One of the most pervasive environmental problems is oily sewage; emerging materials are needed that could effectively solve this global challenge. Special wetting materials typically combine micro/nanoscale hierarchical structures with a low surface energy, which could produce superhydrophobic performance and these superhydrophobic materials are very important for a wide variety of applications, including self-cleaning and antiadhesives. However, the majority of these manmade materials still suffer from poor durability, which seriously hinders their practical applications. A better choice is that use of supramolecular materials with self-healing ability, which could provide an efficient method to solve materials poor durability problem. However, lightweight materials with special wettbility and self-healing still remain a challenge. In this work, we confine polyborosiloxane (PBS) in an ultralight graphene network to form a robust, special function graphene foam that has the ability to self-repair. Hydroxyl terminated poly(dimethylsiloxane) and boric acid as the as raw material were used to synthesis PBS at room temperature. The as-prepared composite network could be compressed and their properties fully restored without an external stimulus after being subjected to repeated damage. In addition, the prepared composite foam retains the porosity of the original graphene foam. The present work suggests encouraging applications of the self-healing graphene/PBS foam in water/organic solvent separations.