New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

Farid El-Tantawy; Nadia Abdel Aal; Yong Kiel Sung

Macromolecular Research, Vol.13, No.3, 194-205, June, 2005

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New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

Farid El-Tantawy, Nadia Abdel Aal¹, and Yong Kiel Sung^{2, †}

Department of Physics, Faculty of Science, Suez Canal University, Ismailia, Egypt
¹Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt
²Department of Chemistry, College of Science, Dongguk University, Seoul 100-715, Korea

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The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

Keywords:Ni-coated carbon black composites;polymer matrix;microstructure;electrical property;stability;mechanical property;electro-magnetic wave shielding effectiveness

[References]

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El-Tantawy F, Eur. Polym. J., 38, 567 (2002)
El-Tantawy F, Kameda K, Ohnebe H, Polym. Int., 51, 635 (2002)
El-Tantawy F, Eur. Polym. J., 37, 565 (2001)
El-Tantawy F, Proceedings of the 7th Japan International SAMPE Symposim & Exhibition, Nov. 13-16, 797 (2001)
El-Tantawy F, Sung YK, Proceedings of the 25 Arab School of Scinece & Technology, Damascus, Syria, August 28-3 September, 100 (2004)
Kang HC, Bae YH, Macromol. Res., 10(2), 67 (2002)
Jingvhang Z, Longtu L, Zhilum G, Sensor. Actuat., A5, 3108 (2001)
Lee BO, Woo WJ, Kim MS, Macromol. Mater. Eng., 286, 114 (2001)
Xiao SY, Wu G, Pan Y, Polym. Int., 44, 117 (1998)
Choi HD, Shim HW, Cho KY, Lee HJ, Park CS, Yoon HG, J. Appl. Polym. Sci., 72(1), 75 (1999)
Mihai R, Nicoleta S, Daniela R, Polym. Test, 20, 409 (2001)
Wan JL, Yong JK, Shinyoung K, Synth. Met., 113, 237 (2001)
Chi YH, Chang CW, Eur. Polym. J., 36, 2729 (2000)
Das NC, Khastgir D, Chaki TK, Chakraborty A, Compos. Pt. A-Appl. Sci. Manuf., 31, 1069 (2000)
Sack HS, Moriarity MC, Solid State Commun., 3, 93 (1995)
Xiao SY, Lie S, Pan Y, Compos. Sci. Technol., 61, 949 (2001)
Cespeds F, Fabregas EM, Alegret A, Anal. Chem., 15, 296 (1996)
Jia W, Tchoudakov R, Segal E, Joseph R, Narkis M, Siegmann A, Synth. Met., 132, 269 (2003)
Fournier J, Boiteux G, Seytre G, Marichy G, Synth. Met., 84, 839 (1996)
Vishal S, Tiwari AN, Kulkarni AR, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 41, 310 (1996)
Li GJ, Huang X, Guo JK, Chen DM, Ceram. Int., 28, 623 (2002)
Chen G, Wang W, Wu D, Wu C, Eur. Polym. J., 39, 2329 (2003)
Jacob M, Thomas S, Varughese K, Compos. Sci. Technol., 64, 955 (2004)

[Referenced By]

[1] El-Tantawy F, Kamada K, Ohnabe H, J. Appl. Polym. Sci., 87(2), 97 (2003)

[2] El-Tantawy F, Eur. Polym. J., 38, 567 (2002)

[3] El-Tantawy F, Kameda K, Ohnebe H, Polym. Int., 51, 635 (2002)

[4] El-Tantawy F, Eur. Polym. J., 37, 565 (2001)

[5] El-Tantawy F, Proceedings of the 7th Japan International SAMPE Symposim & Exhibition, Nov. 13-16, 797 (2001)

[6] El-Tantawy F, Sung YK, Proceedings of the 25 Arab School of Scinece & Technology, Damascus, Syria, August 28-3 September, 100 (2004)

[7] Kang HC, Bae YH, Macromol. Res., 10(2), 67 (2002)

[8] Jingvhang Z, Longtu L, Zhilum G, Sensor. Actuat., A5, 3108 (2001)

[9] Lee BO, Woo WJ, Kim MS, Macromol. Mater. Eng., 286, 114 (2001)

[10] Xiao SY, Wu G, Pan Y, Polym. Int., 44, 117 (1998)

[11] Choi HD, Shim HW, Cho KY, Lee HJ, Park CS, Yoon HG, J. Appl. Polym. Sci., 72(1), 75 (1999)

[12] Mihai R, Nicoleta S, Daniela R, Polym. Test, 20, 409 (2001)

[13] Wan JL, Yong JK, Shinyoung K, Synth. Met., 113, 237 (2001)

[14] Chi YH, Chang CW, Eur. Polym. J., 36, 2729 (2000)

[15] Das NC, Khastgir D, Chaki TK, Chakraborty A, Compos. Pt. A-Appl. Sci. Manuf., 31, 1069 (2000)

[16] Sack HS, Moriarity MC, Solid State Commun., 3, 93 (1995)

[17] Xiao SY, Lie S, Pan Y, Compos. Sci. Technol., 61, 949 (2001)

[18] Cespeds F, Fabregas EM, Alegret A, Anal. Chem., 15, 296 (1996)

[19] Jia W, Tchoudakov R, Segal E, Joseph R, Narkis M, Siegmann A, Synth. Met., 132, 269 (2003)

[20] Fournier J, Boiteux G, Seytre G, Marichy G, Synth. Met., 84, 839 (1996)

[21] Vishal S, Tiwari AN, Kulkarni AR, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 41, 310 (1996)

[22] Li GJ, Huang X, Guo JK, Chen DM, Ceram. Int., 28, 623 (2002)

[23] Chen G, Wang W, Wu D, Wu C, Eur. Polym. J., 39, 2329 (2003)

[24] Jacob M, Thomas S, Varughese K, Compos. Sci. Technol., 64, 955 (2004)