화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.29, No.1, 24-32, January, 2021
DOI10.1007/s13233-021-9006-7  Export Citation
Synthesis, Polymerization Kinetics and Thermal Properties of Benzoxazine Resin Containing ortho-Maleimide Functionality
Boran Hao, Yuqi Liu, Xinye Yu, and Kan Zhang†
  • School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, P. R. China
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A benzoxazine monomer with ortho-maleimide functionality has been synthesized using ortho-maleimide functional phenol, aniline and paraformaldehyde as starting materials. The chemical structure of this benzoxazine monomer is verified by 1H and 13C nuclear magnetic resonance (NMR) and Fourier transform infrared (FT-IR) spectroscopies, elemental analysis as well as high-resolution mass spectrometry. The polymerization behavior of benzoxazine has been studied by differential scanning calorimetry (DSC) and in situ FT-IR. Besides, the kinetic parameters have been calculated by non-isothermal DSC with different heating rates. The apparent activation energy value of the ortho-maleimide functional benzoxazine is calculated to be 72.43 kJ/mol based on the Starink method. In addition, our predicted thermograms based on the developed model fit well with the curves obtained from experimental DSC results. Moreover, DSC and thermogravimetric analyses (TGA) are used to determine the thermal properties of the cross-linked thermoset. The resulting polybenzoxazine derived from ortho-maleimide functional shows excellent thermal stability (T g of 247 °C ; T d5 of 333 °C ), evidencing its great potential application in high-performance fields.
Keywords:benzoxazine;maleimide;polymerization kinetics;thermal properties
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