화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.80, 171-181, December, 2019
DOI10.1016/j.jiec.2019.07.046  Export Citation
Doped porous carbon nanostructure materials as non-precious metal catalysts for oxygen reduction reaction in alkaline and acid media
Suk-Hui Kwon, Sang-Beom Han, Da-Hee Kwak, JiHyeon Song1, and Kyung-Won Park†
  • Department of Chemical Engineering, Soongsil University, Seoul 156-743, Republic of Korea
  • 1Department of Civil and Environmental Engineering, Sejong University, Seoul 05006, Republic of Korea
E-mail:
Various doped porous carbon nanomaterials to replace Pt-based catalysts for oxygen reduction reaction (ORR) in acid and alkaline media have been intensively studied. Herein, doped porous carbon nanostructure materials as non-precious metal catalysts for ORR are synthesized using different weight ratios of polyaniline (PANI) to dicyandiamide (DCDA) as carbon source and dopants with iron salt to control the specific surface area and nitrogen doping content. The as-prepared samples exhibit well-defined porous carbon structure that consists of micro- and meso-pores, high specific surface areas, increased amount of nitrogen dopant, and relative content of graphitic N and pyridinic nitrogen N. Among these doped porous carbon nanostructure catalysts, the catalyst synthesized using a proper ratio of PANI to DCDA exhibits significantly improved electrocatalytic performance for ORR, i.e., high half-wave potential, high specific activity, and enhanced stability in both acid and alkaline media, because of the high graphitic N/pyridinic nitrogen N and micro-pore ratios.
Keywords:Doped porous carbon;Dicyandiamide;Non-precious metal catalyst;Oxygen reduction reaction
  1. Seo MH, Park MG, Lee DU, Wang XL, Ahn W, Noh SH, Choi SM, Cano ZP, Han B, Chen ZW, Appl. Catal. B: Environ., 239, 677 (2018)
  2. Liu X, Dai L, Nat. Rev. Mater., 1, 1 (2016)
  3. Scofield ME, Liu H, Wong SS, Chem. Soc. Rev., 44, 5836 (2015)
  4. Park JY, Kwak DH, Ma KB, Han SB, Chai GS, Kim SK, Peck DH, Kim CS, Kucernak A, Park KW, J. Catal., 359, 46 (2018)
  5. Jiao Y, Zheng Y, Jaroniec M, Qiao SZ, J. Am. Chem. Soc., 136(11), 4394 (2014)
  6. Liu D, Tao L, Yan D, Zou Y, Wang S, ChemElectroChem, 5, 1775 (2018)
  7. Zhu C, Li H, Fu S, Du D, Lin Y, Chem. Soc. Rev., 45, 517 (2016)
  8. Kwak DH, Han SB, Kim DH, Won JE, Park KW, Appl. Catal. B: Environ., 238, 93 (2018)
  9. Zhang J, Qu L, Shi G, Liu J, Chen J, Dai L, Angew. Chem.-Int. Edit., 55, 2230 (2016)
  10. Yang L, Jiang S, Zhao Y, Zhu L, Chen S, Wang X, Wu Q, Ma J, Ma Y, Hu Z, Angew. Chem.-Int. Edit., 50, 7132 (2011)
  11. Choi CH, Park SH, Woo SI, Green Chem., 13, 406 (2011)
  12. Gong K, Du F, Xia Z, Durstock M, Dai L, Science, 323, 460 (2009)
  13. Lai L, Potts JR, Zhan D, Wang L, Poh CK, Tang C, Gong H, Shen Z, Lin J, Ruoff RS, Energy Environ. Sci., 5, 7936 (2012)
  14. Yang L, Shui J, Du L, Shao Y, Liu J, Dai L, Hu Z, Adv. Mater., 1804799, 1 (2019)
  15. Wutscher A, Eckhard T, Hiltrop D, Lotz K, Schuhmann W, Andronescu C, Muhler M, ChemElectroChem, 6, 514 (2019)
  16. Deng H, Li Q, Liu J, Wang F, Carbon, 112, 219 (2017)
  17. Guo DH, Shibuya R, Akiba C, Saji S, Kondo T, Nakamura J, Science, 351(6271), 361 (2016)
  18. Yang HB, Miao J, Hung SF, Chen J, Tao HB, Wang X, Zhang L, Chen R, Gao J, Chen HM, Dai L, Liu B, Sci. Adv., 2, e15011 (2016)
  19. Kim H, Lee K, Woo SI, Jung Y, Phys. Chem. Chem. Phys., 13, 17505 (2011)
  20. Shamsuddin MS, Yusoff NRN, Sulaiman MA, Procedia Chem., 19, 558 (2016)
  21. Pal M, Pal U, Jimenez JMGY, Perez-Rodriguez F, Nanoscale Res. Lett., 7, 1 (2012)
  22. Storck S, Bretinger H, Maier WF, Appl. Catal. A: Gen., 174(1-2), 137 (1998)
  23. Leofanti G, Padovan M, Tozzola G, Venturelli B, Catal. Today, 41(1-3), 207 (1998)
