트리브로모 변성폴리에스테르를 함유한 PU 난연도료의 합성과 도막 특성화

박은경; 양인모; 김대원; 황규현; 박홍수; Eun-Kyung Park; In-Mo Yang; Dae-Won Kim; Kyu-Hyu Hwang; Hong-Soo Park

Polymer(Korea), Vol.25, No.3, 391-398, May, 2001

Export Citation

트리브로모 변성폴리에스테르를 함유한 PU 난연도료의 합성과 도막 특성화

Synthesis and Characterization of PU Flame-Retardant Coatings Using Tribromo Modified Polyesters

박은경, 양인모¹, 김대원¹, 황규현¹, 박홍수^{1, †}

중소기업청 기술지원센터
¹명지대학교 공과대학 세라믹화학공학부

Eun-Kyung Park, In-Mo Yang¹, Dae-Won Kim¹, Kyu-Hyu Hwang¹, and Hong-Soo Park^{1, †}

SMBA Technical Assistance Center, Daejon 305-343, Korea
¹Division of Ceramic and Chemical Engineering, Myongji Univeristy, Yongin 449-728, Korea

E-mail:

초록

난연성분인 트리브로모아세트산의 함량을 10, 20, 30 wt%로 변화시키면서 1,4-부탄디올, 아디프산 및 트리메틸올프로판과 축합중합을 하여 트리브로모 변성폴리에스테르 (TBAO)를 합성한 후에, TBAO류와 이소시아네이트를 블렌드하여 2성분계 폴리우레탄 (PU) 난연도료를 제조하였다. 제조된 난연도료의 도막물성을 측정한 결과, 결코 비난연도료보다 불성이 저하되지는 않았다. 또한 난연도료의 난연성 시험결과, 수직법에서 트리브로모아세트산 20 wt%에서 불꽃에 타지 않아서 양호한 난연도료임을 알 수 있다.

Two-component polyurethane(PU) flame-retardant coatings were prepared by blending tribromo modified polyesters(TBAOs) and isocyanate. TBAOs were synthesized by condensation polymerization of tribromoacetic acid, a flame-retardant component, with 1,4-butanediol, adipic acid, and trimethylolpropane. The content of tribromoacetic acid was varied by 10, 20, and 30 wt% for the reaction. Various physical properties of these new flame-retardant coatings were comparable to nonflame-retardant coatings. Coatings with 20 wt% tribromoacetic acid did not burn during the vertical burning test.

Keywords:Tribromo Modified Polyester;Isocyanate;Polyurethane Coatings;Flame Retardancy

[References]

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Klett MW, Das B, Euro. Patent, 287,829 (1988)
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Ishii N, Konda E, Wakita T, Euro. Patent, 516,438 (1992)
Park H, Keun J, Lee K, J. Polym. Sci. A: Polym. Chem., 34(8), 1455 (1996)
Park HS, Ha KJ, Keun JH, Kim TO, J. Appl. Polym. Sci., 70(5), 913 (1998)
Park HS, Hahm HS, Park EK, J. Appl. Polym. Sci., 61(3), 421 (1996)
Park HS, Wu JP, Kim HK, J. Ind. Eng. Chem., 3(4), 282 (1997)
Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)
Tehranisa M, Ryntz RA, Xiao HX, Kordomenos PI, Frisch KC, J. Coat. Technol., 59(746), 43 (1987)
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David WG, Official Digest, 33, 642 (1961)
Park EK, Ph. D. Dissertation, Myongji Univ., Yongin, Korea (1993)
Patton TC, "Paint Flow and Figment Dispersion: A Rheological Approach to Coating and Ink Technology", 2nd Ed., Wiley, New York (1979)
Lanson HJ, "Encyclopedia of Polymer Science and Engineering", 2nd Ed., ed. by J.I. Kroschwitz, vol. 1, p. 656, Wiley, New York (1985)
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[1] Pettit DM, Vajs L, Lubomir V, Cana. Patent, 1,304,197 (1992)

[2] Klett MW, Das B, Euro. Patent, 287,829 (1988)

[3] Schmidt WG, J. Plast. Inst., 33, 247 (1965)

[4] Park HS, Wu JP, Park CH, J. Coat. Technol., 69(875), 41 (1997)

[5] Anon H, Ind. Finish., 66, 24 (1990)

[6] Woods G, "The ICI Polyurethane Book", Wiley, New York (1987)

[7] Oertel G, "Polyurethane Handbook", Hanser Publishers, New York (1985)

[8] Anderson DG, Vanderberg JT, Anal. Chem., 57, 15 (1985)

[9] Ishii N, Konda E, Wakita T, Euro. Patent, 516,438 (1992)

[10] Park H, Keun J, Lee K, J. Polym. Sci. A: Polym. Chem., 34(8), 1455 (1996)

[11] Park HS, Ha KJ, Keun JH, Kim TO, J. Appl. Polym. Sci., 70(5), 913 (1998)

[12] Park HS, Hahm HS, Park EK, J. Appl. Polym. Sci., 61(3), 421 (1996)

[13] Park HS, Wu JP, Kim HK, J. Ind. Eng. Chem., 3(4), 282 (1997)

[14] Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)

[15] Tehranisa M, Ryntz RA, Xiao HX, Kordomenos PI, Frisch KC, J. Coat. Technol., 59(746), 43 (1987)

[16] Backus JK, McAfee ER, Blue CD, McCarty CG, Boyd PM, Harasin SJ, Eakin JL, "Encyclopedia of Polymer Science and Engineering", 2nd Ed., p. 261, Wiley, New York (1989)

[17] David WG, Official Digest, 33, 642 (1961)

[18] Park EK, Ph. D. Dissertation, Myongji Univ., Yongin, Korea (1993)

[19] Patton TC, "Paint Flow and Figment Dispersion: A Rheological Approach to Coating and Ink Technology", 2nd Ed., Wiley, New York (1979)

[20] Lanson HJ, "Encyclopedia of Polymer Science and Engineering", 2nd Ed., ed. by J.I. Kroschwitz, vol. 1, p. 656, Wiley, New York (1985)

[21] Konishi H, Hirao C, "Flame Retardants", p. 42, Saiwai Shobo, Tokyo (1972)