Photo-Induced Cationic Ring-Opening Polymerization of 4-Methylene-2-styryl-1,3-dioxolane by Benzylsulfonium Salt

Jaekyeung park

Korea Polymer Journal, Vol.9, No.4, 206-209, August, 2001

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Photo-Induced Cationic Ring-Opening Polymerization of 4-Methylene-2-styryl-1,3-dioxolane by Benzylsulfonium Salt

Jaekyeung park^†

Department of Chemical Engineering, Sangju National University, Gajang-Dong Sangju, Kyungbuk 386, Korea

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One of the approaches to obtain functional polymer is polymerization of a monomer having two functional groups. Although polymerization of a monomer having two different types of functional group is general, the author has been interested in the polymerization of a monomer having two similar types of functional group.This work shows the preparation and selective polymerization of 4-methylene-2-styryl-1,3-dioxolane having two similar reactive double bonds via cationic polymerization at ambient temperature.Cationic ring-opening polymerization of 4-methylene-2-styryl-1,3-dioxolane using benzylsulfonium salt as a photo-initiator quantitatively afforded high molecular weight of poly(keto-ether).

[References]

Mizuya J, Yokozawa T, Endo T, J. Am. Chem. Soc., 111, 743 (1989)
Takahashi T, Yokozawa T, Endo T, J. Polym. Sci. A: Polym. Chem., 30, 583 (1992)
Nitadori Y, Tsuruta T, Makromol. Chem., 179, 2069 (1978)
Yokozawa T, Hayashi T, Endo T, Macromolecules, 9, 2776 (1992)
Park J, Yokozawa T, Endo T, Makromol. Chem., 194, 2017 (1993)
Park J, Yokozawa T, Endo T, J. Polym. Sci. A: Polym. Chem., 31, 1141 (1993)
Park J, Kihara N, Ikeda T, Endo T, J. Polym. Sci. A: Polym. Chem., 31, 1083 (1993)
Crivello J, Adv. Polym. Sci., 1, 62 (1984)
Takata T, Endo T, Kag. Kog. Ronbunshu, 48, 978 (1990)
Sanda F, Endo T, Kobunshi, 45, 128 (1996)
Uno H, Endo T, J. Polym. Sci. C-Polym. Lett., 23, 359 (1985)
Uno H, Endo T, Chem. Lett., 1869 (1986)
Endo T, Sato H, Takata T, Macromolecules, 20, 1416 (1987)
Morio K, Murase H, Endo T, J. Appl. Polym. Sci., 32, 5727 (1986)
Kikkawa A, Takata T, Uno H, Hiza M, Endo T, J. Polym. Sci. C-Polym. Lett., 26, 73 (1989)
Lee SB, Takata T, Endo T, Chem. Lett., 1861 (1989)
Hamazu F, Akashi S, Koizumi T, Takata T, Endo T, J. Polym. Sci. A: Polym. Chem., 29, 1675 (1991)
Hamazu F, Akashi S, Koizumi T, Takata T, Endo T, Makromol Chem. Rapid Commun., 13, 203 (1992)
Lin MP, Ikeda T, Endo T, J. Polym. Sci. A: Polym. Chem., 30, 2365 (1992)

[Referenced By]

[1] Mizuya J, Yokozawa T, Endo T, J. Am. Chem. Soc., 111, 743 (1989)

[2] Takahashi T, Yokozawa T, Endo T, J. Polym. Sci. A: Polym. Chem., 30, 583 (1992)

[3] Nitadori Y, Tsuruta T, Makromol. Chem., 179, 2069 (1978)

[4] Yokozawa T, Hayashi T, Endo T, Macromolecules, 9, 2776 (1992)

[5] Park J, Yokozawa T, Endo T, Makromol. Chem., 194, 2017 (1993)

[6] Park J, Yokozawa T, Endo T, J. Polym. Sci. A: Polym. Chem., 31, 1141 (1993)

[7] Park J, Kihara N, Ikeda T, Endo T, J. Polym. Sci. A: Polym. Chem., 31, 1083 (1993)

[8] Crivello J, Adv. Polym. Sci., 1, 62 (1984)

[9] Takata T, Endo T, Kag. Kog. Ronbunshu, 48, 978 (1990)

[10] Sanda F, Endo T, Kobunshi, 45, 128 (1996)

[11] Uno H, Endo T, J. Polym. Sci. C-Polym. Lett., 23, 359 (1985)

[12] Uno H, Endo T, Chem. Lett., 1869 (1986)

[13] Endo T, Sato H, Takata T, Macromolecules, 20, 1416 (1987)

[14] Morio K, Murase H, Endo T, J. Appl. Polym. Sci., 32, 5727 (1986)

[15] Kikkawa A, Takata T, Uno H, Hiza M, Endo T, J. Polym. Sci. C-Polym. Lett., 26, 73 (1989)

[16] Lee SB, Takata T, Endo T, Chem. Lett., 1861 (1989)

[17] Hamazu F, Akashi S, Koizumi T, Takata T, Endo T, J. Polym. Sci. A: Polym. Chem., 29, 1675 (1991)

[18] Hamazu F, Akashi S, Koizumi T, Takata T, Endo T, Makromol Chem. Rapid Commun., 13, 203 (1992)

[19] Lin MP, Ikeda T, Endo T, J. Polym. Sci. A: Polym. Chem., 30, 2365 (1992)