화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.38, No.3, 485-497, March, 2021
Degradation mechanism, reaction pathways and kinetics for the mineralization of Bisphenol A using hybrid ZnO/graphene oxide nano-catalysts
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Removal of Bisphenol A (BPA) from surface waters is necessary before consumption. A study, therefore, was conducted to degrade BPA using graphene oxide, ZnO and ZnO decorated on graphene oxide. Hydrothermal method was used to synthesize the hybrid nano-catalysts. 99.5% photocatalytic degradation of BPA was achieved by using ZG0.6 nano-catalyst in comparison to bare ZnO and GO nano-catalysts at natural pH of 7.5 in 60 min of UV irradiation. The higher photocatalytic activity of ZG0.6 nano-catalyst could be ascribed to an improved surface area, efficient charge separation as well as the decreased recombination rate of electron-hole charge carriers, leading to the generation of highly reactive hydroxyl radicals for the degradation of BPA. Photocatalytic degradation followed Langmuir-Hinshelwood model with pseudo-first-order kinetics. The degradation mechanism is also detailed with identification of reaction intermediates. Degradation pathways, based on LCMS analysis, have been proposed. The pathways revealed the formation of smaller by-products such as phenol, hydroquinol and (Z)-3-hydroxyacrylaldehyde. The developed ZG0.6 nano-catalyst were found to be reusable for consecutive five runs without much loss in the activity and have the advantage of effective charge separation.
  1. Katsumata H, Kawabe S, Kaneco S, Suzuki T, Ohta K, J. Photochem. Photobiol. A-Chem., 162, 297 (2004)
  2. Simsek EB, Appl. Catal. B: Environ., 200, 309 (2017)
  3. Santhosh C, Malathi A, Daneshvar E, Kollu P, Bhatnagar A, Sci. Rep., 8, 15531 (2018)
  4. Abdelraheem WHM, Patil MK, Nadagouda MN, Dionysiou DD, Appl. Catal. B: Environ., 241, 598 (2019)
  5. Flint S, Markle T, Thompson S, Wallace E, J. Environ. Manage., 104, 19 (2012)
  6. Repousi V, Petala A, Frontistis Z, Antonopoulou M, Konstantinou I, Kondarides DI, Mantzavinos D, Catal. Today, 284, 59 (2017)
  7. Gerhardt A, J. Toxicol. Risk Assess., 5, 17 (2019)
  8. Yamamoto T, Yasuhara A, Shiraishi H, Nakasugi O, Chemosphere, 42, 415 (2001)
  9. Zhang H, Zhang Y, Li J, Yang M, Sci. Total Environ., 655, 607 (2019)
  10. Al-Kahtani AA, Alshehri SM, Naushad M, Ruksana, Ahamad T, Int. J. Biol. Macromol., 121, 415 (2019)
  11. EFSA, EFSA J., 13, 3978 (2015)
  12. Atchudan R, Edison TNJI, Perumal S, Shanmugam M, Lee YR, J. Photochem. Photobiol. A-Chem., 337, 100 (2017)
  13. Jain B, Hashmi A, Sanwaria S, Singh AK, Susan MABH, Singh A, Adv. Compos. Hybrid Mater., 3, 231 (2020)
  14. Nguyen VN, Trinh D, Manh T, Nguyen T, Res. Chem. Intermed., 44, 3081 (2018)
  15. Maruthupandy M, Qin P, Muneeswaran T, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 254, 114516 (2020)
  16. Durmus Z, Kurt BZ, Durmus A, ChemistrySelect, 4, 271 (2019)
  17. Phatthanakittiphong T, Seo GT, Nanomaterials, 6, 128 (2016)
  18. Xu J, Wang L, Zhu YF, Langmuir, 28(22), 8418 (2012)
  19. Dukkancı M, Chem. Biochem. Eng. Q., 33, 43 (2019)
  20. Hak CH, Sim LC, Leong KH, Chin YH, Saravanan P, IOP Conf. Ser. Mater. Sci. Eng., 409, 012008 (2018)
  21. Ozmen M, Gungordu A, Erdemoglu S, Ozmen N, Aquat. Toxicol., 165, 144 (2015)
  22. Bechambi O, Sayadi S, Najjar W, J. Ind. Eng. Chem., 32, 201 (2015)
  23. Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
  24. Xu Y, Jin JJ, Li XL, Han YD, Meng H, Wang TY, Zhang X, Mater. Res. Bull., 76, 235 (2016)
  25. Garg R, Gupta R, Bansal A, Int. J. Environ. Sci. Technol., In press (2020).
  26. Chauhan PS, Kant R, Rai A, Gupta A, Bhattacharya S, Mater. Sci. Semicond. Process, 89, 6 (2019)
  27. Dai K, Lu LH, Liang CH, Dai JM, Zhu GP, Liu ZL, Liu QZ, Zhang YX, Mater. Chem. Phys., 143(3), 1410 (2014)
  28. Qin JQ, Zhang XY, Xue YN, Kittiwattanothai N, Kongsittikul P, Rodthongkum N, Limpanart S, Ma MZ, Liu RP, Appl. Surf. Sci., 321, 226 (2014)
  29. Al-hamadani YAJ, Lee G, Kim S, Park CM, Jang M, Chemosphere, 205, 719 (2018)
  30. Archana S, Kumar KY, Jayanna BK, Olivera S, Anand A, Prashanth MK, Muralidhara HB, J. Sci. Adv. Mater. Devices, 3, 167 (2018)
  31. Rahmat NA, Hadibarata T, Yuniarto A, Elshikh MS, Syafiuddin A, IOP Conf. Ser. Mater. Sci. Eng., 495, 012059 (2019)
  32. Verma A, Toor AP, Prakash NT, Bansal P, Sangal VK, New J. Chem., 41, 6296 (2017)
  33. Su R, Xue Y, Zhang G, Wang Q, Hu L, Wang P, Photochem. Photobiol., 92, 775 (2016)
  34. Daneshvar N, Aber S, Dorraji MSS, Khataee AR, Rasoulifard MH, Sep. Purif. Technol., 58(1), 91 (2007)
  35. Fatehah MO, Aziz HA, Stoll S, J. Colloid Sci. Biotechnol., 3, 75 (2014)
  36. Kumar KV, Porkodi K, Rocha F, Catal. Commun., 9, 82 (2008)
  37. Oh WD, Lok LW, Veksha A, Giannis A, Lim TT, Chem. Eng. J., 333, 739 (2017)
  38. Regmi C, Dhakal D, Lee SW, Nanotechnology, 29, 64001 (2018)