Excess molar volumes and refractive indices at 298.15 K for the binary and ternary mixtures of diisopropyl ether plus ethanol plus 2,2,4-trimethylpentane

Se-Jin In; So-Jin Park

Journal of Industrial and Engineering Chemistry, Vol.14, No.3, 377-381, May, 2008

DOI10.1016/j.jiec.2007.12.003 Export Citation

Excess molar volumes and refractive indices at 298.15 K for the binary and ternary mixtures of diisopropyl ether plus ethanol plus 2,2,4-trimethylpentane

Se-Jin In, and So-Jin Park^{1, †}

Department of Fire and Disaster Protection Engineering, Woosong University, Daejeon 300-718, Korea
¹Department of Chemical Engineering, Chungnam National University, Daejeon 305-764, Korea

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Excess molar volumes (V-E) and deviations in molar refractivity (Delta R) data at 298.15 K are reported for the binary systems diisopropyl ether + ethanol, diisopropyl ether + 2,2,4-trimethylpentane(isooctane) and ethanol + isooctane and also for ternary systems of diisopropyl ether + ethanol + isooctane by digital vibrating tube densimeter and a precision digital refractometer. The V-E and Delta R were correlated with Redlich-Kister equation for binary systems and Cibulka equation for ternary system, respectively. Especially the ternary V-E and Delta R were compared with the estimated values from the binary contribution model equations of Tsao-Smith, Kohler, Rastogi and Radojkovic. (C) 2008 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

Keywords:excess molar volumes;deviations in molar refractivity;diisopropyl ether;ternary mixture;correlation

[References]

Arce A, Arce A, Martinez-Ageitos J, Rodil E, Rodriguez O, Soto A, Fluid Phase Equilib., 170(1), 113 (2000)
Kim DH, Kim YD, J. Ind. Eng. Chem., 13(6), 879 (2007)
Redlich O, Kister AT, J. Ind. Eng. Chem., 40, 345 (1948)
Cibulka I, Collect. Czech. Chem. Commun., 47, 1414 (1982)
Tsao CC, Smith JM, Chem. Eng. Prog. Symp. Ser., 49, 107 (1953)
Kohler F, Monatsh. Chem., 91, 738 (1960)
Rastogi RP, Nath J, Das SS, J. Chem. Eng. Data, 22, 249 (1977)
Radojkovic N, Tasic A, Grozdanic B, Malic M, J. Chem. Thermodyn., 9, 349 (1977)
Chen HW, Tu CH, J. Chem. Eng. Data, 50, 1262 (2005)
Oh JH, Park SJ, J. Chem. Eng. Data, 43, 1009 (1998)
Han KJ, Hwang IC, Park SJ, J. Chem. Eng. Data, 52, 1018 (2007)
Aminabhavi TM, Golalakrishina B, J. Chem. Eng. Data, 40, 856 (1995)
Al-Dujaili AH, Yassen AA, Awwad AM, J. Chem. Eng. Data, 45, 647 (2000)
Chen HW, Tu CH, J. Chem. Eng. Data, 51, 261 (2006)
Ku HC, Tu CH, J. Chem. Eng. Data, 50, 608 (2005)

[Referenced By]

[Related Articles]

[1] Arce A, Arce A, Martinez-Ageitos J, Rodil E, Rodriguez O, Soto A, Fluid Phase Equilib., 170(1), 113 (2000)

[2] Kim DH, Kim YD, J. Ind. Eng. Chem., 13(6), 879 (2007)

[3] Redlich O, Kister AT, J. Ind. Eng. Chem., 40, 345 (1948)

[4] Cibulka I, Collect. Czech. Chem. Commun., 47, 1414 (1982)

[5] Tsao CC, Smith JM, Chem. Eng. Prog. Symp. Ser., 49, 107 (1953)

[6] Kohler F, Monatsh. Chem., 91, 738 (1960)

[7] Rastogi RP, Nath J, Das SS, J. Chem. Eng. Data, 22, 249 (1977)

[8] Radojkovic N, Tasic A, Grozdanic B, Malic M, J. Chem. Thermodyn., 9, 349 (1977)

[9] Chen HW, Tu CH, J. Chem. Eng. Data, 50, 1262 (2005)

[10] Oh JH, Park SJ, J. Chem. Eng. Data, 43, 1009 (1998)

[11] Han KJ, Hwang IC, Park SJ, J. Chem. Eng. Data, 52, 1018 (2007)

[12] Aminabhavi TM, Golalakrishina B, J. Chem. Eng. Data, 40, 856 (1995)

[13] Al-Dujaili AH, Yassen AA, Awwad AM, J. Chem. Eng. Data, 45, 647 (2000)

[14] Chen HW, Tu CH, J. Chem. Eng. Data, 51, 261 (2006)

[15] Ku HC, Tu CH, J. Chem. Eng. Data, 50, 608 (2005)