Adsorption Equilibrium Characteristics of 2,4-Dichlorophenoxyacetic Acid and 2,4-Dinitrophenol on Granular Activated Carbons

Sook Jin Kim; Wang Geun Shim; Tae Young Kim; Hee Moon; Seung Jai Kim; Sung Yong Cho

Korean Journal of Chemical Engineering, Vol.19, No.6, 967-977, November, 2002

Sook Jin Kim, Wang Geun Shim¹, Tae Young Kim , Hee Moon^{1, †}, Seung Jai Kim , and Sung Yong Cho

Department of Environmental Engineering, Chonnam National University, Gwangju 500-757, Korea
¹Faculty of Applied Chemistry, Chonnam National University, Gwangju 500-757, Korea

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Adsorption characteristics of 2,4-Dichlorophenoxyacetic acid (2,4-D) and 2,4-Dinitrophenol (2,4-DNP) onto granular activated carbon (GAC) were studied to obtain basic information on their removal from aqueous solution. Single component adsorption equilibria of 2,4-D and 2,4-DNP dissolved in water have been measured for three kinds of GACs (F400, SLS103, and WWL). In case of 2,4-D, the magnitude of adsorption capacity was in the order of F400>SLS103>WWL, and that for 2,4-DNP was SLS103>F400>WWL. The influence of temperature and initial pH of aqueous solution on adsorption has been discussed in detail by using the Sips equation.

Keywords:Adsorption;GAC;2,4-Dichlorophenoxyacetic Acid;2,4-Dinitrophenol;Equilibrium

[References]

Buckingham J, "Dictionary of Organic Compounds," 5th ed. and Supplements, Chapman and Hall, New York, 2, 2275 (1988)
Chen JP, Wang X, Sep. Purif. Technol., 19, 157 (2000)
Do DD, Adsorption Analysis: "Equilibria and Kinetics," Series on Chemical Engineering, Imperial College Press, 2 (1998)
EPA Health Effects Notebook for Hazardous Air Pollutants-Draft
Hornsby AG, Wauchope RD, Herner AE, "Pesticide Properties in the Environment," Springer-Verlag New York, Inc. (1996)
Hsieh CT, Teng H, Carbon, 38, 863 (2000)
Khan AR, Ataullah R, Alhaddad A, J. Colloid Interface Sci., 194(1), 154 (1997)
Kim SH, Bidkar A, Ngo HH, Vigneswaran S, Moon H, Korean J. Chem. Eng., 18(2), 163 (2001)
Ko JY, "Adsorption and Desorption of Chlorophenols Onto Nonionic Polymeric Sorbents," M.S. Thesis, Department of Chemical Technology, Chonnam National University (2001)
Lee DH, Moon H, Korean J. Chem. Eng., 18(2), 247 (2001)
Mangat SS, Elefsiniotis P, Water Res., 33, 861 (1999)
Markovska L, Meshko V, Noveski V, Korean J. Chem. Eng., 18(2), 190 (2001)
Moon JK, Keum DK, Lee WK, Korean J. Chem. Eng., 6(3), 172 (1989)
Na BK, Koo KK, Eum HM, Lee H, Song HK, Korean J. Chem. Eng., 18(2), 220 (2001)
Noll KE, Gounaris V, Hou WS, "Adsorption Technology for Air and Water Pollution Control," Lewis Publishers (1992)
Oh KH, Kim YS, Korea J. Biotechnol. Bioeng., 9, 469 (1994)
Radke CJ, Prausnitz JM, Ind. Eng. Chem. Fundam., 11, 445 (1972)
Toth J, J. Colloid Interface Sci., 94, 573 (1983)
Vroumsia T, Steiman R, Seigle-Murandi F, Benoit-Guyod JL, Chemosphere, 39, 1397 (1999)
Wong PK, Chemosphere, 41, 177 (2000)
Zumriye A, Julide Y, Waste Manage., 21, 695 (2001)

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[1] Buckingham J, "Dictionary of Organic Compounds," 5th ed. and Supplements, Chapman and Hall, New York, 2, 2275 (1988)

[2] Chen JP, Wang X, Sep. Purif. Technol., 19, 157 (2000)

[3] Do DD, Adsorption Analysis: "Equilibria and Kinetics," Series on Chemical Engineering, Imperial College Press, 2 (1998)

[4] EPA Health Effects Notebook for Hazardous Air Pollutants-Draft

[5] Hornsby AG, Wauchope RD, Herner AE, "Pesticide Properties in the Environment," Springer-Verlag New York, Inc. (1996)

[6] Hsieh CT, Teng H, Carbon, 38, 863 (2000)

[7] Khan AR, Ataullah R, Alhaddad A, J. Colloid Interface Sci., 194(1), 154 (1997)

[8] Kim SH, Bidkar A, Ngo HH, Vigneswaran S, Moon H, Korean J. Chem. Eng., 18(2), 163 (2001)

[9] Ko JY, "Adsorption and Desorption of Chlorophenols Onto Nonionic Polymeric Sorbents," M.S. Thesis, Department of Chemical Technology, Chonnam National University (2001)

[10] Lee DH, Moon H, Korean J. Chem. Eng., 18(2), 247 (2001)

[11] Mangat SS, Elefsiniotis P, Water Res., 33, 861 (1999)

[12] Markovska L, Meshko V, Noveski V, Korean J. Chem. Eng., 18(2), 190 (2001)

[13] Moon JK, Keum DK, Lee WK, Korean J. Chem. Eng., 6(3), 172 (1989)

[14] Na BK, Koo KK, Eum HM, Lee H, Song HK, Korean J. Chem. Eng., 18(2), 220 (2001)

[15] Noll KE, Gounaris V, Hou WS, "Adsorption Technology for Air and Water Pollution Control," Lewis Publishers (1992)

[16] Oh KH, Kim YS, Korea J. Biotechnol. Bioeng., 9, 469 (1994)

[17] Radke CJ, Prausnitz JM, Ind. Eng. Chem. Fundam., 11, 445 (1972)

[18] Toth J, J. Colloid Interface Sci., 94, 573 (1983)

[19] Vroumsia T, Steiman R, Seigle-Murandi F, Benoit-Guyod JL, Chemosphere, 39, 1397 (1999)

[20] Wong PK, Chemosphere, 41, 177 (2000)

[21] Zumriye A, Julide Y, Waste Manage., 21, 695 (2001)