Molar Excess Volume of Butyl Acetate with Cyclohexane or Aromatic Hydrocarbons at 298.15 K

Sanjeev Maken; Ankur Gaur; Naveen Verma; K. C. Singh; Seungmoon Lee; Jin-Won Park

Journal of Industrial and Engineering Chemistry, Vol.13, No.7, 1098-1102, December, 2007

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Molar Excess Volume of Butyl Acetate with Cyclohexane or Aromatic Hydrocarbons at 298.15 K

Sanjeev Maken^{1, 2, †}, Ankur Gaur¹, Naveen Verma³, K. C. Singh³, Seungmoon Lee¹, and Jin-Won Park¹

¹Department of Chemical Engineering, Yonsei University, Seoul, 120-749, Korea
²Department of Applied Sciences, Deenbandhu Chhotu Ram University of Science & Technology, Murthal-131 039, Haryana, Korea
³Department of Chemistry, Maharshi Dayanand University, Rohtak-124001, India

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Molar excess volume (VE) of butyl acetate [BAc](A) + cyclohexane (B), +benzene (B), +toluene (B), +o-, +m- and +p-xylene (B) were measure at 298.15 K over the entire composition range with v-shaped dilatometer. The VE values for binary mixture containing cyclohexane or benzene were found to be positive, while these were negative for the BAc + toluene, +o-, +m- and +p-xylene over the entire composition range. The VE values for an equimolar mixture vary in the order: cyclohexane > benzene > toluene ≒ o-xylene > m-xylene > p-xylene. The results are qualitatively explained in terms of the breaking and stretching of dipole-dipole interactions in self-associated BAc and the formation of attractive interactions between polar carboxyl group of butyl acetate and π-electrons of aromatic hydrocarbons.

Keywords:molar excess volume;butyl acetate;aromatic hydrocarbon;dipole-dipole interactions

[References]

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Ortega J, Espiau F, Dieppa R, Fluid Phase Equilib., 215(2), 175 (2004)
Kehiaian HV, Bravo R, Barral MP, Paz Andrade MI, Guieu R, Fluid Phase Equilib., 17, 187 (1984)
Pintos M, Bravo R, Baluja MC, Paz Andrade MI, Roux-Desgranges G, Grolier JPE, Can. J. Chem., 66, 1179 (1988)
Jimenez E, Romani L, Wilhelm E, Rouxdesgranges G, Grolier JP, J. Chem. Thermodyn., 26(8), 817 (1994)
Dakua VK, Sinha B, Roy MN, Indian J. Chem., 45, 1381 (2006)
Resa JM, Gonzalez C, Prieto S, Diez E, Iglesias M, Korean J. Chem. Eng., 23(1), 93 (2006)
Oswal S, J. Chem. Eng. Data, 66, 111 (1988)
Ramachandran D, Rambabu K, Krishnan KM, Venkateswarlu P, Raman GK, J. Chem. Eng. Data, 40(4), 815 (1995)
Kim JH, Min BR, Won J, Kang YS, J. Ind. Eng. Chem., 12(4), 594 (2006)
Ohta T, Kinoshita T, Nagata I, J. Chem. Eng. Data, 28, 36 (1983)
Gmehling J, Meents B, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 20, 177 (1992)
Dharmalingam K, Ramachandran K, Sivagurunathan P, South Afr. J. Chem., 59, 75 (2006)
Resa JM, Gonzalez C, Juez M, de Landaluce SO, Fluid Phase Equilib., 217(2), 175 (2004)
Avedis G, Grolier JPE, Fernandez J, Kehiaian HV, J. Solution Chem., 23, 135 (1994)
Maken S, Deshwal BR, Anu, Singh KC, Park SJ, Park JW, Phys. Chem. Liqs., 43, 149 (2005)
Maken S, Naveen Verma, Singh KC, Park JW, Korean J. Chem. Eng., Accepted on June 28 (2007)
Riddick JA, Bunger WB, Sakano TK, Organic Solvents, 4th Edn., Wiley/Interscience, New York (1986)
Vogel AI, A Text Book of Practical Organic Chemistry, 4th Edn., ELBS, Longman, London (1978)
Lide DR, Hand book of Chemistry and Physics, 76th Edn., CRC Press, Inc., Boca Raton, FL (1995)
Kumaran MK, McGlashan ML, J. Chem. Thermodyn., 9, 259 (1977)
Resa JM, Gonzalez C, Concha RG, Iglesias M, Phys. Chem. Liqs., 42, 493 (2004)

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[1] Ortega J, Espiau F, Toledo FJ, J. Chem. Thermodyn., 36(3), 193 (2004)

[2] Ortega J, Espiau F, Dieppa R, Fluid Phase Equilib., 215(2), 175 (2004)

[3] Kehiaian HV, Bravo R, Barral MP, Paz Andrade MI, Guieu R, Fluid Phase Equilib., 17, 187 (1984)

[4] Pintos M, Bravo R, Baluja MC, Paz Andrade MI, Roux-Desgranges G, Grolier JPE, Can. J. Chem., 66, 1179 (1988)

[5] Jimenez E, Romani L, Wilhelm E, Rouxdesgranges G, Grolier JP, J. Chem. Thermodyn., 26(8), 817 (1994)

[6] Dakua VK, Sinha B, Roy MN, Indian J. Chem., 45, 1381 (2006)

[7] Resa JM, Gonzalez C, Prieto S, Diez E, Iglesias M, Korean J. Chem. Eng., 23(1), 93 (2006)

[8] Oswal S, J. Chem. Eng. Data, 66, 111 (1988)

[9] Ramachandran D, Rambabu K, Krishnan KM, Venkateswarlu P, Raman GK, J. Chem. Eng. Data, 40(4), 815 (1995)

[10] Kim JH, Min BR, Won J, Kang YS, J. Ind. Eng. Chem., 12(4), 594 (2006)

[11] Ohta T, Kinoshita T, Nagata I, J. Chem. Eng. Data, 28, 36 (1983)

[12] Gmehling J, Meents B, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 20, 177 (1992)

[13] Dharmalingam K, Ramachandran K, Sivagurunathan P, South Afr. J. Chem., 59, 75 (2006)

[14] Resa JM, Gonzalez C, Juez M, de Landaluce SO, Fluid Phase Equilib., 217(2), 175 (2004)

[15] Avedis G, Grolier JPE, Fernandez J, Kehiaian HV, J. Solution Chem., 23, 135 (1994)

[16] Maken S, Deshwal BR, Anu, Singh KC, Park SJ, Park JW, Phys. Chem. Liqs., 43, 149 (2005)

[17] Maken S, Naveen Verma, Singh KC, Park JW, Korean J. Chem. Eng., Accepted on June 28 (2007)

[18] Riddick JA, Bunger WB, Sakano TK, Organic Solvents, 4th Edn., Wiley/Interscience, New York (1986)

[19] Vogel AI, A Text Book of Practical Organic Chemistry, 4th Edn., ELBS, Longman, London (1978)

[20] Lide DR, Hand book of Chemistry and Physics, 76th Edn., CRC Press, Inc., Boca Raton, FL (1995)

[21] Kumaran MK, McGlashan ML, J. Chem. Thermodyn., 9, 259 (1977)

[22] Resa JM, Gonzalez C, Concha RG, Iglesias M, Phys. Chem. Liqs., 42, 493 (2004)