A novel method was developed for the preparation of high-resistivity conductive polymer composites reproducibly. The conventional method which involves the simple mixing of a conductive filler and a polymer usually produces a conductive polymer composite having a loading curve with a region in which the resistivity changes rapidly as the filler concentration changes. Hence, it is very difficult to obtain reproducible materials in that region. This newly developed method involves the preparation of a conventional conductive polymer composite, which is prepared by the simple mixing of carbon black and a polymer as the first step. The resulting compound, which is crosslinked by either electron-beam radiation or a chemical-crosslinking agent, is ground into a fine powder (composite filler) with the particle size less than 250 microns. The composite filler is mixed with another polymer to form a conductive particulate composite which has a loading curve showing a more gradual change of resistivity as a function of filler concentration. The modification of the loading curve is controlled by the resistivity, the shape, and the size of the composite filler.