화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.38, No.4, 653-673, April, 2021
DOI10.1007/s11814-020-0730-z  Export Citation
Porphyrinic zirconium metal-organic frameworks: Synthesis and applications for adsorption/catalysis
Kwangsun Yu, Dong-Il Won1, Wan In Lee1, and Wha-Seung Ahn†
  • Department of Chemical Engineering, Inha University, Incheon 22201, Korea
  • 1Department of Chemistry, Inha University, Incheon 22201, Korea
E-mail:
Zr-based porphyrinic MOFs, which have isolated porphyrin units imbedded in MOFs' rigid structure, exhibit excellent textural properties and high stability. Among the porphyrin ligands, tetrakis(4-carboxyphenyl)-porphyrin (TCPP) is broadly employed, and so far, seven Zr-based porphyrinic MOFs of MOF-525, MOF-545 (also named PCN-222), PCN-221, PCN-223, PCN-224, PCN-225, and NU-902 have been synthesized using TCCP. The built-in TCPP ligand with various functionality and coordinatively unsaturated Zr clusters can be subjected to diverse pre- and post-synthesis functionalization or guest encapsulation. Aided by the excellent hydrothermal/chemical stability and high porosity, these Zr-based porphyrinic MOFs are gaining attention for applications in adsorption, sensors, heterogeneous catalysis for chemical conversions, photocatalysis, electrocatalysis, and others. This paper reviews the current status of research and development on the synthesis, characterization, functionalization, and adsorption/catalysis applications of Zr-based porphyrinic MOFs.
Keywords:Zr-based Porphyrinic MOFs;Synthesis;Functionalization;Adsorption;Heterogeneous Catalysis
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