화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.89, 156-165, September, 2020
DOI10.1016/j.jiec.2020.05.005  Export Citation
Sea-urchin-like mesoporous copper-manganese oxide catalysts:Influence of copper on benzene oxidation
Hyun Ji Lee, Jae Hwan Yang†, Jeong Hyun You, and Been Young Yoon
  • Department of Environmental Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea
E-mail:
Mesoporous copper manganese oxides were prepared via a simple method to be used for the catalytic oxidation of benzene emitted from industrial activities. Morphological characterization revealed that the primary particles of the as-synthesized catalysts were nanorods that aggregated with each other to form sea-urchin like structures. Compared with the manganese oxide based catalyst, copper manganese oxides exhibited better performances for benzene oxidation, achieving the best benzene conversion rate of 90% at around 219 °C, which is 23 °C lower than that for the catalyst without copper. The benefit of copper addition exists because the addition of copper in the manganese oxide causes desorption of lattice oxygen, increasing concentrations of oxygen defects on the catalyst surfaces. Furthermore, the addition of copper was found to contribute to the increase in the specific surface area by reducing the sizes of the nanorods and sea-urchin structures. Finally, the influential factors for catalytic oxidation were oxygen acancies and the oxidation state of metals.
Keywords:Mesoporous copper manganese oxide;Nanorod;Sea-urchin like structure;Copper addition;Benzene oxidation
  1. Ferreira RSG, de Oliveira PGP, Noronha FB, Appl. Catal. B: Environ., 29(4), 275 (2001)
  2. Einaga H, Futamura S, J. Catal., 227(2), 304 (2004)
  3. Mu Z, Li JJ, Duan MH, Hao ZP, Qiao SZ, Catal. Commun., 9(9), 1874 (2008)
  4. Falzone L, Marconi A, Loreto C, Franco S, Spandidos DA, Libra M, Mol. Med. Rep., 14(5), 4467 (2016)
  5. Van Der Vaart DR, Vatavuk WM, Wehe AH, J. Air Waste Manag. Assoc., 41(4), 497 (1991)
  6. Gupta VK, Verma N, Chem. Eng. Sci., 57(14), 2679 (2002)
  7. Lalanne F, Malhautier L, Roux JC, Fanlo JL, Bioresour. Technol., 99(6), 1699 (2008)
  8. Gironi F, Piemonte V, Chem. Eng. J., 172(2-3), 671 (2011)
  9. Wang JD, Chen JM, Chem. Eng. J., 123(3), 103 (2006)
  10. Li S, Wang D, Wu X, Chen Y, Chinese, J. Catal., 41(4), 550 (2020)
  11. Kamal MS, Razzak SA, Hossain MM, Atmos. Environ., 140, 117 (2016)
  12. Tomatis M, Xu HH, He J, Zhang XD, J. Chem., 1 (2016).
  13. Yang CT, Miao G, Pi YH, Xia QB, Wu JL, Li Z, Xiao J, Chem. Eng. J., 370, 1128 (2019)
  14. Liu LZ, Sun JT, Ding JD, Zhang Y, Jia JP, Sun TH, Inorg. Chem., 58(20), 14275 (2019)
  15. Joung HJ, Kim JH, Oh JS, You DW, Park HO, Jung KW, Appl. Surf. Sci., 290, 267 (2014)
  16. Chen D, Shi J, Shen H, Chem. Eng. J., 385, 123887 (2019)
  17. Li N, Cheng J, Xing X, Sun Y, Hao Z, J. Hazard. Mater., 393 (2020)
  18. Ahn CW, You YW, Heo I, Hong JS, Jeon JK, Ko YD, Kim YH, Park H, Suh JK, J. Ind. Eng. Chem., 47, 439 (2017)
  19. Zhou L, Zhang J, He JH, Hu YC, Tian H, Mater. Res. Bull., 46(10), 1714 (2011)
  20. Li S, Wang H, Li W, Wu X, Tang W, Chen Y, Appl. Catal. B Environ., 166 (2015).
  21. Sager SM, Kondarides DI, Verykios XE, Appl. Catal. B: Environ., 103(3-4), 275 (2011)
  22. Liu P, Wei GL, He HP, Liang XL, Chen HL, Xi YF, Zhu JX, Appl. Surf. Sci. 464, 287 (2018)(2019).
  23. Liu Y, Yan L, Gao W, Zhu SR, Zhan J, Cao R, Zhou H, Appl. Surf. Sci., 500, 144043 (2019)
  24. Li Z, Yang DP, Chen Y, Du Z, Guo Y, Huang J, Li Q, Mol. Catal., 483 (2020)
  25. Djinovic P, Ristic A, Zumbar T, Dasireddy VDBC, Rangus M, Drazic G, Popva M, Likozar B, Logar NZ, Tusar NN, Appl. Catal. B: Environ., 268, 118749 (2020)
  26. Wang J, Yoshida A, Wang P, Yu T, Wang Z, Hao X, Abudula A, Guan G, Appl. Catal. B Environ., 271, 118941 (2019) (2020).
