surf. Sci., 396, 1499 (2017)
  40. Ramezanzadeh B, Ghasemi E, Askari F, Mahdavian M, Dyes Pigment., 122, 331 (2015)
  41. Mahdavian M, Ashhari S, Prog. Org. Coat., 68, 259 (2010)
  42. Alinejad S, Naderi R, Mahdavian M, J. Ind. Eng. Chem., 48, 88 (2017)
  43. Alibakhshi E, Ghasemi E, Mahdavian M, Prog. Org. Coat., 77, 1155 (2014)
  44. Mahdavian M, Attar MM, Corrosion Sci., 48, 4152 (2006)
  45. Kartsonakis IA, Stanciu SG, Matei AA, Karaxi EK, Hristu R, Karantonis A, Charitidis CA, Corrosion Sci., 100, 194 (2015)
  46. Gao H, Li Q, Dai Y, Luo F, Zhang HX, Corrosion Sci., 52, 1603 (2010)
  47. Sahin M, Bilgic S, Yilmaz H, Appl. Surf. Sci., 195(1-4), 1 (2002)
  48. Dariva CG, Galio AF, in: Aliofkhazraei M(Ed.), Developments in Corrosion Protection, IntechOpen, p.365 2014.
  49. Umoren SA, Solomon MM, J. Environ. Chem. Eng., 5, 246 (2017)
  50. Olivier M, Fedel M, Sciamanna V, Vandermiers C, Motte C, Poelman M, Deflorian F, Prog. Org. Coat., 72, 15 (2011)
  51. Cabral A, Duarte RG, Montemor MF, Zheludkevich ML, Ferreira MGS, Corrosion Sci., 47, 869 (2005)