Journal of Chemical Thermodynamics, Vol.34, No.9, 1377-1386, 2002
Excess molar volumes of (heptane+1-chloropentane) at elevated temperatures and high pressures
An apparatus for (p, V-m T) measurements of liquids and liquid mixtures was designed and tested. It operates in the temperature range 283 to 333 K and the pressure range 0.1 to 40 MPa with an accuracy in density of +/-1 (.) 10(-4) g (.) cm(-3). Its main part is a high-pressure vibrating tube densimeter working in a static mode. The apparatus was used for measuring (p, Vm, T) of (heptane + 1-chloropentane). Excess molar volumes were calculated from the data and fitted to the Redlich-Kister equation.
Keywords:heptane;1-chloropentane;binary mixture;density;excess volume;high pressure;elevated temperature