  27. Karthik M, Lin LY, Bai H, Microporous Mesoporous Mater., 117(1-2), 153 (2009)
  28. Tsoncheva T, Issa G, Nieto JML, Blasco T, Concepcion P, Dimitrov M, Atanasova G, Kovacheva D, Microporous Mesoporous Mater., 180, 156 (2013)
  29. Palacio LA, Silva ER, Catalao R, Silva JM, Hoyos DA, Ribeiro FR, Ribeiro MR, J. Hazard. Mater., 153(1-2), 628 (2008)
  30. Wei G, Liu P, Chen D, Chen T, Liang X, Chen H, Appl. Clay Sci., 182, 105280 (2019)
  31. Hoseini S, Rahemi N, Allahyari S, Tasbihi M, J. Clean Prod., 232, 1134 (2019)
  32. Wang J, Zhao H, Song J, Zhu T, Xu W, Catalysts, 9(9) (2019)
  33. Liu G, Yue R, Jia Y, Ni Y, Yang J, Liu H, Wang Z, Wu X, Chen Y, Particuology, 11(4), 454 (2013)
  34. Tian ZY, Ngamou PHT, Vannier V, Kohse-Hoinghaus K, Bahlawane N, Appl. Catal. B: Environ., 117-118, 125 (2012)
  35. Wang C, Sasmaz E, Wen C, Lauterbach J, Catal. Today, 258, 481 (2015)
  36. Yao X, Xiong Y, Sun J, Gao F, Deng Y, Tang C, Dong L, J. Rare Earths, 32(2), 131 (2014)
  37. Aguilera DA, Perez A, Molina R, Moreno S, Appl. Catal. B: Environ., 104(1-2), 144 (2011)
  38. Jampaiah D, Venkataswamy P, Coyle VE, Reddy BM, Bhargava SK, RSC Adv., 6(84), 80541 (2016)
  39. Kim MH, Cho KH, Shin CH, Kang SE, Ham SW, Korean J. Chem. Eng., 28(4), 1139 (2011)
  40. Wang Y, Yang D, Li S, Zhang L, Zheng G, Guo L, Chem. Eng. J., 357, 258 (2018)(2019).
  41. Kondrat SA, Davies TE, Zu ZL, Boldrin P, Bartley JK, Carley AF, Taylor SH, Rosseinsky MJ, Hutchings GJ, J. Catal., 281(2), 279 (2011)
  42. Chen H, Wang J, Li H, Wu D, Yao M, Li Y, Appl. Catal. A: Gen., 427-428, 73 (2012)
  43. Behar S, Gonzalez P, Agulhon P, Quignard F, Swierczynski D, Catal. Today, 189(1), 35 (2012)
  44. Li ZX, Wang HL, Wu XX, Ye QL, Xu XT, Li B, Wang F, Appl. Surf. Sci., 403, 335 (2017)
  45. Hasegawa YI, Maki RU, Sano M, Miyake T, Appl. Catal. A: Gen., 371(1-2), 67 (2009)
  46. Dey S, Dhal GC, Mater. Today Chem., 14, 100180 (2019)
  47. Veerapandian SKP, Ye Z, Giraudon JM, De Geyter N, Morent R, Lamonier JF, J. Hazard. Mater., 379, 120781 (2019)
  48. Wei G, Zhang Q, Zhang D, Wang J, Tang T, Wang H, Liu X, Song Z, NIng P, Appl. Surf. Sci., 497, 143777 (2019)
  49. Veprek S, Cocke DL, Kehl S, Oswald HR, J. Catal., 100(1), 250 (1986)
  50. Chen H, Tong XL, Li YD, Appl. Catal. A: Gen., 370(1-2), 59 (2009)
  51. Mars P, van Krevelen DW, Chem. Eng. Sci., 3, 41 (1954)
  52. Li D, Shen G, Tang W, Liu H, Chen Y, Particuology, 14, 71 (2014)
  53. Fu X, Feng J, Wang H, Ng KM, Catal. Commun., 10(14), 1844 (2009)
  54. Hong YS, Sin KR, Pak JS, Kim CJ, Liu BS, Energy Fuels, 31(9), 9874 (2017)
  55. Zhu J, Gao Q, Microporous Mesoporous Mater., 124, 144 (2009)
  56. Zhang FM, Liu BS, Zhang Y, Guo YH, Wan ZY, Subhan F, J. Hazard. Mater., 223-234, 219 (2012)
  57. Bui VKH, Park D, Pham TN, An Y, Choi JS, Lee HU, Kwon OH, Moon JY, Kim KT, Lee YC, Sci. Rep., 9(1), 1 (2019)
  58. Li J, Chen Y, Wu QS, Wu J, Xu YY, J. Mater. Sci., 54(2), 1341 (2019)
  59. Wu H, Xu X, Shi L, Yin Y, Zhang LC, Wu Z, Duan X, Wang S, Sun H, Water Res., 167, 115110 (2019)
  60. Zhao Q, Zheng Y, Song C, Liu Q, Ji N, Ma D, Lu X, Appl. Catal. B: Environ., 265, 118552 (2019)
