Progress on the Preparation of Ultra-pure Hydrogen Peroxide

Guo Yan Luan; Ping Jing Yao; Wei Ping Gao

Journal of Industrial and Engineering Chemistry, Vol.13, No.7, 1047-1053, December, 2007

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Progress on the Preparation of Ultra-pure Hydrogen Peroxide

Guo Yan Luan^{1, 2, †}, Ping Jing Yao¹, and Wei Ping Gao³

¹Department of Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian116012, China
²Department of Chemical Engineering, School of Chemical and Materials Engineering, Jilin Institute of Chemical, Jilin 132022, China
³Department of Chemical Engineering, School of Chemical and Materials Engineering, Jilin Institute of ChemicalTechnology, Jilin 132022, China

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Progress on the preparation of ultra-pure hydrogen peroxide is reviewed. The technologies include distillation and relative technologies, combination methods of ion exchange and adsorption resin, membrane separation and relative technologies, crystallization, flocculation, and adding addition agents as so well. Distillation is reliable and easy to industrialize, while purity of hydrogen peroxide distilled is not high enough. Crystallization, flocculation, and adding addition agents can only be used as accessory technologies. It is safe for membrane separation, but the life of membrane is short. Ion exchange and adsorption resin processes are simple and the product purity is high, but ion exchange resin is easy to be oxidized. It is the tendency for the preparation of ultra-pure hydrogen peroxide that distillation is used firstly and then the combination of membrane separation technologies or ion exchange and adsorption resin processes are followed.

Keywords:ultra-pure hydrogen peroxide;organic carbon compounds;impurity;purification

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[1] Xu ZL, Wei YM, Lang WZ, Chemical Reagents, 27, 633 (2005)

[2] Http://www.eb-mag.com.cn/detail.asp? unid=6313

[3] Lin Q, Geng JM, Jiang YB, Qian Y, Chem. Ind. Eng. Proc., 25, 1031 (2006)

[4] US Patent 5,456,898 (1995)

[5] US Patent 5,670,028 (1999)

[6] Kim TY, Jeung SY, Cho SY, Kang Y, Kim SJ, J. Ind. Eng. Chem., 10(5), 695 (2004)

[7] Baek KW, Song SH, Kang SH, Rhee YW, Lee CS, Lee BJ, Hudson S, Hwang TS, J. Ind. Eng. Chem., 13(3), 452 (2007)

[8] US Patent 6,001,324 (1999)

[9] US Patent 5,932,187 (1999)

[10] US Patent 5,961,947 (1999)

[11] US Patent 6,296,829 (2001)

[12] US Patent 6,540,921 (2003)

[13] US Patent 4,999,179 (1991)

[14] US Patent 6,054,109 (2000)

[15] US Patent 6,783,748 (2004)

[16] US Patent 6,939,527 (2005)

[17] US Patent 5,906,738 (1999)

[18] US Patent 6,333,018 (2001)

[19] US Patent 5,932,187 (1999)

[20] US Patent 6,001,324 (1999)

[21] US Patent 6,187,189 (2001)

[22] US Patent 6,780,206 (2004)

[23] US Patent 6,649,139 (2003)

[24] JP Patent 2,001,080,910 (2001)

[25] US Patent 5,055,286 (1991)

[26] US Patent 6,113,798 (2000)