화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.106, 503-511, February, 2022
DOI10.1016/j.jiec.2021.11.031  Export Citation
Studies of methanol electro-oxidation with ternary wet-chemically prepared ZCSO hexagonal nanodiscs with electrochemical approach
Mohammed M. Rahman1, 2, †, M.M. Alam2, Abdullah M. Asiri1, 2, Sulaiman Y.M. Alfaifi1, and Hadi M. Marwani1, 2
  • 1Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia
  • 2Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah 21589, P.O. Box 80203, Saudi Arabia
E-mail:
High performance acute toxic methanol sensor based on hydrothermally prepared hexagonal nanodiscs (NDs) of ZnO/CdO/SnO2 (ZnCdSnO2 or ZCSO) was fabricated onto glassy carbon electrode (GCE). The characterization of ZCSO NDs in-terms of functional group analysis, binding energy evaluation, oxidation states, optical absorbance, crystallinity, structural morphology, and elemental compositions were performed by FTIR spectroscopy, X-ray photoelectron spectroscopy (XPS), UV-visible spectroscopy, XRD, FESEM-coupled-EDS analysis respectively. The current versus concentration plot was exhibited linear on a wide range of methanol concentration (0.01 nM to 0.1 mM) clarified as linear dynamic methanol detection range (LDR). Considering the ZCSO NDs-coated surface area onto GCE over the slope of LDR, noticeable methanol sensor sensitivity (4.5475 mA μM-1 cm-2) was perceived. Besides this, a considerable lower limit (7.69 ± 0.38 pM) of detection at signal/noise = 3 is obtained. The overall results of methanol chemical sensor were found with satisfactory and acceptable results in terms of their reproducibility, sensitivity, stability, and response-time. Additionally, the assembled ZCSO NDs-coated electrode was validated with real environmental samples and result was found good and acceptable. On considering the outcome of applicability and the way of this sensor assembling, this unique method might be a potential technique in the field of portable sensor development for the safety of environmental and healthcare fields in a broad scale.
Keywords:Methanol detection;Electrochemical approach;ZCSO nanodiscs;Sensitivity;Healthcare safety
  1. Meng D, Zhang S, Thomas T, Huang C, Zhao J, Zhao R, Shi Y, Qu F, Yang M, Sens. Actuators, B, 307 (2020)
  2. Olah GA, Angew. Chem. Int. Ed. Eng., 44, 2636 (2005)
  3. Zheng W, Lu X, Wang W, Dong B, Zhang H, Wang Z, J. Am. Ceram. Soc., 93, 15 (2010)
  4. Phasuksom K, Ouajai WP, Sirivat A, Sens. Actuators, B, 262, 1013 (2018)
  5. Paulraj R, Shankar P, Mani GK, Nallathambi L, Rayappan JBB, J. Mater. Sci. Mater. Electron., 28, 10799 (2017)
  6. Jain N, Himanshu D, Verma SP, Parihar A, Ann. Saudi Med., 33, 68 (2013)
  7. Rubinstein D, Escott E, Kelly JP, AJNR Am. J. Neuroradiol., 16, 1492 (1995)
  8. Q. Kang, L.X. Yang, Q.Y. Cai, Bioelectrochemistry, 74, 62 (2008)
  9. Wanekaya AK, Uematsu M, Breimer M, Sadik OA, Sens. Actuat. B, 110, 41 (2005)
  10. Wrobel K, Rodr?guez DM, Aguilar FJA, Wrobel K, Talanta, 66, 125 (2005)
  11. Evtugyn GA, Budnikov HC, Nikolskaya EB, Talanta, 46 (1998)
  12. Qin D, Cadet G, Anal. Chem., 69, 1942 (1997)
  13. Lee MS, Shim JSJ, Lee WM, Sens. Actuat. B, 124, 323 (2007)
  14. Blanco M, Coello J, Iturriaga H, Maspoch S, Porcel M, Anal. Chim. Acta., 398, 83 (1999)
  15. Almuzara C, Cos O, Baeza M, Gabriel D, Valero F, Biotechnol. Lett., 24, 413 (2002)
  16. Harraz FA, Faisal M, Jalalah M, Almadiy AA, Al-Sayari SA, Al-Assiri MS, Appl. Surf. Sci., 508 (2020)
  17. Tao B, Zhang J, Hui S, Chen X, Wan L, Electrochim. Acta., 55, 5019 (2010)
  18. Hira SA, Annas D, Nagappan S, Kumar YA, Song S, Kim HJ, Park S, Park KH, J. Environ. Chem. Eng., 9 (2021)
  19. Karimi Z, Shamsipur M, Tabrizi MA, Rostamnia S, Anal. Biochem., 548, 32 (2018)
