화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.28, No.12, 1074-1081, November, 2020
DOI10.1007/s13233-020-8150-9  Export Citation
Symmetric Supercapacitor Application of Anhydrous Gel Electrolytes Comprising Doped Tetrazole Terminated Flexible Spacers
Seyda T. Gunday, Emre Cevik1, Ismail Anil2, Omar Alagha2, Hussein Sabit1, and Ayhan Bozkurt†
  • Department of Biophysics, Institute for Research and Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University, 1982, PO Box:1982, Dammam, 31441, Saudi Arabia
  • 1Department of Genetic Research, Institute for Research and Medical Consultations (IRMC, Imam Abdulrahman Bin Faisal University, PO Box:1982, Dammam, 31441, Saudi Arabia
  • 2Environmental Engineering Department, College of Engineering, Imam Abdulrahman Bin Faisal University, Main Campus, P.O. Box 1982, Dammam, 31441, Saudi Arabia
E-mail:
The current research aimed to produce anhydrous gel organic electrolytes with superior performance for high-temperature supercapacitor applications. Within this scope, anhydrous electrolytes were designed by the termination of 1,4-butanediol diglycidyl ether (BDE] with 5-aminotetrazole (AT). The BDE(AT]2 was further doped with phosphoric acid (PA] and l-Ethyl-3-methylimidazolium tetra-fluoroborate (EMT, as an ionic liquid] at varied ratios. The structure of fabricated electrolytes was elucidated with various spectroscopic techniques, and thermal studies confirmed high thermal stabilities and low glass transition temperatures, suggesting that they could be used in a wide temperature range. Different supercapacitor systems, in combination with carbon-based electrodes and BDE(AT)2, BDE(AT)2-0.1EMT, and BDE(AT)2-PA-0.1EMT electrolytes, were constructed. The supercapacitor device in combination with BDE(AT)2-PA-0.1EMT electrolyte, showed the highest ionic conductivity value of 1.2×10-4 S cm-1. The electrode/electrolyte combination demonstrated a maximum specific capacitance (80.4 F g-1), the highest specific energy (2.91 Wh kg-1), and highly effective electrochemical reversibility (up to 2.250 cycles). The supercapacitor device illustrated a better performance at higher temperatures in terms of its specific capacitance value.
Keywords:anhydrous gel electrolyte;supercapacitor;ionic liquid;tetrazole
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