  61. Mamaghani AH, Haghighat F, Lee CS, Appl. Catal. B: Environ., 269 (2020)
  62. Li J, Jiang J, Zhao D, Xu Z, Liu M, Liu X, Tong H, Qian D, Electrochim. Acta, 330, 135196 (2020)
  63. Tabakova T, Kolentsova E, Dimitrov D, Ivanov K, Manzoli M, Venezia AM, Karakirova Y, Petrova P, Nihtianova D, Avdeev G, Top. Catal., 60(1-2), 110 (2017)
  64. Cu-mn T, Juan W, JIA, Bing, 32(8), 2084 (2016)
  65. Biswas S, Mullick K, Chen SY, Kriz DA, Shakil M, Kuo CH, Angeles-Boza AM, Rossi AR, Suib SL, ACS Catal., 6(8), 5069 (2016)
  66. Genuino HC, Dharmarathna S, Njagi EC, Mei MC, Suib SL, J. Phys. Chem. C, 116(22), 12066 (2012)
  67. Morales MR, Barbero BP, Cadus LE, Appl. Catal. B: Environ., 67(3-4), 229 (2006)
  68. Ye Z, Giraudon JM, Nuns N, Simon P, De Geyter N, Morent R, Lamonier JF, Appl. Catal. B: Environ., 223, 154 (2018)
  69. Behar S, Gomez-Mendoza NA, Gomez-Garcia MA, Swierczynski D, Quignard F, Tanchoux N, Appl. Catal. A: Gen., 504, 203 (2015)
  70. Morales MR, Yeste MP, Vidal H, Gatica JM, Cadus LE, Fuel, 208, 637 (2017)
  71. Lu H, Kong X, Huang H, Zhou Y, Chen Y, J. Environ. Sci., 32, 102 (2015)
  72. Vu VH, Belkouch J, Ould-Dris A, Taouk B, J. Hazard. Mater., 169(1-3), 758 (2009)
  73. Tang WX, Wu XF, Li SD, Shan X, Liu G, Chen YF, Appl. Catal. B: Environ., 162, 110 (2015)
  74. Cao H, Li X, Chen Y, Gong M, Wang J, J. Rare Earths, 30(9), 871 (2012)
  75. Lu H, Zhou Y, Huang H, Zhang B, Chen Y, J. Rare Earths, 29(9), 855 (2011)
  76. Kolentsova EN, Dimitrov DY, Ivanov KI, Tabakova TT, Karakirova YG, 49, (L) 59(2017).
  77. Liu LZ, Li JX, Zhang HB, Li L, Zhou P, Meng XL, Guo MM, Jia JP, Sun TH, J. Hazard. Mater., 362, 178 (2019)
  78. Yan D, Yan P, Cheng S, Chen J, Zhuo R, Feng J, Zhang G, Cryst. Growth Des., 9(1), 218 (2009)
  79. Liang S, Teng F, Bulgan G, Zong R, Zhu Y, J. Phys. Chem. C, 112(14), 5307 (2008)
  80. Ding KQ, Int. J. Electrochem. Sci, 5(1), 72 (2010)
  81. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T, Pure Appl. Chem., 57(4), 603 (1985)
  82. Alifanti M, Florea M, Somacescu S, Parvulescu VI, Appl. Catal. B: Environ., 60(1-2), 33 (2005)
  83. Li XW, Dai HX, Deng JG, Liu YX, Zhao ZX, Wang Y, Yang HG, Au CT, Appl. Catal. A: Gen., 458, 11 (2013)
  84. Ji K, Dai H, Deng J, Li X, Wang Y, Gao B, Bai G, Au CT, Appl. Catal. A: Gen., 447-448, 41 (2012)
  85. Zhang JY, Weng XL, Wu ZB, Liu Y, Wang HQ, Appl. Catal. B: Environ., 126, 231 (2012)
  86. Liu Y, Dai H, Deng J, Du Y, Li X, Zhao Z, Wang Y, Gao B, Yang H, Guo G, Appl. Catal. B: Environ., 140-141, 493 (2013)
  87. Zhou G, He X, Liu S, Xie H, Fu M, J. Ind. Eng. Chem., 21, 932 (2015)
  88. Chen J, Chen X, Xu WJ, Xu Z, Chen JZ, Jia HP, Chen J, Chem. Eng. J., 330, 281 (2017)
  89. Si W, Wang Y, Zhao S, Hu F, Li J, Environ. Sci. Technol., 50(8), 4572 (2016)
  90. Liu Y, Dai H, Deng J, Zhang L, Zhao Z, Li X, Wang Y, Xie S, Yang H, Guo G, Inorg. Chem. (2013).
  91. Chen SY, Song W, Lin HJ, Wang S, Biswas S, Mollahosseini M, Kuo CH, Gao PX, Suib SL, ACS Appl. Mater. Interfaces, 8(12), 7834 (2016)
  92. He C, Cheng J, Zhang X, Douthwaite M, Pattisson S, Hao ZP, Chem. Rev., 119(7), 4471 (2019)
  93. Gao W, Zhang Z, Li J, Ma Y, Qu Y, Nanoscale, 7(27), 11686 (2015)