  20. Rahman MM, Hussein MA, Alamry KA, Al-Shehry FM, Asiri AM, Talanta, 150, 71 (2016)
  21. Rahman MM, Khan SB, Jamal A, Faisal M, Asiri AM, Talanta, 95, 18 (2012)
  22. Alam MM, Asiri AM, Uddin MT, Rahman MM, Islam MA, RSC Adv., 10, 44641 (2020)
  23. Alam MM, Mukhlish MZB, Tazrin A, Jui NA, Asiri AM, Rahman MM, Islam MA, Uddin MT, RSC Adv., 10, 32532 (2020)
  24. Alam MM, Uddin MT, Asiri AM, Awual MR, Fazal MA, Rahman MM, Islam MA, Mater. Chem. Phys., 251 (2020)
  25. Alam MM, Asiri AM, Rahman MM, Islam MA, SN Appl. Sci., 2, 1953 (2020)
  26. Alam MM, Asiri AM, Rahman MM, Islam MA, Surf. Interfaces, 19 (2020)
  27. Alam MM, Asiri AM, Rahman MM, Microchem. J., 165 (2021)
  28. Alam MM, Uddin MT, Asiri AM, Rahman MM, Islam MA, Measurement, 163 (2020)
  29. Alam MM, Uddin MT, Asiri AM, Rahman MM, Islam MA, Arab. J. Chem., 13, 5406 (2020)
  30. Rahman MM, Alam MM, Asiri AM, J. Ind. Eng. Chem., 62, 392 (2018)
  31. Sirohil K, Kumar S, Singh V, Vohra A, Acta Metall. Sin., 31, 254 (2018)
  32. Kumar PS, Selvakumar M, Bhagabati P, Bharathi B, Karuthapandian S, Balakumar S, RSC Adv., 4, 32977 (2014)
  33. Ghaderi A, Abbasi S, Farahbod F, Iran. J. Chem. Eng., 12, 3 (2015)
  34. Majumder S, Mater. Sci.-Poland, 27, 1 (2009)
  35. Lupan O, Chowa L, Chai G, Heinrich H, Park S, Schulte A, J. Cryst. Growth, 311, 152 (2008)
  36. Wang J, Fan H, Yu H, J. Nanomater., 395483 (2015)
  37. Mostafaei A, Zolriasatein A, Prog. Nat. Sci. Mater. Int., 22, 273 (2012)
  38. Zak AK, Razali R, Majid WHA, Darroudi M, Int. J. Nanomed., 6, 1399 (2011)
  39. Kumari R, Singh P, Kumar V, J. Mater. Sci. Mater. Electron., 29, 8989 (2018)
  40. Aldwayyan AS, Al-Jekhedab FM, Al-Noaimi M, Hammouti B, Hadda TB, Suleiman M, Warad I, Int. J. Electrochem. Sci., 8, 10506 (2013)
  41. Karthik K, Dhanuskodi S, Gobinath C, Prabukumar S, Sivaramakrishnan S, Mater. Res. Innovations (2018).
  42. Alam MM, Rahman MM, Uddin MT, Asiri AM, Inamuddin, Chani MTS, Islam MA, J. Lumin, 227 (2020)
  43. Alam MM, Mukhlish MZB, Tazrin A, Jui NA, Asiri AM, Rahman MM, Islam MA, Uddin MT, RSC Adv, 10, 32532 (2020)
  44. M.M. Alam, A.M. Asiri, M.M. Rahman, Microchem. J., 165 (2021)
  45. M.M. Alam, A.M. Asiri, M.M. Rahman, M.A. Islam,, SN Appl. Sci., 2, 1953 (2020)
  46. Jadhav H, Suryawanshi S, More MA, Sinha S, Appl. Surf. Sci., 419, 764 (2017)
  47. Wang J, Li H, Meng S, Ye X, Fu X, Chen S, RSC Adv., 7, 27024 (2017)
  48. Junfeng H, Liu X, Limei C, Hamon J, Besland MP, Mater. Sci. Semicond. Process., 40, 402 (2015)
  49. Alam MM, Uddin MT, Asiri AM, Rahman MM, Islam MA, Measurement, 163 (2020)
  50. Rahman MM, Alam MM, Asiri AM, Uddin J, New J. Chem., 44, 2001 (2020)
  51. Rahman MM, Alam MM, Asiri AM, RSC Adv., 9, 42050 (2019)
  52. Rahman MM, Alam MM, Asiri AM, RSC Adv., 9, 35146 (2019)
  53. Alam MM, Asiri AM, Rahman MM, Islam MA, Mater. Chem. Phys., 244 (2020)
  54. Alam MM, Asiri AM, Uddin MT, Islam MA, Rahman MM, Nanoparticle, 3, 11460 (2018)
  55. Alam MM, Asiri AM, Uddin MT, Inamuddin, Islam MA, Awual MR, Rahman MM, New J. Chem., 43, 4849 (2019)
  56. Alam MM, Asiri AM, Uddin MT, Islam MA, Awual MR, Rahman MM, New J. Chem., 43, 8651 (2019)
  57. Rahman MM, Alam MM, Alamry KA, J. Ind. Eng. Chem., 77, 309 (2019)
  58. Khan A, Khan AAP, Rahman MM, Alamry KA, Asiri AM, RSC Adv., 5, 105169 (2015)
  59. Rahman MM, Abu-Zied BM, Hasan MM, Asiri AM, Hasnat MA, RSC Adv., 6, 48435 (2016)
  60. Ghann W, Sharma V, Kang H, Karim F, Richards B, Mobin SM, Uddin J, Rahman MM, Hossain MF, Kabir MH, Uddin MN, Int. J. Hydrogen Energy, 44, 14580 (2019)
  61. Shakeel N, Ahamed MI, Ahmed A, Inamuddin MM, Rahman AMA, Int. J. Hydrogen Energy, 44, 28294 (2019)
  62. Karim MR, Rahman MM, Asiri AM, Hayami S, ACS Appl. Mater. Interfaces, 12, 10829 (2020)