화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.81, 294-302, January, 2020
DOI10.1016/j.jiec.2019.09.017  Export Citation
Exploration of Ni-X (O, S, Se) for high performance supercapacitor with long-term stability via solution phase synthesis
Chebrolu Venkata Thulasi-Varma, Balamuralitharan Balakrishnan1, and Hee-Je Kim†
  • Department of Electrical Engineering, Pusan National University, Gumjeong-Ku, Jangjeong-Dong, Busan, 46241, Republic of Korea
  • 1Korea Univeristy, R&D Centre, Green School, Korea University, Seoul, 02842, Republic of Korea
E-mail:
Here, we report a simple strategy to grow NiSe architectures vertically on nickel foam (NF) via facile solution-based deposition. The as-synthesized NSE7h core-shell nanoplate structure with a mass loading of 6.4 mg/cm-2 can be delivered a high specific capacitance of 2234.84 Fg-1 at 10 mA cm-2 and outstanding rate capability compared to that of NO (708.52 Fg-1), NS (968.22 Fg-1), NSE1h (1357.43 Fg-1), and NSE4h (1675.87 Fg-1). The desirable electrochemical performance was mainly attributed to the component’s synergy assuring rich redox reactions, deposition of selenium on the surface of NiO nanotubes, high conductivity, great specific area and furthermore, rapid ion diffusion distance, with effective transport pathway of electrons and electrolyte ions. The existence of selenium vacancies and versatile synthesis of NiSe architectures would open up a wide range of applications in energy storage and conversion applications including supercapacitors, electrocatalysis, and batteries.
Keywords:Selenium vacancy;Core.shell structure;Deposition time;Solution approach;Ni-foam
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