  24. Jaouen F, Herranz J, Lefevre M, Dodelet JP, Kramm UI, Herrmann I, et al., ACS Appl. Mater. Interfaces, 1, 1623 (2009)
  25. Lee S, Kwak DH, Han SB, Lee YW, Lee JY, Choi IA, Park HS, Park JY, Park KW, ACS Catal., 6, 5095 (2016)
  26. Zhang J, Chen X, Takanabe K, Maeda K, Domen K, Epping JD, Fu X, Antonieta M, Wang X, Angew. Chem.-Int. Edit., 49, 441 (2010)
  27. Liang HW, Wei W, Wu ZS, Feng XL, Mullen K, J. Am. Chem. Soc., 135(43), 16002 (2013)
  28. Huang H, Feng X, Du C, Wu S, Song W, J. Mater. Chem. A, 3, 4976 (2015)
  29. Yu HJ, Shang L, Bian T, Shi R, Waterhouse GIN, Zhao YF, Zhou C, Wu LZ, Tung CH, Zhang TR, Adv. Mater., 28(25), 5080 (2016)
  30. Ma JH, Wang L, Mu X, Li L, Int. J. Hydrog. Energy, 40(6), 2641 (2015)
  31. Daems N, Sheng X, Vankelecom IFJ, Pescarmona PP, J. Mater. Chem. A, 2, 4085 (2014)
  32. Xing T, Zheng Y, Li LH, Cowie BCC, Gunzelmann D, Qiao SZ, Huang S, Chen Y, ACS Nano, 8, 6856 (2014)
  33. Nam G, Park J, Kim ST, Shin DB, Park N, Kim Y, Lee JS, Cho J, Nano Lett., 14, 1870 (2014)
  34. Ge X, Sumboja A, Wuu D, An T, Li B, Goh FWT, Hor TSA, Zong Y, Liu Z, ACS Catal., 5, 4643 (2015)
  35. Claude E, Addou T, Latour JM, Aldebert P, J. Appl. Electrochem., 28, 57 (1997)
  36. Cardoso ESF, Fortunato GV, Maia G, ChemElectroChem, 5, 1691 (2018)
  37. Wang N, Lu B, Li L, Niu W, Tang Z, Kang X, Chen S, ACS Catal., 8, 6827 (2018)
  38. Zhang L, Xia Z, J. Phys. Chem. C, 115, 11170 (2011)
  39. Niwa H, Horiba K, Harada Y, Oshima M, Ikeda T, Terakura K, Ozaki J, Miyata S, J. Power Sources, 187(1), 93 (2009)
  40. Zhu J, Xiao M, Song P, Fu J, Jin Z, Ma L, Ge J, Liu C, Chen Z, Xing W, Nano Energy, 49, 23 (2018)
  41. Merzougui B, Bukola S, Zaffou R, Mater. Today Proc., 3, 691 (2016)
  42. Yuan S, Shui JL, Grabstanowicz L, Chen C, Commet S, Reprogle B, Xu T, Yu L, Liu DJ, Angew. Chem.-Int. Edit., 52, 8349 (2013)
  43. Jaouen F, Lefevre M, Dodelet JP, Cai M, J. Phys. Chem. B, 110(11), 5553 (2006)
  44. Jia O, Ramaswamy N, Tylus U, Strickland K, Li J, Serov A, Artyushkova K, et al., Nano Energy, 29, 65 (2016)
  45. Thorum MS, Hankett JM, Gewirth AA, J. Phys. Chem. Lett., 2, 295 (2011)
  46. Park HS, Han SB, Kwak DH, Han JH, Park KW, J. Catal., 370, 130 (2019)
  47. Mahmood J, Li F, Kim C, Choi HJ, Gwon O, Jung SM, Seo JM, Cho SJ, Ju YW, Jeong HY, Kim G, Baek JB, Nano Energy, 44, 304 (2018)
  48. Meier JC, Galeano C, Katsounaros I, Topalov AA, Kostka A, Schuth F, Mayrhofer KJJ, ACS Catal., 2, 832 (2012)
  49. Liang HW, Wei W, Wu ZS, Feng XL, Mullen K, J. Am. Chem. Soc., 135(43), 16002 (2013)
  50. Ferrero GA, Preuss K, Marinovic A, Jorge AB, Mansor N, Brett DJL, Fuertes AB, Sevilla M, Titirici MM, ACS Nano, 10, 5922 (2016)
  51. Ferrero GA, Diez N, Sevilla M, Fuertes AB, Microporous Mesoporous Mater., 278, 280 (2019)
  52. Deng YJ, Wang GH, Sun KL, Chi B, Shi XD, Dong YY, Zheng L, Zeng JH, Li XH, Liao SJ, J. Power Sources, 417, 117 (2019)
  53. Fu X, Choi JY, Zamani P, Jiang G, Hoque MA, Hassan FM, Chen Z, ACS Appl. Mater. Interfaces, 8, 6488 (2016)
  54. Yang J, Wang X, Li B, Ma L, Shi L, Xiong Y, Xu H, Adv. Funct. Mater., 27, 160649 (2017)
  55. Yan ZX, Dai CJ, Zhang MM, Lv XM, Zhao XH, Xie JM, Int. J. Hydrog. Energy, 44(8), 4090 (2019)
  56. Liu Y, Huang B, Zhang X, Huang X, Xie Z, J. Power Sources, 412, 125 (2018)
  57. Yan X, Liu K, Wang T, You Y, Liu J, Wang P, Pan X, Wang G, Luo J, Zhu J, J. Mater. Chem. A, 5, 3336 (2017)
  58. Deng Y, Chi B, Li J, Wang G, Zheng L, Shi X, Cui Z, Du L, Liao S, Zang K, Luo J, Hu Y, Sun X, Adv. Eng. Mater., 1802856, 1 (2019)
  59. Mehmood A, Pampel J, Ali G, Ha HY, Ruiz-Zepeda F, Fellinger TP, Adv. Eng. Mater., 8, 170177 (2018)
  60. Wang XX, Cullen DA, Pan YT, Hwang S, Wang M, Feng Z, Wang J, Engelhard MH, Zhang H, He Y, Shao Y, Su D, More KL, Spendelow JS, Wu G, Adv. Mater., 30, 170675 (2018)