화학공학소재연구정보센터
Thin Solid Films, Vol.280, No.1-2, 265-270, 1996
Analysis of the Oxidation-Kinetics and Barrier Layer Properties of Zrn and Pt/Ru Thin-Films for DRAM Applications
ZrN and Pt/Ru thin films have been grown by an automated ion beam sputter-deposition system. Both materials were evaluated for use as barrier layers (ZrN) and bottom electrodes (Pt/Ru) in dynamic random access memory (DRAM) applications. The ZrN films had resistivities on the order of 250-300 mu Omega cm. The ZrN films were (002) oriented and were rather smooth with an average surface roughness of +/- 17 Angstrom. Analysis of the oxidation kinetics of the ZrN thin films reveals a thermally activated, diffusion-limited oxidation process with an activation energy of 2.5 eV in the temperature range of 500-650 degrees C. This implies that there is an advantage in using ZrN as a barrier layer instead of TiN since the activation energy for oxidation of TiN is 2.05 eV. In addition, preliminary data suggest that a Pt/Ru double layer may be a promising bottom electrode and oxygen diffusion barrier for use in DRAMs with high-permittivity dielectrics.