화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.81, 405-414, January, 2020
DOI10.1016/j.jiec.2019.09.031  Export Citation
Nanoporous composites of activated carbon-metal organic frameworks for organic dye adsorption: Synthesis, adsorption mechanism and kinetics studies
Mahdi Hasanzadeh1, 2, Abdolreza Simchi1, 2, †, and Hossein Shahriyari Far3
  • 1Department of Materials Science and Engineering, Sharif University of Technology, Azadi Avenue, P.O. Box 11365-8639, Tehran, Iran
  • 2Department of Textile Engineering, Yazd University, P.O. Box 89195-741, Yazd, Iran
  • 3Department of Chemistry, Iran University of Science and Technology, Narmak, P.O. Box 16846-13114, Tehran, Iran
E-mail:
Activated carbon (AC) is an inert adsorbent material that has widely been used in water treatment or removing of environmental pollutants from water. In order to improve the adsorption of AC, which highly depends on its pore size and surface area, we prepared highly porous adsorbent composites of activated carbon (AC)/chromium-based MOF (MIL-101(Cr)). The composite has a high specific surface area of 2440 m2 g-1 and total pore volume of 1.27 cm3 g-1. To show the efficiency of the composite as an adsorbent, the removal kinetics of anionic dyes (Direct Red 31 and Acid Blue 92) from aqueous solutions dependent on the amount of composite, adsorption time, concentration of dye and pH is demonstrated. It is shown that the kinetics of organic dye removal by AC@MIL-101(Cr) composite is faster than MIL-101 (Cr) under near neutral pH conditions. The half-time of removal is about 3 min while about 85% of the dye is removed after 5 min. This study provides new idea into the design and synthesis of highly efficient nanoporous adsorbent based on MOFs for removal of pollutants as well as organic dyes from wastewater.
Keywords:Carbon composite;Hybrid inorganic.organic framework;Nanoporous adsorbent;Anionic dye;Adsorption
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