Rare earth metal functionalized electrospun nanofiber catalyst for effective photo-decontamination of profenofos toxin

Krishnasamy Lakshmi; Krishna Kadirvelu; Palathurai Subramaniam Mohan

Journal of Industrial and Engineering Chemistry, Vol.80, 182-189, December, 2019

DOI10.1016/j.jiec.2019.07.047 Export Citation

Rare earth metal functionalized electrospun nanofiber catalyst for effective photo-decontamination of profenofos toxin

Krishnasamy Lakshmi, Krishna Kadirvelu^†, and Palathurai Subramaniam Mohan¹

DRDO-BU Center for Life Sciences, Bharathiar University Campus, Coimbatore 641046, India
¹Department of Chemistry, Bharathiar University, Coimbatore 641046, India

E-mail:

Polyacrylonitrile containing La-doped ZnO nanodisks act as heterogenous catalyst in oxidative degradation of profenofos in field samples. The nanodisks on PAN fibers has unique characteristics for the processes including wurtzite structure of ZnO with no error phases. The degradation of the profenofos was processed under the UVand it shows that the reaction follows first-order kinetics and achieved 98.5% degradation within 210 min as estimated by HPLC technique. GC-MS analysis confirmed the degradation of profenofos from the production of 2-chloro-4-bromophenol.This study shows that the material has unique property, the processes is found to be simple/feasible and economically viable.

Keywords:Electrospun nanofiber;Metal oxides;Detection;Photodegradation;Profenofos

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[2] McDaniel KL, Moser VC, Neurotoxicol. Teratol., 26, 407 (2004)

[3] Jabeen H, Iqbal S, Anwar S, Parales RE, Int. Biodeterior. Biodegrad., 100, 89 (2015)

[4] Zhao W, Shen C, Ding N, Jia S, Fan Z, J. Qingdao Univ. Sci. Technol., 4,006 (Nat. Sci. Ed.) (2008).

[5] Lari SZ, Khan NA, Gandhi KN, Meshram TS, Thacker NP, J Environ. Health Sci. Eng., 12, 11 (2014)

[6] Radwan M, Abu-Elamayem M, Shiboob M, Abdel-Aal A, Food Chem. Toxicol., 43, 553 (2005)

[7] Baig SA, Akhtera NA, Ashfaq M, Asi MR, Am.-Eurasian J. Agric. Environ. Sci., 6, 513 (2009)

[8] Shalaby A, Egy. Sci. J. Pestic., 7, 845 (2016)

[9] Khalifa ME, Kenawy IM, El-Reash YA, Abdallah A, J. Environ Chem. Eng., 5, 3447 (2017)

[10] Randhawa MA, Zaman M, Anjum FM, Asghar A, Sajid MW, J. Chem. Soc. Pak., 37, 574 (2015)

[11] Zaidon SZ, Hamsan H, Bin HY, A Review on Pesticides Occurrence in Fruits and Vegetables in Malaysia and their Potential Health Risk among Adults, (2016).

[12] Mansouriieh N, Sohrabi MR, Khosravi M, Arab. J. Chem. (2015).

[13] Jung SH, Oh E, Lee KH, Yang Y, Park CG, Park W, Jeong SH, Cryst. Growth Des., 8(1), 265 (2007)

[14] Sanchez JP, Domagala JM, Hagen SE, Heifetz CL, Hutt MP, Nichols JB, Trehan AK, J. Med. Chem., 31, 983 (1988)

[15] Lakshmi K, Mathusalini S, Arasakumar T, Kadirvelu K, Mohan PS, J. Mater. Sci. Mater. Electron., 28, 12944 (2017)

[16] Korake P, Dhabbe R, Kadam A, Gaikwad Y, Garadkar K, J. Photochem. Photobiol. B-Biol., 130, 11 (2014)

[17] Guo CF, Wang Y, Jiang P, Cao S, Miao J, Zhang Z, Liu Q, Nanotechnology, 19, 445710 (2008)

[18] Tuyen NV, Long NN, Hoa TTQ, Nghia NX, Chi DH, Higashimine K, Mitani T, Canh TD, J. Exp. Nanosci., 4, 243 (2009)

[19] Thirunavukkarasu K, Jothiramalingam R, Powder Technol., 239, 308 (2013)

[20] Shouqin T, Yupeng Z, Dawen Z, Hao W, Neng L, Changsheng X, Chunxu P, Xiujian Z, Phys. Chem. Chem. Phys., 17, 27437 (2015)

[21] Minggang Z, Xinchang W, Lingling N, Jianfeng J, Xinjian L, Liangliang C, Sens. Actuators B-Chem., 156(588) (2011)

[22] Santoshkumar B, Kalyanaraman S, Vettumperumal R, Thangavel R, Kityk I, Velumani S, J. Alloy. Compd., 658, 435 (2016)

[23] Kaneti YV, Zakaria QM, Zhang Z, Chen C, Yue J, Liu M, Jiang X, Yu A, J. Mater. Chem. A Mater., 2, 13283 (2014)

[24] Silva NA, Birolli WG, Seleghim MHR, Porto ALM, Biodegradation of the Organophosphate Pesticide Profenofos by Marine Fungi, httphttps://www.doi.org/10.5772/56372.

[25] Sahub C, Tuntulani T, Nhujak T, Tomapatanaget B, Sens. Actuators B-Chem., 258, 88 (2018)

[26] Keihan AH, Rasoulnezhad H, Mohammadgholi A, Sajjadi S, Hosseinzadeh M, Farhadian R, Hosseinzadeh G, J. Mater. Sci. Mater. Electron., 28, 16718 (2017)

[27] Ho GW, Wong ASW, Appl. Phys. A-Mater. Sci. Process., 86, 457 (2007)

[28] Vera S, Hans GJM, Paul Z, Marc T, Coen JR, Violette G, Sci. Total Environ., 653, 1532 (2019)

[29] Wei LO, Srinivasan N, Bradley K, Ghim WH, Nanoscale, 5, 5568 (2013)

[30] Umaralikhan L, Jaffar MJM, J Mater Sci.: Mater. Electron., 28, 7677 (2017)